File name: Pandora259s1_TylerTX_20250804_L2Fit_fout2c3d20230310p1-8.txt File generation date: 20250805T063857.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: James Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 259 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora259_OF_v4d20221229.txt Instrument calibration file used: Pandora259s1_CF_v3d20230310.txt Level 1 file used: Pandora259s1_TylerTX_20250804_L1_smca1c3d20230310p1-8.txt Full location name: Tyler Pounds Regional Airport Short location name: TylerTX Country of location: United States Location latitude [deg]: 32.3440 Location longitude [deg]: -95.4159 Location altitude [m]: 164 Local noon date: 20250804 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 195 337 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1851 305.3256 305.4661 305.6066 305.7470 305.8875 306.0279 306.1684 306.3088 306.4492 306.5896 306.7300 306.8704 307.0108 307.1511 307.2915 307.4318 307.5721 307.7125 307.8528 307.9930 308.1333 308.2736 308.4139 308.5541 308.6943 308.8346 308.9748 309.1150 309.2552 309.3954 309.5355 309.6757 309.8158 309.9560 310.0961 310.2362 310.3763 310.5164 310.6565 310.7966 310.9366 311.0767 311.2167 311.3567 311.4967 311.6367 311.7767 311.9167 312.0567 312.1966 312.3366 312.4765 312.6164 312.7563 312.8962 313.0361 313.1760 313.3159 313.4557 313.5955 313.7354 313.8752 314.0150 314.1548 314.2946 314.4344 314.5741 314.7139 314.8536 314.9934 315.1331 315.2728 315.4125 315.5522 315.6918 315.8315 315.9711 316.1108 316.2504 316.3900 316.5296 316.6692 316.8088 316.9484 317.0879 317.2275 317.3670 317.5065 317.6460 317.7855 317.9250 318.0645 318.2040 318.3434 318.4829 318.6223 318.7617 318.9011 319.0405 319.1799 319.3193 319.4587 319.5980 319.7373 319.8767 320.0160 320.1553 320.2946 320.4339 320.5731 320.7124 320.8516 320.9909 321.1301 321.2693 321.4085 321.5477 321.6869 321.8261 321.9652 322.1044 322.2435 322.3826 322.5217 322.6608 322.7999 322.9390 323.0780 323.2171 323.3561 323.4952 323.6342 323.7732 323.9122 324.0512 324.1901 324.3291 324.4680 324.6070 324.7459 324.8848 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250804T161052.8Z 9347.674222 189 1 12.01 2 34.45 108.06 158.13 85.27 0.00 1 0.00 1 0 25 1.191e-02 9.155e-03 2.527e-03 1.904e-03 1.637644e-01 1.055948e-03 1.888777e-03 -6.000000e+00 7.431972e-03 230.61 -2.00 3.31 -2.00 314.42 0.00e+00 -1.979377e-04 8.705498e-05 1.875074e-05 -6.000000e+00 3.487201e-04 292.97 -2.00 20.00 -2.00 313.74 0.00e+00 1.212 0.000 302.00 328.00 3 5.0737e+00 2.7023e-03 1.4388e-02 -6.0000e+00 1.8506e-02 2.1897e-02 2.9774e-03 8.0355e-03 -6.0000e+00 1.9926e-02 8.9129e-04 1.7065e-03 3.9147e-03 -6.0000e+00 1.1923e-02 -4.0107e-03 7.3189e-04 1.0878e-03 -6.0000e+00 5.0296e-03 8.6423e-04 9.8234e-05 6.2431e-05 1.7743e-05 -6.0000e+00 3.9543e-04 1.1261e-02 0.0000e+00 12 9 1 12 1 1 91.90 28.97 0.55 0.01126 0.01200 7 4 1 5 0 1500.540 37.00 20.02 28.97 31.11 3.6 1022.24 -2787 -3211 -3824 -2672 2334 1871 952 2082 815 -1090 754 1633 1688 -421 -477 -1032 -363 1581 200 1418 265 1495 1144 377 158 -303 -1158 -1226 2360 2805 2290 1651 146 -2322 -1016 1861 804 412 649 -1720 -2021 -970 -847 -1514 -1165 -1149 -1111 -664 72 900 1017 414 965 316 222 486 762 528 492 1844 1594 1418 918 -186 -1189 -328 983 1053 2065 1125 -775 -760 -874 -677 -817 -117 331 1275 1545 632 -1225 -1543 -2421 -1365 -458 -565 -528 -480 -598 -646 41 464 528 1694 1985 1150 505 -125 -801 -930 -477 -458 530 933 -265 -1400 -727 -598 61 137 -122 -458 -392 145 227 1150 964 1035 470 -89 -718 -276 -62 44 667 1016 680 1555 928 389 272 -361 -159 299 165 -198 -216 378 -372 -555 -376 -391 -683 -1111 -1358 -1622 -1067 829 684 359 784 336 -474 325 713 730 -204 -238 -549 -199 872 115 772 148 831 643 220 96 -190 -717 -726 1356 1543 1269 960 85 -1385 -586 1100 480 266 461 -1348 -1650 -825 -737 -1336 -1022 -996 -939 -540 59 727 840 343 833 285 197 437 691 480 443 1638 1455 1364 900 -184 -1178 -317 908 977 1868 1069 -780 -804 -935 -706 -840 -114 306 1094 1327 590 -1224 -1615 -2622 -1484 -525 -664 -632 -595 -746 -785 48 519 561 1758 2079 1244 577 -151 -988 -1152 -585 -526 599 1061 -311 -1701 -921 -761 80 182 -169 -643 -534 191 285 1383 1131 1244 580 -113 -963 -371 -82 58 832 1245 828 1839 1092 484 341 -468 -208 388 224 -275 -310 535 -537 -796 -543 -548 -939 SS 20250804T161624.2Z 9347.678058 192 1 54.05 2 33.34 109.36 157.02 86.20 0.00 1 0.00 1 0 25 1.573e-02 1.027e-02 2.563e-03 1.761e-03 1.639174e-01 9.689473e-04 1.882156e-03 -6.000000e+00 9.819770e-03 230.61 -2.00 3.31 -2.00 314.89 0.00e+00 -2.241516e-04 8.781613e-05 4.745851e-05 -6.000000e+00 4.607205e-04 292.97 -2.00 20.00 -2.00 314.17 0.00e+00 1.196 0.000 302.00 328.00 3 6.3952e+00 2.4913e-03 1.4266e-02 -6.0000e+00 2.4452e-02 3.2539e-02 2.7519e-03 8.0376e-03 -6.0000e+00 2.6328e-02 6.1959e-03 1.5719e-03 3.9095e-03 -6.0000e+00 1.5753e-02 -6.5439e-03 6.8333e-04 1.0960e-03 -6.0000e+00 6.6461e-03 2.3248e-04 2.8503e-04 5.7614e-05 1.7441e-05 -6.0000e+00 5.2243e-04 1.0653e-02 0.0000e+00 12 9 8 11 8 0 99.92 28.97 0.78 0.01065 0.01279 15 2 1 5 0 3602.980 37.25 20.02 28.97 31.34 3.6 1024.38 -4488 -1175 -5778 -1786 5933 -1540 -2030 -1282 -756 535 4062 1290 1472 133 -2954 -4 1665 4590 -1629 4655 487 1282 670 433 -74 -802 -614 -3408 534 2274 4450 2297 -409 -2940 -250 1687 1005 -1075 1840 -1386 -1477 -1482 -123 -849 -1267 -1854 -1119 -570 426 791 -337 378 128 337 450 471 165 2136 240 3087 1911 1327 832 -551 -1560 -235 1041 1024 1863 351 -608 -727 -1096 -888 -541 -147 -512 1308 915 1626 -1163 -1647 -2140 -1137 -87 45 -44 43 -951 -752 777 831 138 1651 2043 279 709 -423 -1252 -802 -1026 -719 481 281 -116 -1883 -942 -676 656 71 666 -121 -447 378 136 1635 439 1229 -105 -160 -629 272 -287 -259 604 1187 450 1158 818 643 303 -331 -90 -239 248 5 26 91 -637 -270 -434 -529 -241 -1543 -413 -2119 -599 1723 -459 -623 -424 -269 195 1439 481 581 54 -1343 -2 798 2189 -845 2324 257 676 359 239 -39 -441 -331 -1954 278 1121 2153 1184 -226 -1672 -136 891 567 -652 1262 -1035 -1204 -1187 -100 -697 -1041 -1514 -948 -465 333 611 -269 314 111 284 390 415 148 1868 212 2651 1701 1250 835 -546 -1550 -232 939 887 1651 344 -611 -767 -1173 -925 -530 -140 -476 1118 789 1496 -1132 -1648 -2302 -1279 -97 53 -55 53 -1184 -963 920 957 146 1739 2170 302 836 -516 -1537 -1042 -1278 -836 560 332 -137 -2410 -1183 -883 881 100 920 -170 -613 507 178 1968 521 1482 -136 -209 -860 372 -387 -337 785 1455 529 1408 966 798 395 -446 -116 -318 342 8 38 133 -952 -398 -625 -740 -347 SS 20250804T170224.6Z 9347.710007 214 1 55.75 2 24.62 123.36 147.80 92.44 0.00 1 0.00 1 0 17 1.173e-02 8.970e-03 1.585e-03 1.196e-03 1.495633e-01 6.601998e-04 1.716838e-03 -6.000000e+00 7.323244e-03 230.61 -2.00 3.31 -2.00 314.39 0.00e+00 -1.377518e-04 5.467706e-05 1.808737e-05 -6.000000e+00 3.435745e-04 292.97 -2.00 20.00 -2.00 313.73 0.00e+00 1.100 0.000 302.00 328.00 3 5.8843e+00 1.6897e-03 1.3073e-02 -6.0000e+00 1.8235e-02 2.2808e-02 1.8625e-03 7.3152e-03 -6.0000e+00 1.9634e-02 3.8825e-03 1.0668e-03 3.5606e-03 -6.0000e+00 1.1748e-02 -4.4288e-03 4.5833e-04 9.8543e-04 -6.0000e+00 4.9567e-03 4.4058e-04 2.1668e-04 3.9153e-05 1.6225e-05 -6.0000e+00 3.8959e-04 1.0283e-02 0.0000e+00 11 9 0 11 8 0 99.84 28.95 0.57 0.01028 0.01191 21 2 1 5 0 2654.330 37.00 20.02 28.95 33.57 3.6 1040.10 -2713 -1956 -4223 -2233 2932 1061 395 715 -47 -1031 1752 1821 886 872 -1844 -1280 171 1694 -470 1606 354 1581 1422 -73 180 131 -1025 -1833 1406 2684 3248 1934 337 -2255 -669 1552 798 -15 991 -1686 -1844 -1000 -831 -1104 -1399 -1258 -1137 -518 203 746 750 137 733 654 159 579 444 1170 601 2079 1615 1226 834 -399 -1406 -354 1050 865 2265 940 -524 -894 -1243 -658 -460 -102 381 1148 1217 626 -923 -1621 -1983 -1336 -351 -589 -421 -67 -812 -730 420 694 300 1536 2329 608 570 -185 -1091 -1026 -623 -453 403 977 -93 -1392 -539 -544 89 156 203 -369 -430 129 377 1242 803 1037 412 -195 -595 4 -212 -180 340 828 616 1226 943 422 401 -204 60 20 179 -239 -182 224 -480 -452 -321 -512 -309 -1066 -803 -1764 -869 1096 384 147 287 -19 -434 722 764 397 427 -940 -687 94 935 -270 926 209 930 843 -42 108 80 -622 -1146 804 1454 1747 1094 201 -1388 -396 892 490 -10 704 -1311 -1564 -885 -710 -951 -1205 -1068 -996 -435 164 591 606 117 649 567 142 524 407 1062 544 1855 1483 1188 814 -409 -1444 -339 966 808 2029 927 -538 -969 -1299 -702 -463 -99 353 986 1046 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