File name: Pandora254s1_TubaCityAZ_20251007_L2Fit_fout2c2d20221208p1-8.txt File generation date: 20251008T071839.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vaughn Salabye Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 254 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora254_OF_v2d20221208.txt Instrument calibration file used: Pandora254s1_CF_v2d20221208.txt Level 1 file used: Pandora254s1_TubaCityAZ_20251007_L1_smca1c2d20221208p1-8.txt Full location name: Greyhills Academy High School, Tuba City, AZ Short location name: TubaCityAZ Country of location: United States Location latitude [deg]: 36.1270 Location longitude [deg]: -111.2212 Location altitude [m]: 1470 Local noon date: 20251007 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0315 305.1725 305.3134 305.4543 305.5952 305.7361 305.8770 306.0179 306.1587 306.2996 306.4404 306.5812 306.7220 306.8629 307.0036 307.1444 307.2852 307.4260 307.5667 307.7074 307.8482 307.9889 308.1296 308.2703 308.4110 308.5516 308.6923 308.8330 308.9736 309.1142 309.2548 309.3954 309.5360 309.6766 309.8172 309.9577 310.0983 310.2388 310.3793 310.5199 310.6604 310.8009 310.9413 311.0818 311.2223 311.3627 311.5031 311.6436 311.7840 311.9244 312.0648 312.2052 312.3455 312.4859 312.6262 312.7666 312.9069 313.0472 313.1875 313.3278 313.4681 313.6083 313.7486 313.8888 314.0291 314.1693 314.3095 314.4497 314.5899 314.7301 314.8702 315.0104 315.1505 315.2906 315.4308 315.5709 315.7110 315.8511 315.9911 316.1312 316.2712 316.4113 316.5513 316.6913 316.8313 316.9713 317.1113 317.2513 317.3912 317.5312 317.6711 317.8111 317.9510 318.0909 318.2308 318.3706 318.5105 318.6504 318.7902 318.9301 319.0699 319.2097 319.3495 319.4893 319.6291 319.7688 319.9086 320.0483 320.1881 320.3278 320.4675 320.6072 320.7469 320.8865 321.0262 321.1659 321.3055 321.4451 321.5847 321.7243 321.8639 322.0035 322.1431 322.2827 322.4222 322.5617 322.7013 322.8408 322.9803 323.1198 323.2593 323.3987 323.5382 323.6776 323.8171 323.9565 324.0959 324.2353 324.3747 324.5141 324.6534 324.7928 324.9321 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251007T135626.0Z 9411.580857 244 1 54.43 2 84.63 101.13 90.00 282.37 0.00 1 0.00 1 0 17 5.803e-01 1.884e-02 4.182e-01 1.117e-02 9.225293e-01 6.517975e-03 9.330793e-03 -6.000000e+00 3.256822e-01 226.49 -2.00 3.37 -2.00 322.44 0.00e+00 4.171494e-03 4.183791e-03 2.249027e-03 -6.000000e+00 1.593491e-02 280.27 -2.00 20.00 -2.00 322.02 0.00e+00 9.337 0.013 302.00 328.00 3 3.4642e-01 2.7297e-02 9.4720e-02 -6.0000e+00 8.0832e-01 8.1439e-01 4.1021e-02 5.8835e-02 -6.0000e+00 8.8123e-01 -1.0556e+00 4.2246e-02 2.8158e-02 -6.0000e+00 5.2393e-01 4.1497e-01 1.8788e-02 1.0691e-02 -6.0000e+00 2.2496e-01 6.1403e-05 -6.0071e-04 3.0495e-04 1.3400e-04 -6.0000e+00 1.5780e-02 3.6369e-02 12 8 8 10 0 0 3.56 24.76 0.70 0.03637 0.03185 91 9 1 5 0 598.080 33.75 20.10 24.76 15.07 3.4 888.13 -103344 -206374 900000 900000 -71004 -146719 -235294 -38730 -243911 900000 -199167 -11479 -114531 -77815 -43160 -94174 -98124 -79187 -63108 42052 900000 900000 -61591 900000 65852 21013 158141 900000 -106264 -82172 900000 -38797 -96838 -3917 -6174 -55423 113553 78072 28028 40039 124776 23998 34686 31471 59709 28886 46395 30217 -151 42929 58807 38134 59939 28219 69296 35648 62814 21861 27324 62082 12679 6992 11516 13409 29666 -1820 23907 3361 18491 20425 4401 18915 20574 19476 7639 -886 1543 4757 -7934 7770 2595 3167 784 3440 2857 2019 2953 4458 1502 -2264 739 6208 -3362 -2451 -2694 1035 -3130 600 -1842 -550 -1562 -970 -4406 -3717 -3394 -3990 -2783 -3088 -352 232 -1801 -612 -939 -1373 -125 -915 -467 -235 -188 1442 397 2617 1294 2562 2153 1247 1420 906 -488 1054 364 376 420 718 -233 -1044 -273 1182 746 -91 -759 -1496 -772 -1124 -3555 900000 900000 -773 -1596 -4655 -421 -6032 900000 -3349 -125 -1246 -847 -470 -1677 -2038 -1488 -1061 458 900000 900000 -975 900000 717 229 1721 900000 -2733 -1869 900000 -883 -4598 -77 -116 -1645 1236 849 554 832 1358 688 926 872 1240 829 1147 927 -7 1359 1803 1622 2253 1591 2742 2045 2796 1427 1595 2702 924 601 1103 1459 2937 -246 2549 468 2495 3133 867 3313 3425 3009 1180 -132 215 683 -1528 1573 661 934 262 1187 1057 798 1205 1829 629 -941 277 2101 -1251 -981 -1272 565 -2118 459 -1589 -468 -1249 -681 -2862 -2410 -2367 -2952 -2168 -2644 -333 255 -2313 -843 -1328 -1922 -166 -1196 -621 -329 -278 2146 575 3499 1688 3203 2622 1490 1661 1162 -752 1863 728 818 979 1799 -636 -3005 -791 3416 2139 -247 -1915 -3513 -1738 SS 20251007T140812.4Z 9411.589032 247 1 54.52 2 82.30 102.93 92.19 284.09 0.00 1 0.00 1 0 17 5.991e-01 7.389e-03 1.822e-01 2.246e-03 7.524209e-01 1.214421e-03 8.123647e-03 -6.000000e+00 3.356685e-01 226.48 -2.00 3.37 -2.00 321.65 0.00e+00 2.129317e-03 6.573618e-04 3.762805e-03 -6.000000e+00 1.480418e-02 280.27 -2.00 20.00 -2.00 321.13 0.00e+00 6.959 0.005 302.00 328.00 3 3.4372e-01 4.4006e-03 7.1830e-02 -6.0000e+00 8.3235e-01 1.0740e-01 6.6592e-03 4.4690e-02 -6.0000e+00 9.0644e-01 -1.2991e-01 7.4062e-03 2.4917e-02 -6.0000e+00 5.3963e-01 4.3172e-02 3.4023e-03 8.1367e-03 -6.0000e+00 2.2896e-01 5.2861e-04 5.3087e-04 6.0134e-05 1.2369e-04 -6.0000e+00 1.5700e-02 3.6727e-02 11 8 0 10 0 0 21.63 24.77 0.38 0.03673 0.04072 310 31 1 5 0 175.830 33.75 19.94 24.77 15.59 3.4 893.06 -199042 -260138 -214980 -192902 -240004 -72191 -196332 -59962 -181406 -211123 -157920 -113039 -112534 -118780 -108585 -72342 -36478 -61646 -76395 -52254 -49589 -40723 -62700 -37828 -34057 -21983 -23170 -38935 -30659 -26362 -29760 -40964 -17727 -15895 -27921 -14127 -10024 -10290 -1163 -9265 5631 -7705 -2369 -1643 2109 811 5480 1711 -2771 2551 5465 2018 3096 4025 7739 5146 4618 3679 -2176 -619 -609 5617 5539 4798 3809 2040 472 1764 1317 1023 2007 3206 1768 1073 1101 -1674 -2313 -982 -1142 -321 -296 -685 -2144 -1736 -830 128 756 505 1377 793 843 -158 -1130 -1184 -895 -868 385 1592 436 -196 -871 -1109 -1181 -278 -1806 -1479 -1189 -639 -16 277 513 465 395 -151 -322 -248 13 214 381 -7 177 591 1066 344 516 -517 -117 797 362 -51 -100 -308 -499 -255 -7 -364 327 617 257 -79 -118 -264 -274 -832 -2383 -1370 -960 -1769 -158 -1056 -131 -1120 -1934 -912 -495 -650 -970 -1038 -591 -240 -589 -928 -531 -504 -381 -787 -414 -393 -241 -263 -504 -403 -375 -548 -1032 -419 -397 -752 -334 -257 -320 -41 -432 257 -434 -134 -95 119 48 321 110 -199 191 453 196 330 469 929 666 622 497 -301 -83 -85 826 945 944 798 428 102 396 336 304 650 1064 582 332 308 -431 -570 -250 -338 -114 -124 -332 -1156 -989 -503 82 502 344 926 512 506 -90 -641 -714 -619 -706 361 1550 465 -207 -862 -1077 -1045 -249 -1780 -1528 -1298 -683 -19 373 770 739 631 -234 -475 -353 19 326 613 -11 285 902 1566 492 709 -693 -153 1105 583 -94 -203 -670 -1149 -573 -16 -923 836 1598 662 -192 -294 -617 -625 SS 20251007T142601.8Z 9411.601410 252 1 54.50 2 78.82 105.71 95.49 286.74 0.00 1 0.00 1 0 17 1.991e-01 5.869e-03 2.312e-02 6.564e-04 5.696705e-01 3.366853e-04 6.168354e-03 -6.000000e+00 1.115364e-01 226.48 -2.00 3.37 -2.00 320.47 0.00e+00 1.981735e-03 1.286648e-04 1.031249e-03 -6.000000e+00 4.919152e-03 280.27 -2.00 20.00 -2.00 319.89 0.00e+00 4.982 0.002 302.00 328.00 3 2.4945e-01 1.0220e-03 5.0498e-02 -6.0000e+00 2.7657e-01 3.0731e-02 1.3065e-03 2.8658e-02 -6.0000e+00 3.0119e-01 -2.0060e-02 1.2711e-03 1.5394e-02 -6.0000e+00 1.7931e-01 -1.3940e-03 6.4000e-04 5.4485e-03 -6.0000e+00 7.6078e-02 3.3363e-03 4.2236e-04 1.8013e-05 5.6743e-05 -6.0000e+00 5.2168e-03 3.6760e-02 10 0 0 10 0 0 8.14 24.78 0.32 0.03676 0.03993 796 81 1 5 0 68.460 33.50 20.00 24.78 17.48 3.4 905.00 -66093 -75160 -51425 -66332 -68832 -80987 -77240 -64586 -45731 -51126 -51561 -52960 -36912 -27657 -20059 -13840 -17907 -13193 -13176 -9287 -14383 -16392 -13269 -9603 -10699 -9103 -10651 -11074 -11254 -9646 -6120 -2727 -2910 -5772 -8249 -8006 -4732 -3923 -2090 -1546 -451 -1639 -20 -16 206 1098 482 74 -303 843 1831 1000 1773 2155 1734 1847 1505 681 194 353 1774 2157 3068 2879 744 141 -105 -600 1045 572 1002 962 640 523 -554 -860 -1563 -1744 -1145 -1093 -1084 -1024 -1992 -1589 -744 -269 294 636 1054 1123 773 89 -341 -286 -151 -223 416 1143 381 -197 -653 -1012 -546 -143 -1177 -1287 -1087 -761 114 390 473 321 337 -84 -254 4 59 159 334 -38 -179 351 680 343 515 -207 73 780 219 -92 -121 -322 -400 -143 -114 -207 168 542 220 -22 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