File name: Pandora254s1_TubaCityAZ_20250807_L2Fit_fout2c2d20221208p1-8.txt File generation date: 20250808T073507.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vaughn Salabye Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 254 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora254_OF_v2d20221208.txt Instrument calibration file used: Pandora254s1_CF_v2d20221208.txt Level 1 file used: Pandora254s1_TubaCityAZ_20250807_L1_smca1c2d20221208p1-8.txt Full location name: Greyhills Academy High School, Tuba City, AZ Short location name: TubaCityAZ Country of location: United States Location latitude [deg]: 36.1270 Location longitude [deg]: -111.2212 Location altitude [m]: 1470 Local noon date: 20250807 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0315 305.1725 305.3134 305.4543 305.5952 305.7361 305.8770 306.0179 306.1587 306.2996 306.4404 306.5812 306.7220 306.8629 307.0036 307.1444 307.2852 307.4260 307.5667 307.7074 307.8482 307.9889 308.1296 308.2703 308.4110 308.5516 308.6923 308.8330 308.9736 309.1142 309.2548 309.3954 309.5360 309.6766 309.8172 309.9577 310.0983 310.2388 310.3793 310.5199 310.6604 310.8009 310.9413 311.0818 311.2223 311.3627 311.5031 311.6436 311.7840 311.9244 312.0648 312.2052 312.3455 312.4859 312.6262 312.7666 312.9069 313.0472 313.1875 313.3278 313.4681 313.6083 313.7486 313.8888 314.0291 314.1693 314.3095 314.4497 314.5899 314.7301 314.8702 315.0104 315.1505 315.2906 315.4308 315.5709 315.7110 315.8511 315.9911 316.1312 316.2712 316.4113 316.5513 316.6913 316.8313 316.9713 317.1113 317.2513 317.3912 317.5312 317.6711 317.8111 317.9510 318.0909 318.2308 318.3706 318.5105 318.6504 318.7902 318.9301 319.0699 319.2097 319.3495 319.4893 319.6291 319.7688 319.9086 320.0483 320.1881 320.3278 320.4675 320.6072 320.7469 320.8865 321.0262 321.1659 321.3055 321.4451 321.5847 321.7243 321.8639 322.0035 322.1431 322.2827 322.4222 322.5617 322.7013 322.8408 322.9803 323.1198 323.2593 323.3987 323.5382 323.6776 323.8171 323.9565 324.0959 324.2353 324.3747 324.5141 324.6534 324.7928 324.9321 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250807T132506.0Z 9350.559097 162 1 55.24 2 81.60 75.98 121.23 258.95 0.00 1 0.00 1 0 17 6.011e-01 2.457e-02 4.199e-01 1.687e-02 7.341602e-01 9.555383e-03 8.693809e-03 -6.000000e+00 3.487814e-01 230.62 -2.00 3.37 -2.00 321.79 0.00e+00 4.546275e-03 5.352949e-03 8.072600e-03 -6.000000e+00 1.733119e-02 284.82 -2.00 20.00 -2.00 321.25 0.00e+00 6.447 0.004 302.00 328.00 3 3.2345e+00 3.6336e-02 7.6761e-02 -6.0000e+00 8.6964e-01 4.8411e-01 5.0853e-02 6.3959e-02 -6.0000e+00 9.4651e-01 -6.7585e-01 4.6297e-02 3.2697e-02 -6.0000e+00 5.6173e-01 2.7147e-01 2.1006e-02 8.5044e-03 -6.0000e+00 2.3733e-01 4.0522e-05 8.1114e-04 4.7799e-04 1.7781e-04 -6.0000e+00 1.6408e-02 3.3566e-02 12 8 8 10 0 0 76.08 25.81 0.26 0.03357 0.03966 23 2 1 5 0 2401.270 34.25 20.00 25.81 27.66 3.3 972.06 900000 -131175 -160085 900000 -132087 900000 -112452 46245 -209779 -136556 -188902 31357 -143930 -74293 -18780 -98018 900000 51459 21118 900000 183343 900000 -52634 119390 900000 900000 125467 900000 -69511 -38707 124051 -66726 2523 90144 -476 91214 210281 128235 176197 -13327 7712 77796 16897 17858 -10726 79788 45354 61717 20215 92315 49909 36847 43364 42211 14799 37089 43518 23981 16931 19852 34790 14819 10707 7061 4926 13288 13865 14514 14530 5678 581 2539 5509 9005 16886 -3024 -11369 25927 -7592 -4313 2809 -8294 47 -212 211 2399 2553 -688 -1626 -1597 3374 -1247 -6620 -3339 168 -3525 -821 47 -2888 -106 -2500 -3722 1167 -1818 -1252 -2644 -1868 -2253 -648 -700 1581 -72 -1415 -595 -358 -479 -1104 898 115 962 922 798 3636 3661 1749 1798 -1170 889 -627 828 950 31 -772 -710 893 -21 736 872 -134 -222 -45 -2422 -857 900000 -2333 -3943 900000 -2169 900000 -1846 759 -8768 -2854 -6767 515 -4727 -1553 -308 -3804 900000 845 347 900000 3010 900000 -1650 1960 900000 900000 2060 900000 -2698 -1213 2037 -3984 87 1480 -16 1498 3453 2106 2893 -935 483 2555 1059 1120 -897 2739 2234 2672 1388 3307 3054 2860 3431 3655 1767 3654 4092 2685 1946 2163 3376 1947 1678 1296 963 2553 2641 2860 3197 1576 185 817 1674 2455 3826 -745 -2875 4683 -2207 -1459 1038 -3922 23 -107 113 1335 1484 -422 -1001 -939 1751 -637 -3478 -1793 100 -2552 -675 45 -3030 -107 -2398 -3221 877 -1442 -1069 -2410 -1792 -2345 -738 -905 2232 -110 -2181 -879 -500 -647 -1533 1288 177 1512 1415 1172 5015 4870 2284 2264 -1476 1178 -971 1435 1809 64 -1684 -1653 2196 -55 1926 2313 -356 -558 -106 -5429 -1841 SS 20250807T133947.3Z 9350.569297 167 1 54.32 2 78.71 78.03 124.01 260.75 0.00 1 0.00 1 0 17 3.163e-01 8.254e-03 1.616e-01 4.067e-03 5.864821e-01 2.134631e-03 6.432331e-03 -6.000000e+00 1.800651e-01 230.62 -2.00 3.37 -2.00 320.95 0.00e+00 3.148006e-03 9.484385e-04 2.364777e-03 -6.000000e+00 7.969245e-03 284.82 -2.00 20.00 -2.00 320.33 0.00e+00 4.938 0.002 302.00 328.00 3 3.0225e+00 6.9525e-03 5.1849e-02 -6.0000e+00 4.5021e-01 5.6843e-02 9.2689e-03 3.1904e-02 -6.0000e+00 4.8832e-01 -8.5258e-02 9.0034e-03 1.7574e-02 -6.0000e+00 2.9053e-01 2.8571e-02 4.3791e-03 5.9733e-03 -6.0000e+00 1.2277e-01 2.0799e-04 3.6282e-04 1.1323e-04 7.0983e-05 -6.0000e+00 8.2981e-03 3.3925e-02 11 8 0 10 0 0 92.07 25.86 0.38 0.03393 0.03665 56 6 1 5 0 969.900 34.50 20.01 25.86 28.73 3.3 978.32 -107062 -110881 -76074 -96515 -93728 -98978 19421 -115279 -105797 -61771 -143996 -136751 -26559 -29161 -20623 1897 -40213 -33536 -20992 -5256 -7987 -45841 -24463 7178 -14054 -27445 2561 -1075 -11284 -14516 -2980 -8423 -21905 -3762 2082 -4855 -8653 -12652 -1929 103 -2436 -2343 6651 5454 -1248 -3318 2562 -1 1087 -131 6792 1354 4048 4029 2094 4925 1762 2132 3515 3020 417 4177 4862 4525 1518 1254 -303 -71 454 1505 1663 1829 1192 1367 -775 57 -3156 -3954 -2678 -1322 -783 -1659 -1828 -1170 -400 -406 648 817 1289 1245 -160 -196 -638 -887 -815 -846 402 428 634 -395 -730 -1906 -495 -346 -1308 -1572 -956 -426 379 469 679 198 326 -191 -410 98 25 -131 680 248 -117 577 530 436 529 -37 552 515 182 -375 -148 51 -202 -213 -81 -446 397 588 27 6 58 -523 -520 -927 -1160 -604 -905 -777 -857 77 -1455 -1373 -557 -3064 -3057 -249 -358 -290 25 -914 -786 -469 -106 -170 -1422 -644 150 -390 -920 65 -30 -340 -489 -106 -374 -1286 -195 97 -241 -498 -903 -152 9 -258 -265 723 614 -152 -424 314 0 144 -19 1010 237 751 812 453 1076 409 490 774 661 97 1042 1367 1427 510 405 -98 -23 165 628 760 867 560 605 -319 21 -1113 -1423 -1069 -617 -422 -1024 -1227 -823 -300 -325 539 697 1091 1010 -122 -139 -434 -623 -642 -768 415 503 800 -496 -857 -2034 -480 -346 -1429 -1813 -1156 -547 527 661 1046 320 518 -291 -587 147 38 -190 1049 400 -188 883 786 685 795 -54 767 754 302 -631 -270 99 -406 -454 -185 -1068 961 1449 66 15 129 -1105 -1072 SS 20250807T134622.6Z 9350.573873 170 1 54.59 2 77.41 78.95 125.26 261.57 0.00 1 0.00 1 0 17 1.578e-01 6.026e-03 1.072e-01 2.612e-03 5.364616e-01 1.361145e-03 5.903997e-03 -6.000000e+00 8.980423e-02 230.62 -2.00 3.37 -2.00 320.58 0.00e+00 2.264557e-03 5.384582e-04 1.395932e-03 -6.000000e+00 3.974451e-03 284.82 -2.00 20.00 -2.00 319.90 0.00e+00 4.464 0.001 302.00 328.00 3 2.8953e+00 4.2900e-03 4.6742e-02 -6.0000e+00 2.2454e-01 1.8625e-02 5.4617e-03 2.7984e-02 -6.0000e+00 2.4354e-01 -2.6201e-02 5.0321e-03 1.4786e-02 -6.0000e+00 1.4489e-01 1.2457e-03 2.5044e-03 4.9697e-03 -6.0000e+00 6.1231e-02 3.6682e-04 5.6164e-04 7.3875e-05 5.9160e-05 -6.0000e+00 4.1383e-03 3.3677e-02 10 0 0 10 0 0 75.10 25.91 0.38 0.03368 0.03790 75 8 1 5 0 727.740 34.50 20.00 25.91 29.14 3.3 981.35 -35551 -72170 -21477 -62453 -76540 -48510 15677 -26099 -56947 -36808 -33566 -10639 -47631 50180 -6510 -2925 -19621 -5776 -18818 16 -10556 3628 -16381 -13041 -12126 -13101 -9858 -24464 -9253 -17214 4714 -7768 6361 -4796 -9269 -6364 -6615 -2299 -3621 783 -2340 3487 -1715 1649 -1440 2596 -1503 1834 1140 352 1080 528 2347 1707 -153 1173 475 348 372 -985 -13 3130 2964 3181 993 -687 1123 -167 1727 1133 1399 2250 66 1769 -647 -418 261 -1701 -2623 -1064 -757 -1150 -2454 -1525 -722 -547 378 156 343 933 1164 -313 52 -220 171 -138 -10 876 269 -252 -486 -1031 -636 156 -631 -1096 -799 -693 -256 433 500 360 284 -103 -131 -40 -166 1 353 180 -65 376 637 320 206 -273 -277 779 407 -220 -340 -94 -639 -50 145 -314 186 702 295 -76 -55 -466 -227 -222 -752 -144 -607 -780 -371 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