File name: Pandora193s1_Tsukuba_20211123_L2Fit_fout2c1d20211001p1-8.txt File generation date: 20251211T064355.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Kei Shiomi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 193 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora193_OF_v3d20210223.txt Instrument calibration file used: Pandora193s1_CF_v1d20211001.txt Level 1 file used: Pandora193s1_Tsukuba_20211123_L1_smca1c1d20211001p1-8.txt Full location name: Japan Aerospace Exploration Agency, Tsukuba Space Center (JAXA-TKSC) Short location name: Tsukuba Country of location: Japan Location latitude [deg]: 36.0661 Location longitude [deg]: 140.1244 Location altitude [m]: 51 Local noon date: 20211123 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 369 Nominal wavelengths inside fitting window [nm]: 305.0577 305.1987 305.3397 305.4807 305.6217 305.7627 305.9036 306.0446 306.1855 306.3265 306.4674 306.6083 306.7492 306.8901 307.0310 307.1719 307.3128 307.4536 307.5945 307.7353 307.8761 308.0169 308.1578 308.2986 308.4393 308.5801 308.7209 308.8616 309.0024 309.1431 309.2838 309.4246 309.5653 309.7059 309.8466 309.9873 310.1280 310.2686 310.4092 310.5499 310.6905 310.8311 310.9717 311.1123 311.2528 311.3934 311.5340 311.6745 311.8150 311.9555 312.0960 312.2365 312.3770 312.5175 312.6580 312.7984 312.9389 313.0793 313.2197 313.3601 313.5005 313.6409 313.7813 313.9216 314.0620 314.2023 314.3427 314.4830 314.6233 314.7636 314.9039 315.0442 315.1844 315.3247 315.4649 315.6052 315.7454 315.8856 316.0258 316.1660 316.3061 316.4463 316.5865 316.7266 316.8667 317.0069 317.1470 317.2871 317.4272 317.5672 317.7073 317.8474 317.9874 318.1274 318.2675 318.4075 318.5475 318.6874 318.8274 318.9674 319.1073 319.2473 319.3872 319.5271 319.6670 319.8069 319.9468 320.0867 320.2266 320.3664 320.5063 320.6461 320.7859 320.9257 321.0655 321.2053 321.3451 321.4849 321.6246 321.7644 321.9041 322.0438 322.1835 322.3232 322.4629 322.6026 322.7422 322.8819 323.0215 323.1612 323.3008 323.4404 323.5800 323.7196 323.8591 323.9987 324.1383 324.2778 324.4173 324.5568 324.6964 324.8358 324.9753 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211122T230415.3Z 7996.961289 309 1 0.89 2 73.82 131.21 73.93 290.60 0.00 1 0.00 1 0 25 8.816e-02 1.346e-02 5.950e-02 7.452e-03 3.967054e-01 3.716939e-03 4.516316e-03 -6.000000e+00 5.009032e-02 224.10 -2.00 3.41 -2.00 318.79 0.00e+00 3.729724e-03 7.542449e-04 1.440699e-04 -6.000000e+00 2.051289e-03 283.27 -2.00 20.00 -2.00 318.47 0.00e+00 3.529 0.001 302.00 328.00 3 6.9274e-01 9.9956e-03 3.9964e-02 -6.0000e+00 1.2430e-01 -2.5878e-02 1.1348e-02 1.9490e-02 -6.0000e+00 1.3598e-01 -6.1477e-03 8.3647e-03 9.7886e-03 -6.0000e+00 8.0176e-02 2.3183e-03 4.4858e-03 2.8829e-03 -6.0000e+00 3.3289e-02 5.1941e-03 -8.7307e-04 2.1849e-04 3.2320e-05 -6.0000e+00 2.4759e-03 -3.2325e-03 -7.1202e-05 12 9 9 12 1 1 999.00 22.75 0.43 -0.00323 -0.00979 2 42 1 5 0 236.480 26.11 19.94 22.75 18.66 25.7 970.14 -23218 -9386 -6150 -51167 -4321 -42663 -5711 -24770 -15627 -35353 -17387 -22179 -22977 6803 -17492 11561 -13944 12540 -6418 4205 -8448 10222 -4563 8061 2537 -1377 1869 -10212 -2064 -8117 10299 -1245 5747 -4293 -3874 -9562 -6571 -4982 786 1479 -1172 1880 -2025 3129 183 230 -2239 5088 -403 4131 746 5965 3245 435 2996 3674 2381 -1249 -859 -565 2772 1567 3142 3736 920 554 -1028 1131 -317 2167 882 1226 450 -1265 -2506 -1619 -3509 -3411 -483 -2187 -1540 -1997 -2036 -165 -1114 -1230 -168 1077 1028 884 1373 -89 -2956 -395 -858 -184 166 1487 -712 98 -644 -1237 -1049 -1637 -2239 -1769 -478 65 1506 192 1838 936 486 167 -460 972 -939 886 -229 545 -211 1297 1601 389 1959 -1182 988 8 1364 -1307 59 -1690 -382 -55 -419 -179 693 950 -414 798 -658 -725 -679 -842 -340 -228 -2822 -141 -1933 -191 -1102 -706 -2038 -866 -1238 -1525 411 -1584 912 -1516 1143 -739 459 -1062 1087 -569 945 328 -193 256 -1519 -277 -1188 1410 -211 1013 -863 -751 -1928 -1400 -1196 211 452 -400 659 -759 1151 70 89 -885 1909 -159 1623 319 2623 1539 222 1549 1930 1285 -692 -469 -307 1518 923 1976 2483 633 369 -670 728 -217 1598 700 1003 368 -1019 -1929 -1155 -2396 -2300 -337 -1702 -1307 -1831 -1965 -162 -1159 -1337 -188 1217 1166 980 1449 -91 -2926 -385 -882 -204 198 1888 -951 130 -823 -1505 -1228 -1957 -2820 -2298 -637 90 2139 289 2850 1480 760 252 -671 1366 -1339 1286 -349 851 -333 2005 2429 581 2823 -1694 1370 12 2026 -2067 97 -2855 -653 -97 -763 -335 1308 1814 -797 1497 -1215 -1310 -1215 SS 20211123T003630.8Z 7997.025356 370 1 29.95 2 62.06 150.83 90.07 302.55 0.00 1 0.00 1 0 17 1.558e-02 8.937e-03 8.657e-04 3.569e-04 2.545867e-01 1.786106e-04 2.957689e-03 -6.000000e+00 8.859136e-03 224.10 -2.00 3.41 -2.00 316.68 0.00e+00 1.171896e-03 2.048608e-05 4.532920e-05 -6.000000e+00 3.624116e-04 283.26 -2.00 20.00 -2.00 316.36 0.00e+00 2.123 0.000 302.00 328.00 3 3.3812e-01 4.6314e-04 2.4399e-02 -6.0000e+00 2.1985e-02 -2.9045e-03 5.1920e-04 1.2373e-02 -6.0000e+00 2.4044e-02 2.1158e-03 3.0685e-04 6.1569e-03 -6.0000e+00 1.4177e-02 -5.2668e-03 1.4655e-04 1.7745e-03 -6.0000e+00 5.8909e-03 3.4407e-02 1.2557e-04 1.0412e-05 2.1072e-05 -6.0000e+00 4.3731e-04 -5.5561e-03 7.8522e-05 12 9 1 12 1 1 100.00 22.80 0.36 -0.00556 -0.00461 595 200 1 5 0 49.700 26.11 19.96 22.80 18.97 26.0 972.46 -1868 -746 -1981 -4152 -4746 -3537 -4289 -2649 -2485 -5116 -5081 -4079 -2161 -1537 1143 -6 873 1547 1948 2331 1243 2067 2465 1699 699 987 -834 -561 -776 841 963 1283 1203 -2815 -3618 -2810 -2736 -1813 -449 -994 -852 -240 -90 -94 841 394 -22 392 -626 816 1010 820 1252 1340 635 1110 485 -180 102 188 1493 1631 2473 1739 -30 -87 -113 -162 1400 903 695 1226 507 785 -335 -641 -1518 -1943 -1372 -2125 -2010 -2145 -2654 -1581 -697 -526 490 579 908 379 251 -454 -768 -215 -437 -164 600 970 -353 -520 -775 -1259 -800 -368 -1726 -1354 -630 -544 736 1071 1138 672 566 92 -87 149 7 411 550 409 250 1011 762 722 768 -262 317 876 116 -361 -341 -609 -318 57 33 -79 539 575 -87 -102 -453 -764 -851 -269 -117 -323 -655 -675 -519 -663 -406 -421 -938 -929 -758 -440 -358 296 -2 242 443 579 714 392 643 778 567 247 360 -310 -197 -256 270 326 467 474 -1188 -1457 -1100 -1161 -816 -238 -573 -537 -158 -57 -60 533 251 -14 257 -407 527 684 555 894 1007 465 824 368 -137 76 140 1132 1327 2166 1534 -26 -77 -93 -130 1176 808 681 1179 490 771 -309 -568 -1233 -1515 -1115 -1953 -1951 -2170 -2881 -1691 -792 -607 590 718 1124 454 293 -487 -802 -218 -468 -184 704 1255 -463 -672 -989 -1492 -945 -449 -2195 -1725 -836 -756 1016 1567 1673 1000 847 129 -117 190 9 546 748 593 369 1465 1079 1027 1035 -341 411 1146 156 -519 -492 -905 -481 85 52 -127 881 962 -147 -167 -720 -1230 -1349 SS 20211123T005044.9Z 7997.035242 376 1 8.65 2 60.74 154.32 92.38 304.59 0.00 1 0.00 1 0 17 1.451e-02 8.890e-03 1.206e-03 5.734e-04 2.451979e-01 2.878552e-04 2.855296e-03 -6.000000e+00 8.248085e-03 224.10 -2.00 3.41 -2.00 316.30 0.00e+00 1.017696e-03 3.026734e-05 3.884616e-05 -6.000000e+00 3.374624e-04 283.26 -2.00 20.00 -2.00 315.98 0.00e+00 2.036 0.000 302.00 328.00 3 1.8333e-01 7.4329e-04 2.3421e-02 -6.0000e+00 2.0468e-02 -4.0791e-03 8.3285e-04 1.1904e-02 -6.0000e+00 2.2386e-02 2.6221e-03 4.8468e-04 5.9210e-03 -6.0000e+00 1.3199e-02 -5.0582e-03 2.2545e-04 1.7033e-03 -6.0000e+00 5.4842e-03 4.4392e-02 1.6184e-05 1.6695e-05 2.0629e-05 -6.0000e+00 4.0721e-04 -5.3510e-03 5.6950e-05 12 9 1 12 1 1 99.88 22.81 0.35 -0.00535 -0.00523 151 178 1 5 0 55.760 26.11 20.08 22.81 19.93 25.8 978.11 -1113 -806 -1572 -4215 -3917 -3859 -3262 -2222 -2157 -4940 -4421 -3288 -1862 -1099 555 -4 1148 1894 1584 2096 1276 2146 2449 1916 909 1139 -202 -484 -291 945 1063 1286 1396 -2693 -3351 -2719 -2731 -1719 -637 -931 -820 -159 -104 129 730 283 10 200 -638 787 1083 838 1121 1249 645 888 423 -248 130 50 1457 1560 2392 1630 -211 -156 -142 -110 1326 772 684 1125 437 812 -234 -666 -1370 -1806 -1264 -2175 -1879 -2131 -2670 -1646 -670 -494 423 584 888 415 276 -369 -787 -64 -426 -221 695 951 -394 -568 -738 -1326 -767 -407 -1630 -1360 -560 -551 753 1026 1071 641 581 152 -110 322 76 451 561 454 194 918 753 805 816 -251 463 839 176 -341 -329 -482 -362 117 20 -79 456 504 -161 -114 -482 -742 -831 -198 -157 -316 -823 -682 -638 -560 -418 -449 -1114 -988 -744 -462 -285 161 -1 384 652 568 714 446 740 857 707 355 459 -82 -188 -105 361 394 512 598 -1236 -1464 -1156 -1260 -844 -345 -589 -532 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