File name: Pandora163s1_Tsukuba-NIES-West_20251124_L2Fit_fout2c12d20240101p1-8.txt File generation date: 20251124T143853.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c12p1-8 Local principal investigator: Jinsoo Park Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 163 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora163_OF_v9d20190605.txt Instrument calibration file used: Pandora163s1_CF_v12d20240101.txt Level 1 file used: Pandora163s1_Tsukuba-NIES-West_20251124_L1_smca1c12d20240101p1-8.txt Full location name: National Institute for Environmental Studies (NIES), lidar building Short location name: Tsukuba-NIES-West Country of location: Japan Location latitude [deg]: 36.0506 Location longitude [deg]: 140.1202 Location altitude [m]: 30 Local noon date: 20251124 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 11 for fieldcal for VP from 20240101 First and last pixel inside fitting window: 225 366 Nominal wavelengths inside fitting window [nm]: 305.1227 305.2636 305.4045 305.5454 305.6863 305.8272 305.9680 306.1089 306.2497 306.3906 306.5314 306.6722 306.8130 306.9538 307.0946 307.2353 307.3761 307.5168 307.6575 307.7982 307.9390 308.0796 308.2203 308.3610 308.5017 308.6423 308.7829 308.9236 309.0642 309.2048 309.3454 309.4860 309.6265 309.7671 309.9076 310.0482 310.1887 310.3292 310.4697 310.6102 310.7506 310.8911 311.0316 311.1720 311.3124 311.4529 311.5933 311.7337 311.8740 312.0144 312.1548 312.2951 312.4355 312.5758 312.7161 312.8564 312.9967 313.1370 313.2772 313.4175 313.5577 313.6980 313.8382 313.9784 314.1186 314.2588 314.3990 314.5391 314.6793 314.8194 314.9596 315.0997 315.2398 315.3799 315.5200 315.6600 315.8001 315.9402 316.0802 316.2202 316.3602 316.5002 316.6402 316.7802 316.9202 317.0601 317.2001 317.3400 317.4799 317.6198 317.7597 317.8996 318.0395 318.1794 318.3192 318.4591 318.5989 318.7387 318.8785 319.0183 319.1581 319.2979 319.4376 319.5774 319.7171 319.8568 319.9965 320.1362 320.2759 320.4156 320.5553 320.6949 320.8346 320.9742 321.1138 321.2534 321.3930 321.5326 321.6722 321.8117 321.9513 322.0908 322.2304 322.3699 322.5094 322.6489 322.7883 322.9278 323.0673 323.2067 323.3461 323.4856 323.6250 323.7644 323.9038 324.0431 324.1825 324.3218 324.4612 324.6005 324.7398 324.8791 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251123T220944.1Z 9458.923427 58 1 50.87 2 82.86 121.90 119.88 104.23 0.00 1 0.00 1 0 25 6.437e-01 3.435e-02 4.354e-01 2.713e-02 8.023534e-01 1.565150e-02 9.128067e-03 -6.000000e+00 3.654051e-01 224.10 -2.00 3.41 -2.00 321.97 0.00e+00 6.357681e-03 7.714186e-03 7.088156e-04 -6.000000e+00 1.754206e-02 283.31 -2.00 20.00 -2.00 321.48 0.00e+00 7.405 0.006 302.00 328.00 3 1.5157e+00 5.6241e-02 8.4402e-02 -6.0000e+00 9.0256e-01 1.1361e+00 7.0095e-02 4.2734e-02 -6.0000e+00 9.8537e-01 -1.4934e+00 5.2503e-02 2.1331e-02 -6.0000e+00 5.8698e-01 6.1100e-01 2.5994e-02 7.5926e-03 -6.0000e+00 2.5475e-01 3.0345e-05 -3.5460e-03 7.6603e-04 1.0412e-04 -6.0000e+00 1.7216e-02 1.4664e-02 0.0000e+00 12 8 8 10 0 0 82.25 21.01 0.53 0.01466 -0.01198 30 5 1 5 0 1695.390 24.86 20.01 21.01 13.79 17.5 884.05 -21133 96049 104927 900000 -93590 167025 -78444 28948 97763 -97522 900000 -83226 900000 216207 900000 -27740 900000 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2053 3234 3360 4739 4185 2854 1167 1846 4344 2221 5395 1199 4986 3485 3611 611 2374 461 6375 5324 -2210 -112 156 3215 -1273 1569 -3510 912 3297 -2301 3094 -5667 3142 -3023 450 -706 -4302 3655 -3842 -428 -5294 1439 -3614 1246 -1138 -79 -2156 -4091 1261 -8735 -794 -4455 352 -1392 -4208 572 1193 110 -3360 1128 2063 4621 2694 2010 -894 -2945 -326 1592 2978 -4565 6909 3256 4284 -134 6451 184 401 -252 2572 97 540 -2241 -2075 3600 -5306 -250 1060 -1424 -827 SS 20251123T222043.9Z 9458.931064 61 1 50.88 2 80.99 123.69 117.82 105.49 0.00 1 0.00 1 0 25 4.687e-01 7.108e-03 3.234e-01 5.397e-03 6.816089e-01 2.965511e-03 7.528308e-03 -6.000000e+00 2.640735e-01 224.10 -2.00 3.41 -2.00 321.63 0.00e+00 2.166386e-03 1.618085e-03 8.983589e-04 -6.000000e+00 1.274094e-02 283.31 -2.00 20.00 -2.00 321.11 0.00e+00 6.053 0.003 302.00 328.00 3 1.1960e+00 1.1007e-02 6.9845e-02 -6.0000e+00 6.4985e-01 6.7681e-02 1.6580e-02 3.7380e-02 -6.0000e+00 7.0700e-01 -1.0645e-01 1.8020e-02 2.0851e-02 -6.0000e+00 4.2084e-01 3.6239e-02 8.3107e-03 7.2122e-03 -6.0000e+00 1.8336e-01 2.0892e-04 -7.7934e-04 1.5389e-04 8.3655e-05 -6.0000e+00 1.2460e-02 1.3906e-02 0.0000e+00 11 8 0 10 0 0 74.26 21.01 0.41 0.01391 0.00805 108 20 1 5 0 471.070 24.86 20.01 21.01 14.32 17.5 887.93 -210560 -225132 -78033 -62695 430 900000 -201283 -160726 -64344 -192235 900000 -143903 -61703 25441 -36601 -55996 -74180 156083 -82306 -10673 22704 -68384 1105 -3470 4760 -22984 900000 5906 -32964 -14876 -13916 -5586 -13775 -22162 13767 18486 33882 1718 12739 19307 -4771 -9206 -836 11507 7519 2069 13979 6832 6505 457 1183 5096 2268 2063 4971 -2232 2430 -1493 -1615 -3373 3189 6353 7957 6680 1338 54 -2467 909 2146 4234 1078 -145 -977 2401 -935 -874 -4255 -3066 -3904 -1157 -1106 -453 -600 -671 -914 -1005 1092 -179 161 1542 781 -150 318 1070 -485 272 1178 4 140 -486 -1009 -168 -589 -2051 -547 -1919 -1126 -327 296 522 549 478 250 737 -557 -114 119 177 -315 -174 278 374 96 -5 137 300 634 463 -190 270 -327 43 -514 102 -197 57 264 84 -166 -102 -159 182 -1611 -2260 -410 -330 2 900000 -1732 -1076 -338 -2114 900000 -1307 -325 134 -245 -535 -958 821 -1377 -92 141 -1079 10 -35 48 -319 900000 59 -504 -243 -278 -123 -377 -664 275 369 677 59 482 802 -278 -600 -52 648 451 135 838 463 472 39 114 528 266 263 648 -327 346 -217 -228 -486 463 1019 1448 1363 291 12 -550 211 571 1258 354 -49 -320 702 -254 -215 -1063 -819 -1246 -429 -477 -219 -312 -371 -544 -635 706 -118 104 928 441 -81 171 625 -334 218 1081 4 153 -514 -970 -143 -483 -1817 -514 -1921 -1191 -373 378 749 859 770 396 1105 -801 -161 174 275 -520 -289 445 572 143 -7 190 398 839 685 -326 514 -678 94 -1189 252 -474 142 663 214 -413 -264 -385 415 SS 20251123T223308.5Z 9458.939682 66 1 50.69 2 78.93 125.77 115.50 106.91 0.00 1 0.00 1 0 25 2.347e-01 4.674e-03 1.063e-01 2.085e-03 5.809495e-01 1.110871e-03 6.499366e-03 -6.000000e+00 1.311125e-01 224.10 -2.00 3.41 -2.00 321.05 0.00e+00 1.863830e-03 5.048146e-04 4.209776e-04 -6.000000e+00 5.869440e-03 283.30 -2.00 20.00 -2.00 320.46 0.00e+00 5.025 0.002 302.00 328.00 3 9.1047e-01 3.6935e-03 5.7954e-02 -6.0000e+00 3.2314e-01 1.6242e-02 4.9915e-03 3.0396e-02 -6.0000e+00 3.5129e-01 -3.7564e-02 5.0495e-03 1.6160e-02 -6.0000e+00 2.0978e-01 9.2434e-03 2.4565e-03 5.6856e-03 -6.0000e+00 9.1507e-02 8.0851e-04 -7.0880e-04 5.9880e-05 5.9625e-05 -6.0000e+00 6.0991e-03 1.3515e-02 0.0000e+00 10 0 0 10 0 0 72.84 21.02 0.36 0.01351 0.00819 242 44 1 5 0 209.420 24.86 20.01 21.02 15.40 17.7 897.52 -108811 -71909 -114939 -66508 -76757 -69323 -75679 -41071 -55029 -80449 -31614 -65812 -33384 -20654 -39454 -16290 -21916 -16913 -20370 -6185 -16375 -4682 -7670 -4049 -6393 -20443 -13279 -21833 -4734 -16276 -2755 -5614 -4084 -6223 -4399 -13127 -2147 -4139 1010 -751 -2960 1902 1847 451 1870 -2091 -1308 -1498 276 82 -504 2580 1605 1812 1269 1467 -715 1640 284 120 1525 2768 2854 1840 1208 1175 249 740 1777 965 1362 359 612 156 352 -1062 -1522 -665 -1287 -712 -433 -1607 -1517 -1574 -653 -193 55 355 1035 457 615 559 141 -77 25 27 543 174 -64 41 -417 -467 -80 -969 -1246 -1192 -606 -89 572 401 463 307 308 8 -96 261 77 107 -436 -423 53 246 128 97 61 11 738 362 231 260 -92 -226 -196 -122 -99 -84 304 80 -57 5 -206 -65 -804 -412 -1041 -344 -411 -359 -476 -213 -366 -729 -187 -657 -309 -214 -605 -252 -397 -320 -427 -118 -350 -90 -165 -93 -162 -623 -373 -644 -119 -520 -92 -228 -184 -287 -190 -646 -110 -267 76 -67 -295 192 194 49 203 -242 -153 -182 35 11 -78 429 294 356 263 316 -160 351 60 26 344 696 815 580 382 356 76 239 654 407 613 166 272 65 131 -364 -506 -233 -528 -344 -240 -1008 -1016 -1120 -494 -155 46 299 849 356 443 378 94 -55 21 25 536 193 -74 45 -463 -466 -77 -1006 -1396 -1401 -683 -108 762 595 740 500 487 13 -135 359 111 163 -707 -698 84 378 192 139 84 15 1058 520 377 469 -178 -457 -417 -278 -239 -210 772 205 -143 12 -465 -139 SS 20251123T223855.6Z 9458.943699 69 1 50.85 2 77.99 126.76 114.43 107.57 0.00 1 0.00 1 0 25 1.549e-01 4.572e-03 6.746e-02 1.507e-03 5.456263e-01 7.891173e-04 6.186441e-03 -6.000000e+00 8.656064e-02 224.10 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