File name: Pandora254s1_TubaCityAZ_20251010_L2Fit_fout2c2d20221208p1-8.txt File generation date: 20251011T071802.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vaughn Salabye Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 254 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora254_OF_v2d20221208.txt Instrument calibration file used: Pandora254s1_CF_v2d20221208.txt Level 1 file used: Pandora254s1_TubaCityAZ_20251010_L1_smca1c2d20221208p1-8.txt Full location name: Greyhills Academy High School, Tuba City, AZ Short location name: TubaCityAZ Country of location: United States Location latitude [deg]: 36.1270 Location longitude [deg]: -111.2212 Location altitude [m]: 1470 Local noon date: 20251010 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 192 334 Nominal wavelengths inside fitting window [nm]: 305.0315 305.1725 305.3134 305.4543 305.5952 305.7361 305.8770 306.0179 306.1587 306.2996 306.4404 306.5812 306.7220 306.8629 307.0036 307.1444 307.2852 307.4260 307.5667 307.7074 307.8482 307.9889 308.1296 308.2703 308.4110 308.5516 308.6923 308.8330 308.9736 309.1142 309.2548 309.3954 309.5360 309.6766 309.8172 309.9577 310.0983 310.2388 310.3793 310.5199 310.6604 310.8009 310.9413 311.0818 311.2223 311.3627 311.5031 311.6436 311.7840 311.9244 312.0648 312.2052 312.3455 312.4859 312.6262 312.7666 312.9069 313.0472 313.1875 313.3278 313.4681 313.6083 313.7486 313.8888 314.0291 314.1693 314.3095 314.4497 314.5899 314.7301 314.8702 315.0104 315.1505 315.2906 315.4308 315.5709 315.7110 315.8511 315.9911 316.1312 316.2712 316.4113 316.5513 316.6913 316.8313 316.9713 317.1113 317.2513 317.3912 317.5312 317.6711 317.8111 317.9510 318.0909 318.2308 318.3706 318.5105 318.6504 318.7902 318.9301 319.0699 319.2097 319.3495 319.4893 319.6291 319.7688 319.9086 320.0483 320.1881 320.3278 320.4675 320.6072 320.7469 320.8865 321.0262 321.1659 321.3055 321.4451 321.5847 321.7243 321.8639 322.0035 322.1431 322.2827 322.4222 322.5617 322.7013 322.8408 322.9803 323.1198 323.2593 323.3987 323.5382 323.6776 323.8171 323.9565 324.0959 324.2353 324.3747 324.5141 324.6534 324.7928 324.9321 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251010T160426.6Z 9414.669752 318 1 13.50 2 61.47 124.50 72.35 289.62 0.00 1 0.00 1 0 17 1.086e-02 6.844e-03 3.801e-03 1.703e-03 2.394903e-01 8.444357e-04 2.767036e-03 -6.000000e+00 6.080032e-03 226.22 -2.00 3.37 -2.00 316.49 0.00e+00 9.288834e-05 9.919621e-05 8.051250e-05 -6.000000e+00 2.679796e-04 279.91 -2.00 20.00 -2.00 315.83 0.00e+00 2.084 0.000 302.00 328.00 3 3.9396e+00 2.1937e-03 2.1036e-02 -6.0000e+00 1.5069e-02 7.3519e-03 2.4645e-03 1.1662e-02 -6.0000e+00 1.6412e-02 -2.7407e-03 1.4359e-03 5.7446e-03 -6.0000e+00 9.7708e-03 -1.4459e-03 6.8041e-04 1.6176e-03 -6.0000e+00 4.1485e-03 1.3575e-03 4.6526e-04 4.7049e-05 1.8147e-05 -6.0000e+00 2.8451e-04 3.3940e-02 12 9 1 12 1 1 98.37 25.52 0.26 0.03394 0.03744 16 7 1 5 0 793.890 34.00 20.00 25.52 25.61 3.3 956.29 -786 -1184 -906 -3659 -2635 -4532 958 -96 -941 -585 -2161 -1909 -1636 1816 -351 675 -652 835 689 1575 597 686 730 1615 647 639 453 -505 -1288 755 1526 1322 2325 -1283 -3764 -1726 -2005 -1546 120 -550 -859 -764 -219 -514 -377 -1020 -607 -212 -515 413 791 275 859 1449 1126 1255 860 204 33 197 930 1940 1622 1834 271 -282 -385 -521 1074 0 260 358 315 682 -24 -157 -707 -1137 -281 -956 -1057 -1495 -2441 -1819 -1098 -631 -144 329 651 305 480 212 -2 241 -36 -317 750 1135 -121 -264 -271 -962 -825 278 -748 -894 -770 -694 -14 434 402 239 363 253 68 196 248 -22 319 50 -357 320 710 318 742 182 218 1057 393 88 -25 -79 -272 52 111 -175 219 282 -29 -59 -257 -774 -603 -135 -221 -171 -658 -413 -695 148 -17 -186 -121 -443 -399 -382 425 -95 198 -201 262 224 526 204 231 252 586 249 255 180 -189 -448 253 539 503 948 -553 -1534 -677 -868 -715 66 -325 -553 -511 -150 -354 -258 -702 -406 -137 -327 260 526 196 643 1054 844 957 670 159 25 149 724 1611 1467 1640 243 -248 -314 -414 902 0 255 365 319 662 -22 -136 -558 -923 -221 -858 -993 -1555 -2550 -1974 -1272 -735 -176 412 812 365 560 226 -2 242 -38 -355 922 1449 -164 -350 -335 -1170 -952 332 -930 -1171 -1053 -936 -20 648 599 357 547 352 92 249 317 -30 435 73 -532 466 1004 432 1005 236 268 1305 525 119 -35 -114 -401 80 172 -284 362 454 -46 -98 -410 -1198 -916 SS 20251010T164604.6Z 9414.698664 343 1 6.21 2 54.96 133.95 79.79 294.77 0.00 1 0.00 1 0 17 1.565e-02 9.850e-03 1.257e-02 6.768e-03 2.041720e-01 3.362670e-03 2.333483e-03 -6.000000e+00 8.763130e-03 226.21 -2.00 3.37 -2.00 315.94 0.00e+00 7.290946e-04 3.497194e-04 5.446601e-05 -6.000000e+00 3.862239e-04 279.91 -2.00 20.00 -2.00 315.31 0.00e+00 1.737 0.000 302.00 328.00 3 5.5476e+00 8.6804e-03 1.7618e-02 -6.0000e+00 2.1719e-02 3.2391e-02 9.7339e-03 9.8759e-03 -6.0000e+00 2.3655e-02 -9.3599e-03 5.6080e-03 4.8472e-03 -6.0000e+00 1.4082e-02 -3.4508e-04 2.5742e-03 1.4322e-03 -6.0000e+00 5.9795e-03 3.8126e-04 5.1600e-04 1.8687e-04 1.5610e-05 -6.0000e+00 4.1003e-04 3.3470e-02 12 9 9 12 1 1 999.00 25.60 0.50 0.03347 0.03735 1 2 1 5 0 3102.220 34.25 20.00 25.60 25.26 3.3 953.55 4834 -3507 -2236 329 -3725 -1554 -2796 827 -3746 -1689 1126 -3284 -2412 1557 -602 -358 1036 4003 1874 4269 474 -532 608 -313 3049 82 2010 -1512 -3590 -1748 1001 2184 4239 -2222 -2502 -2011 -3762 -808 631 -1393 -830 -622 150 -212 -745 -1450 -2039 1382 -1706 1094 -439 1566 1223 1336 1542 197 1020 -172 1252 -312 1240 2186 2925 1495 -890 148 -2252 -1968 966 299 -32 1038 454 1285 -915 1266 647 -1611 -1087 -1671 -2267 -1365 -1701 -806 -485 -766 469 813 247 1366 52 -1065 -156 652 273 251 -332 1241 -548 -250 -874 -196 -1126 70 -672 -1982 -672 -252 -296 649 350 668 569 150 191 -788 716 -580 1123 215 -81 71 1223 704 761 169 -265 681 43 103 214 -760 -468 -10 230 -313 995 428 -137 -573 357 -91 -1450 1062 -821 -574 76 -782 -305 -587 187 -979 -449 282 -871 -705 450 -201 -129 377 1453 718 1645 192 -214 246 -134 1317 38 896 -649 -1450 -679 397 911 1862 -1056 -1096 -858 -1792 -435 367 -960 -614 -438 108 -153 -539 -1051 -1446 991 -1224 760 -326 1120 920 1052 1239 163 848 -144 1008 -254 1030 1933 2576 1410 -842 135 -1940 -1638 835 275 -32 1068 468 1263 -853 1111 514 -1341 -870 -1515 -2144 -1405 -1857 -910 -548 -931 592 1054 322 1686 60 -1202 -158 634 283 286 -393 1598 -708 -333 -1094 -224 -1325 80 -844 -2650 -868 -339 -416 958 510 970 837 204 252 -988 888 -764 1472 304 -117 102 1682 928 1012 214 -320 822 56 142 289 -1054 -655 -15 354 -478 1534 680 -219 -898 536 -140 -2230 SS 20251010T165031.8Z 9414.701756 346 1 1.32 2 54.32 135.06 80.57 295.34 0.00 1 0.00 1 0 17 1.209e-02 8.208e-03 7.657e-03 5.215e-03 1.972804e-01 2.619712e-03 2.308583e-03 -6.000000e+00 6.768628e-03 226.21 -2.00 3.37 -2.00 314.97 0.00e+00 4.113564e-05 2.239713e-04 3.169282e-05 -6.000000e+00 2.983231e-04 279.91 -2.00 20.00 -2.00 314.42 0.00e+00 1.710 0.000 302.00 328.00 3 3.8066e+00 6.6965e-03 1.7284e-02 -6.0000e+00 1.6776e-02 1.4548e-02 7.4711e-03 9.6049e-03 -6.0000e+00 1.8271e-02 -2.3472e-04 4.2745e-03 4.7361e-03 -6.0000e+00 1.0877e-02 -2.6461e-03 1.8936e-03 1.3307e-03 -6.0000e+00 4.6184e-03 2.2689e-03 4.3935e-04 1.4216e-04 1.6837e-05 -6.0000e+00 3.1672e-04 3.3690e-02 12 9 1 12 1 1 999.00 25.60 0.33 0.03369 0.03699 1 8 1 5 0 658.590 34.25 20.00 25.60 25.39 3.3 955.60 -1487 464 -2138 -4217 -2734 -4082 2929 2115 1319 -1198 -1785 -33 -1486 -479 1197 44 251 2008 1945 1585 1301 -1638 1042 1719 1364 -1421 -672 -522 -29 2012 3702 1790 698 -2170 -2609 -1762 -3148 -1547 -304 -78 -841 -94 -778 -270 710 -146 -528 -437 363 -1010 1016 231 680 1064 688 1524 1631 -637 610 546 751 953 1524 2043 206 -500 -417 -1082 481 277 -521 332 641 430 242 -536 -426 -895 -646 -1421 -995 -653 -2070 -1539 -522 -965 414 6 635 439 -543 -8 268 -844 -214 -131 574 726 536 -54 -622 -379 -454 -510 -563 -735 -697 -220 -16 213 425 -16 767 100 -138 225 -110 60 316 -544 -784 842 1147 805 883 -454 656 1214 858 758 -89 -270 134 -24 -360 55 65 484 485 -228 -252 -1351 -1034 -474 156 -745 -1380 -831 -1202 854 696 451 -437 -636 -12 -589 -198 546 21 120 966 966 815 679 -867 547 889 740 -819 -381 -274 -15 981 1856 971 387 -1255 -1394 -971 -1819 -968 -214 -58 -673 -74 -630 -219 565 -116 -431 -343 274 -769 797 185 571 892 592 1321 1435 -569 527 470 666 869 1432 2015 202 -467 -373 -945 441 266 -528 347 665 448 235 -509 -380 -756 -569 -1358 -973 -671 -2283 -1697 -591 -1136 506 8 799 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