File name: Pandora259s1_TylerTX_20250813_L2Fit_fout2c3d20230310p1-8.txt File generation date: 20250814T063905.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: James Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 259 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora259_OF_v4d20221229.txt Instrument calibration file used: Pandora259s1_CF_v3d20230310.txt Level 1 file used: Pandora259s1_TylerTX_20250813_L1_smca1c3d20230310p1-8.txt Full location name: Tyler Pounds Regional Airport Short location name: TylerTX Country of location: United States Location latitude [deg]: 32.3440 Location longitude [deg]: -95.4159 Location altitude [m]: 164 Local noon date: 20250813 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 195 337 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1851 305.3256 305.4661 305.6066 305.7470 305.8875 306.0279 306.1684 306.3088 306.4492 306.5896 306.7300 306.8704 307.0108 307.1511 307.2915 307.4318 307.5721 307.7125 307.8528 307.9930 308.1333 308.2736 308.4139 308.5541 308.6943 308.8346 308.9748 309.1150 309.2552 309.3954 309.5355 309.6757 309.8158 309.9560 310.0961 310.2362 310.3763 310.5164 310.6565 310.7966 310.9366 311.0767 311.2167 311.3567 311.4967 311.6367 311.7767 311.9167 312.0567 312.1966 312.3366 312.4765 312.6164 312.7563 312.8962 313.0361 313.1760 313.3159 313.4557 313.5955 313.7354 313.8752 314.0150 314.1548 314.2946 314.4344 314.5741 314.7139 314.8536 314.9934 315.1331 315.2728 315.4125 315.5522 315.6918 315.8315 315.9711 316.1108 316.2504 316.3900 316.5296 316.6692 316.8088 316.9484 317.0879 317.2275 317.3670 317.5065 317.6460 317.7855 317.9250 318.0645 318.2040 318.3434 318.4829 318.6223 318.7617 318.9011 319.0405 319.1799 319.3193 319.4587 319.5980 319.7373 319.8767 320.0160 320.1553 320.2946 320.4339 320.5731 320.7124 320.8516 320.9909 321.1301 321.2693 321.4085 321.5477 321.6869 321.8261 321.9652 322.1044 322.2435 322.3826 322.5217 322.6608 322.7999 322.9390 323.0780 323.2171 323.3561 323.4952 323.6342 323.7732 323.9122 324.0512 324.1901 324.3291 324.4680 324.6070 324.7459 324.8848 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250813T183855.2Z 9356.777027 412 1 36.33 2 18.16 189.71 117.42 302.90 0.00 1 0.00 1 0 25 1.116e-02 8.955e-03 1.192e-03 9.527e-04 1.401405e-01 5.311415e-04 1.617528e-03 -6.000000e+00 6.959789e-03 230.38 -2.00 3.31 -2.00 314.03 0.00e+00 1.339116e-05 4.107734e-05 1.296289e-05 -6.000000e+00 3.270070e-04 293.11 -2.00 20.00 -2.00 313.41 0.00e+00 1.052 0.000 302.00 328.00 3 5.1180e+00 1.3550e-03 1.2419e-02 -6.0000e+00 1.7320e-02 4.8417e-03 1.4895e-03 6.8571e-03 -6.0000e+00 1.8651e-02 9.6276e-04 8.5644e-04 3.3435e-03 -6.0000e+00 1.1163e-02 -2.8085e-03 3.6479e-04 9.2570e-04 -6.0000e+00 4.7124e-03 1.0211e-03 1.6281e-04 3.1254e-05 1.5759e-05 -6.0000e+00 3.7056e-04 1.0771e-02 0.0000e+00 12 9 1 12 9 1 99.00 28.85 0.55 0.01077 0.01199 28 4 1 5 0 1252.590 37.00 20.01 28.85 31.63 3.6 1026.13 -1499 -2440 -4011 -2774 270 1962 1244 1374 195 -959 560 2046 1438 721 -258 -1130 -195 1033 18 967 761 1456 1404 408 373 -95 -1709 -1343 1676 2746 2202 1702 538 -2005 -927 1794 1050 560 836 -1603 -2248 -1253 -929 -1351 -1102 -951 -1311 -653 167 775 874 531 726 813 -201 609 574 433 571 1726 1633 1295 595 -421 -1196 -373 875 1127 2270 1078 -582 -991 -795 -556 -386 67 474 1160 1243 315 -1154 -1461 -2050 -1283 -604 -999 -383 -395 -827 -772 393 547 324 1675 2030 771 675 -123 -938 -743 -526 -450 163 1137 -92 -1281 -400 -535 -220 138 95 -265 -278 140 287 1107 1051 992 410 -192 -555 -212 -123 -158 397 961 719 1430 1025 412 195 -368 -227 202 267 -174 -265 105 -405 -549 -93 -525 -448 -667 -1154 -1913 -1241 117 793 516 616 89 -457 264 966 721 373 -147 -645 -114 608 11 594 475 906 880 250 238 -62 -1110 -878 1004 1656 1332 1009 334 -1283 -574 1070 669 386 631 -1335 -1952 -1081 -818 -1202 -975 -829 -1171 -558 137 655 715 456 650 720 -184 563 535 404 528 1579 1533 1227 600 -427 -1210 -368 821 1008 2066 1032 -588 -1056 -856 -584 -399 66 442 1003 1074 295 -1148 -1521 -2199 -1384 -688 -1171 -455 -486 -1029 -936 460 608 342 1720 2097 824 756 -145 -1134 -899 -632 -526 181 1269 -106 -1590 -497 -670 -285 179 129 -363 -368 179 349 1291 1241 1155 510 -247 -723 -278 -158 -203 484 1149 853 1648 1216 496 246 -460 -288 261 348 -239 -367 149 -583 -785 -129 -713 -616 SS 20250813T184340.4Z 9356.780329 415 1 54.78 2 18.36 193.33 118.21 303.80 0.00 1 0.00 1 0 25 1.129e-02 8.884e-03 1.031e-03 8.162e-04 1.404560e-01 4.546158e-04 1.623782e-03 -6.000000e+00 7.042627e-03 230.38 -2.00 3.31 -2.00 314.08 0.00e+00 -1.540960e-04 3.548014e-05 1.272695e-05 -6.000000e+00 3.309060e-04 293.11 -2.00 20.00 -2.00 313.46 0.00e+00 1.053 0.000 302.00 328.00 3 5.2450e+00 1.1602e-03 1.2445e-02 -6.0000e+00 1.7526e-02 5.9887e-03 1.2752e-03 6.8868e-03 -6.0000e+00 1.8873e-02 1.3741e-03 7.3321e-04 3.3565e-03 -6.0000e+00 1.1296e-02 -3.2038e-03 3.1328e-04 9.3120e-04 -6.0000e+00 4.7684e-03 8.9808e-04 2.0423e-04 2.6786e-05 1.5814e-05 -6.0000e+00 3.7498e-04 1.0915e-02 0.0000e+00 11 8 0 10 0 0 99.38 28.85 0.52 0.01092 0.01245 37 4 1 5 0 1480.230 37.00 20.02 28.85 32.06 3.7 1030.25 -1976 -2389 -3836 -3270 1962 1732 1148 1472 310 -1056 537 1903 1574 684 -450 -1145 -307 844 -151 1094 616 1538 1505 359 358 -212 -1421 -1404 1421 2645 2398 1845 764 -1953 -1075 1744 1260 63 801 -1558 -2058 -1112 -930 -1514 -999 -834 -1339 -723 8 567 765 502 764 630 24 529 423 639 820 1932 1757 1333 626 -387 -1239 -345 954 985 2100 970 -575 -818 -983 -727 -581 28 374 1026 1275 452 -1038 -1646 -2017 -1301 -530 -787 -517 -357 -583 -743 165 426 377 1634 2010 797 621 -73 -951 -775 -491 -262 319 971 -88 -1353 -578 -538 -242 192 80 -284 -344 13 331 1104 1016 851 442 -175 -684 -82 -103 -109 534 1056 699 1340 1046 330 402 -295 17 206 71 -145 -343 53 -454 -531 -150 -546 -415 -861 -1099 -1777 -1430 813 683 465 643 138 -492 247 879 770 345 -250 -677 -175 485 -89 654 375 932 918 227 236 -135 -952 -896 884 1558 1411 1132 462 -1218 -649 1078 781 42 591 -1265 -1741 -980 -837 -1379 -902 -742 -1166 -603 7 467 642 441 667 570 22 477 386 580 773 1802 1605 1287 616 -399 -1274 -346 913 901 1955 947 -591 -848 -1034 -777 -586 27 340 909 1127 411 -1006 -1672 -2107 -1425 -587 -934 -622 -444 -732 -911 196 481 404 1709 2023 865 706 -87 -1163 -948 -597 -298 359 1101 -102 -1636 -728 -679 -317 252 108 -391 -459 17 406 1302 1168 1004 534 -219 -900 -108 -134 -142 658 1276 807 1567 1209 402 491 -373 22 269 94 -195 -478 75 -635 -738 -210 -747 -556 SS 20250813T184908.4Z 9356.784125 418 1 54.07 2 18.67 197.39 119.10 304.86 0.00 1 0.00 1 0 17 1.166e-02 9.235e-03 8.249e-04 6.586e-04 1.400807e-01 3.658663e-04 1.616217e-03 -6.000000e+00 7.272700e-03 230.38 -2.00 3.31 -2.00 314.03 0.00e+00 -6.061342e-05 2.845760e-05 1.410778e-05 -6.000000e+00 3.416899e-04 293.11 -2.00 20.00 -2.00 313.42 0.00e+00 1.055 0.000 302.00 328.00 3 4.8202e+00 9.3359e-04 1.2442e-02 -6.0000e+00 1.8098e-02 2.3182e-03 1.0264e-03 6.8532e-03 -6.0000e+00 1.9489e-02 9.4548e-04 5.9028e-04 3.3400e-03 -6.0000e+00 1.1665e-02 -2.4845e-03 2.5187e-04 9.2296e-04 -6.0000e+00 4.9246e-03 1.3731e-03 1.7006e-04 2.1567e-05 1.5720e-05 -6.0000e+00 3.8720e-04 1.0354e-02 0.0000e+00 11 8 0 10 0 0 99.45 28.89 0.46 0.01035 0.01163 74 8 1 5 0 730.620 37.25 20.02 28.89 32.81 3.7 1036.93 -1838 -2705 -4026 -3223 1736 2442 1173 1566 708 -950 550 1845 1565 798 -394 -1203 -474 846 175 877 554 1487 1434 393 351 -131 -1590 -1457 1769 2935 1998 1481 771 -1918 -925 1778 1107 505 872 -1716 -2281 -1379 -984 -1367 -1129 -1308 -1366 -679 -7 871 916 622 720 780 23 665 627 489 706 1607 1638 1425 749 -474 -1265 -504 1043 1112 2061 1019 -560 -753 -864 -645 -469 42 502 1154 1406 600 -1011 -1559 -2064 -1370 -755 -828 -617 -549 -772 -806 126 635 582 1893 2028 894 639 -43 -1000 -883 -383 -380 403 1191 -78 -1258 -558 -542 -297 149 -83 -399 -329 81 268 1047 1103 825 486 -96 -605 -258 -151 -127 481 1045 689 1445 1003 334 322 -271 -51 138 206 -173 -269 92 -387 -523 -180 -499 -451 -807 -1260 -1887 -1517 725 1029 476 686 337 -445 255 858 771 433 -221 -680 -275 494 105 534 343 916 889 253 223 -85 -1025 -945 1049 1744 1194 923 474 -1214 -567 1112 698 346 656 -1429 -1984 -1196 -870 -1221 -1002 -1149 -1222 -582 -6 734 751 533 646 693 21 616 587 458 655 1477 1543 1356 760 -484 -1290 -500 981 1000 1887 982 -570 -807 -902 -684 -469 40 469 1000 1216 560 -967 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