File name: Pandora259s1_TylerTX_20250821_L2Fit_fout2c3d20230310p1-8.txt File generation date: 20250822T063748.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: James Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 259 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora259_OF_v4d20221229.txt Instrument calibration file used: Pandora259s1_CF_v3d20230310.txt Level 1 file used: Pandora259s1_TylerTX_20250821_L1_smca1c3d20230310p1-8.txt Full location name: Tyler Pounds Regional Airport Short location name: TylerTX Country of location: United States Location latitude [deg]: 32.3440 Location longitude [deg]: -95.4159 Location altitude [m]: 164 Local noon date: 20250821 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 195 337 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1851 305.3256 305.4661 305.6066 305.7470 305.8875 306.0279 306.1684 306.3088 306.4492 306.5896 306.7300 306.8704 307.0108 307.1511 307.2915 307.4318 307.5721 307.7125 307.8528 307.9930 308.1333 308.2736 308.4139 308.5541 308.6943 308.8346 308.9748 309.1150 309.2552 309.3954 309.5355 309.6757 309.8158 309.9560 310.0961 310.2362 310.3763 310.5164 310.6565 310.7966 310.9366 311.0767 311.2167 311.3567 311.4967 311.6367 311.7767 311.9167 312.0567 312.1966 312.3366 312.4765 312.6164 312.7563 312.8962 313.0361 313.1760 313.3159 313.4557 313.5955 313.7354 313.8752 314.0150 314.1548 314.2946 314.4344 314.5741 314.7139 314.8536 314.9934 315.1331 315.2728 315.4125 315.5522 315.6918 315.8315 315.9711 316.1108 316.2504 316.3900 316.5296 316.6692 316.8088 316.9484 317.0879 317.2275 317.3670 317.5065 317.6460 317.7855 317.9250 318.0645 318.2040 318.3434 318.4829 318.6223 318.7617 318.9011 319.0405 319.1799 319.3193 319.4587 319.5980 319.7373 319.8767 320.0160 320.1553 320.2946 320.4339 320.5731 320.7124 320.8516 320.9909 321.1301 321.2693 321.4085 321.5477 321.6869 321.8261 321.9652 322.1044 322.2435 322.3826 322.5217 322.6608 322.7999 322.9390 323.0780 323.2171 323.3561 323.4952 323.6342 323.7732 323.9122 324.0512 324.1901 324.3291 324.4680 324.6070 324.7459 324.8848 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250821T130141.4Z 9364.542841 118 1 54.26 2 75.94 84.65 55.46 85.02 0.00 1 0.00 1 0 25 1.528e-01 8.765e-03 2.918e-02 1.384e-03 5.153486e-01 7.485857e-04 5.671944e-03 -6.000000e+00 9.518856e-02 230.07 -2.00 3.31 -2.00 319.36 0.00e+00 2.739763e-03 2.150450e-04 6.276647e-04 -6.000000e+00 4.473619e-03 292.89 -2.00 20.00 -2.00 318.51 0.00e+00 4.022 0.001 302.00 328.00 3 2.7798e+00 2.1378e-03 4.6939e-02 -6.0000e+00 2.3671e-01 4.9933e-02 2.5339e-03 2.5533e-02 -6.0000e+00 2.5498e-01 -8.1490e-02 1.9096e-03 1.2915e-02 -6.0000e+00 1.5263e-01 2.4864e-02 9.9543e-04 4.5109e-03 -6.0000e+00 6.4456e-02 3.5418e-04 -2.1225e-04 4.3038e-05 5.4855e-05 -6.0000e+00 5.0736e-03 1.0953e-02 0.0000e+00 11 8 0 10 0 0 82.69 29.07 0.53 0.01095 0.00936 126 13 1 5 0 430.620 37.25 19.96 29.07 33.94 3.6 1041.72 -74899 -7373 -25640 -11592 95186 -73621 -53255 -47510 -27175 -15136 22345 -37920 -3665 -8666 -29012 1330 16171 13787 -9568 19477 9141 2128 -8964 -963 -6107 -7649 -2958 -17154 -3760 2108 13194 5315 -1926 -1466 -14 -6 874 -5267 2177 -1298 -2912 -1364 669 -496 -1622 -2871 -2792 840 2276 1374 616 532 2558 1413 2165 1281 -399 739 -43 3221 1944 2017 1927 -116 -407 1674 1202 2144 2513 1271 221 -101 -1101 -1199 -751 632 -768 665 1038 986 -1104 -1355 -2460 -1621 -527 -388 -369 -178 -582 -269 880 1524 370 1694 1722 237 481 -374 -1123 -1181 -766 -699 11 732 -756 -1731 -918 -688 -120 45 91 -502 -344 250 499 1601 1005 895 199 -302 -497 -19 75 30 312 722 554 1382 784 124 116 -168 -161 36 148 -215 -78 215 -452 -451 3 -339 -110 -1952 -111 -492 -192 527 -2167 -1344 -1257 -649 -345 377 -1311 -106 -323 -1594 62 734 698 -655 1052 566 145 -703 -74 -528 -700 -260 -1730 -333 184 1142 569 -248 -198 -2 -1 128 -957 398 -286 -731 -365 184 -142 -480 -873 -860 254 700 448 219 189 973 583 935 581 -189 347 -20 1457 919 1026 998 -67 -245 982 693 1239 1553 823 158 -76 -848 -891 -518 394 -485 407 675 676 -829 -1151 -2173 -1523 -522 -385 -387 -192 -635 -284 871 1489 347 1563 1697 250 544 -454 -1488 -1596 -990 -883 13 841 -923 -2149 -1196 -950 -168 66 144 -801 -551 385 762 2303 1507 1318 311 -475 -797 -30 120 46 461 1073 798 1992 1162 195 198 -292 -293 66 275 -423 -153 430 -914 -894 6 -638 -208 SS 20250821T161608.8Z 9364.677880 231 1 54.41 2 35.90 117.37 17.15 128.49 0.00 1 0.00 1 0 25 1.174e-02 9.158e-03 1.827e-04 1.417e-04 1.653140e-01 7.854196e-05 1.915822e-03 -6.000000e+00 7.311914e-03 230.06 -2.00 3.31 -2.00 314.26 0.00e+00 -4.546989e-05 6.332361e-06 1.990551e-05 -6.000000e+00 3.436564e-04 292.89 -2.00 20.00 -2.00 313.61 0.00e+00 1.234 0.000 302.00 328.00 3 1.5878e+00 2.0045e-04 1.4589e-02 -6.0000e+00 1.8183e-02 -3.4781e-03 2.2081e-04 8.0981e-03 -6.0000e+00 1.9587e-02 -5.4273e-05 1.2678e-04 3.9535e-03 -6.0000e+00 1.1724e-02 -2.1578e-03 5.4275e-05 1.0946e-03 -6.0000e+00 4.9510e-03 2.7813e-02 1.1869e-04 4.6469e-06 1.8306e-05 -6.0000e+00 3.8976e-04 1.1288e-02 0.0000e+00 11 9 0 11 8 0 99.26 28.88 0.39 0.01129 0.01218 1337 137 1 5 0 40.690 37.00 20.02 28.88 31.17 3.7 1023.26 -1358 -3210 -3928 -3321 1016 2627 1565 1763 589 -1023 -117 2297 1468 723 217 -1176 -745 474 204 447 530 1241 1534 283 607 19 -1645 -825 2035 2975 1838 1428 718 -1843 -866 1873 865 869 473 -1745 -2460 -1502 -1201 -1481 -940 -972 -1201 -608 63 845 1140 605 815 588 -101 521 643 200 757 1349 1544 1394 654 -437 -1211 -348 1037 1168 2290 1256 -603 -866 -1064 -655 -552 10 759 1202 1513 389 -961 -1507 -2003 -1265 -667 -987 -641 -462 -714 -742 45 612 725 1825 2043 1053 570 18 -954 -907 -316 -413 407 1195 -163 -1202 -602 -580 -373 166 -205 -475 -391 24 364 992 1253 863 503 -172 -712 -367 -164 -48 481 920 652 1499 1116 299 248 -228 -73 298 241 -229 -308 37 -411 -501 -171 -424 -449 -576 -1396 -1717 -1444 416 1008 621 720 263 -458 -52 1028 704 367 116 -650 -426 263 117 260 314 734 912 169 376 12 -1045 -497 1175 1707 1070 836 441 -1126 -534 1115 531 587 347 -1392 -2025 -1253 -1024 -1276 -804 -823 -1025 -499 51 679 933 506 693 520 -90 469 585 183 682 1209 1415 1311 639 -437 -1214 -335 966 1074 2089 1225 -616 -908 -1130 -676 -552 10 696 1061 1337 363 -947 -1546 -2155 -1393 -757 -1143 -765 -557 -871 -901 52 677 770 1866 2111 1146 648 22 -1183 -1129 -383 -481 460 1354 -193 -1467 -750 -737 -483 220 -276 -650 -530 31 451 1192 1498 1038 628 -221 -940 -487 -218 -61 611 1129 784 1751 1346 374 317 -294 -96 391 324 -319 -436 53 -594 -719 -243 -587 -621 SS 20250821T162553.3Z 9364.684645 234 1 54.42 2 34.10 120.09 15.66 134.37 0.00 1 0.00 1 0 25 1.167e-02 9.114e-03 1.742e-04 1.357e-04 1.616703e-01 7.513391e-05 1.869914e-03 -6.000000e+00 7.272478e-03 230.06 -2.00 3.31 -2.00 314.22 0.00e+00 -4.719013e-05 6.025866e-06 1.958573e-05 -6.000000e+00 3.417710e-04 292.89 -2.00 20.00 -2.00 313.58 0.00e+00 1.207 0.000 302.00 328.00 3 1.5299e+00 1.9176e-04 1.4266e-02 -6.0000e+00 1.8085e-02 -3.7699e-03 2.1108e-04 7.9104e-03 -6.0000e+00 1.9480e-02 1.0783e-05 1.2124e-04 3.8601e-03 -6.0000e+00 1.1661e-02 -2.0227e-03 5.1914e-05 1.0686e-03 -6.0000e+00 4.9247e-03 3.0473e-02 1.3676e-04 4.4500e-06 1.8016e-05 -6.0000e+00 3.8762e-04 1.0621e-02 0.0000e+00 11 8 0 10 0 0 91.14 28.96 0.39 0.01062 0.01165 1717 176 1 5 0 31.690 37.00 20.02 28.96 32.80 3.7 1036.76 -1329 -3168 -3958 -3309 845 2627 1474 1754 548 -963 -189 2196 1559 671 142 -1226 -812 413 168 429 635 1332 1618 394 639 82 -1540 -797 2059 2971 1888 1487 812 -1788 -840 1885 889 859 480 -1722 -2465 -1488 -1199 -1533 -966 -954 -1182 -595 53 871 1139 641 820 593 -109 504 604 190 738 1357 1523 1382 667 -427 -1188 -414 953 1107 2226 1264 -587 -840 -1032 -618 -577 -5 736 1168 1475 393 -956 -1467 -2000 -1294 -705 -963 -616 -468 -744 -738 27 608 685 1806 2021 1019 566 -7 -935 -911 -331 -349 429 1210 -126 -1168 -589 -569 -369 182 -175 -424 -362 5 365 978 1272 850 506 -162 -686 -357 -126 -45 469 915 658 1483 1099 287 243 -255 -96 275 252 -213 -325 42 -407 -490 -189 -398 -460 -551 -1413 -1775 -1404 339 1038 602 735 238 -441 -87 1004 725 330 77 -685 -469 231 97 252 378 791 966 235 397 53 -980 -481 1192 1711 1102 871 499 -1133 -517 1120 566 576 350 -1357 -2066 -1261 -1039 -1342 -839 -820 -993 -496 44 711 948 543 705 531 -98 458 555 175 671 1226 1408 1308 655 -428 -1195 -401 894 995 2041 1236 -600 -878 -1095 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