File name: Pandora259s1_TylerTX_20250913_L2Fit_fout2c3d20230310p1-8.txt File generation date: 20250914T063012.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: James Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 259 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora259_OF_v4d20221229.txt Instrument calibration file used: Pandora259s1_CF_v3d20230310.txt Level 1 file used: Pandora259s1_TylerTX_20250913_L1_smca1c3d20230310p1-8.txt Full location name: Tyler Pounds Regional Airport Short location name: TylerTX Country of location: United States Location latitude [deg]: 32.3440 Location longitude [deg]: -95.4159 Location altitude [m]: 164 Local noon date: 20250913 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 195 337 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1851 305.3256 305.4661 305.6066 305.7470 305.8875 306.0279 306.1684 306.3088 306.4492 306.5896 306.7300 306.8704 307.0108 307.1511 307.2915 307.4318 307.5721 307.7125 307.8528 307.9930 308.1333 308.2736 308.4139 308.5541 308.6943 308.8346 308.9748 309.1150 309.2552 309.3954 309.5355 309.6757 309.8158 309.9560 310.0961 310.2362 310.3763 310.5164 310.6565 310.7966 310.9366 311.0767 311.2167 311.3567 311.4967 311.6367 311.7767 311.9167 312.0567 312.1966 312.3366 312.4765 312.6164 312.7563 312.8962 313.0361 313.1760 313.3159 313.4557 313.5955 313.7354 313.8752 314.0150 314.1548 314.2946 314.4344 314.5741 314.7139 314.8536 314.9934 315.1331 315.2728 315.4125 315.5522 315.6918 315.8315 315.9711 316.1108 316.2504 316.3900 316.5296 316.6692 316.8088 316.9484 317.0879 317.2275 317.3670 317.5065 317.6460 317.7855 317.9250 318.0645 318.2040 318.3434 318.4829 318.6223 318.7617 318.9011 319.0405 319.1799 319.3193 319.4587 319.5980 319.7373 319.8767 320.0160 320.1553 320.2946 320.4339 320.5731 320.7124 320.8516 320.9909 321.1301 321.2693 321.4085 321.5477 321.6869 321.8261 321.9652 322.1044 322.2435 322.3826 322.5217 322.6608 322.7999 322.9390 323.0780 323.2171 323.3561 323.4952 323.6342 323.7732 323.9122 324.0512 324.1901 324.3291 324.4680 324.6070 324.7459 324.8848 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250913T130226.7Z 9387.543364 234 1 54.97 2 78.61 93.01 23.86 263.61 0.00 1 0.00 1 0 25 5.733e-01 3.888e-02 2.063e-01 7.885e-03 5.657759e-01 4.516357e-03 1.021835e-02 -6.000000e+00 3.625189e-01 228.98 -2.00 3.31 -2.00 320.60 0.00e+00 1.786266e-02 1.873901e-03 1.042260e-02 -6.000000e+00 2.067508e-02 291.83 -2.00 20.00 -2.00 319.86 0.00e+00 4.890 0.002 302.00 328.00 3 4.5367e+00 1.4317e-02 6.9191e-02 -6.0000e+00 9.0577e-01 4.6591e-01 1.7813e-02 5.9075e-02 -6.0000e+00 9.8429e-01 -5.2571e-01 1.3654e-02 2.9944e-02 -6.0000e+00 5.8558e-01 2.0301e-01 6.8018e-03 8.5406e-03 -6.0000e+00 2.4606e-01 2.2232e-05 -9.0535e-04 2.5714e-04 2.5703e-04 -6.0000e+00 1.9521e-02 1.7115e-02 0.0000e+00 12 8 8 10 0 0 99.97 29.12 1.57 0.01711 0.01031 24 2 1 5 0 2289.960 37.25 20.00 29.12 31.82 3.6 1025.15 -115265 900000 195431 900000 900000 -141898 -102664 -107191 -6667 900000 900000 -59338 36677 231135 -80664 900000 900000 900000 -12614 900000 900000 253478 -16230 132731 -49825 -29385 900000 -67505 -41124 49464 900000 302926 -13850 35252 91578 73057 123317 -21871 91942 39800 46722 21010 57299 39017 -10810 -4059 -5023 12276 32190 27775 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-4937 -886 2134 -4662 2259 -7248 -6969 -3556 -5179 -607 440 -2738 -2004 -7559 -4249 -4760 4130 -2089 5623 1531 -2936 3021 287 12205 -2819 2050 -6 -512 2040 7103 -1826 2 2642 4449 4495 1361 303 3504 2135 100 3744 -1079 -1801 -963 111 1665 -4216 -1726 -3227 -4138 1776 SS 20250913T130759.1Z 9387.547212 237 1 41.65 2 77.44 93.77 24.99 264.60 0.00 1 0.00 1 0 17 2.892e-01 1.540e-02 8.147e-02 3.625e-03 5.412184e-01 2.026805e-03 6.163930e-03 -6.000000e+00 1.810184e-01 228.98 -2.00 3.31 -2.00 320.08 0.00e+00 5.027529e-03 7.328579e-04 2.151234e-03 -6.000000e+00 9.768179e-03 291.83 -2.00 20.00 -2.00 319.30 0.00e+00 4.469 0.001 302.00 328.00 3 3.7691e+00 6.1254e-03 5.1683e-02 -6.0000e+00 4.5130e-01 7.8142e-02 7.6139e-03 2.8357e-02 -6.0000e+00 4.8862e-01 -8.4167e-02 6.3377e-03 1.5993e-02 -6.0000e+00 2.9063e-01 2.2576e-02 3.2100e-03 5.9795e-03 -6.0000e+00 1.2318e-01 8.3137e-05 -5.1777e-04 1.1589e-04 8.3637e-05 -6.0000e+00 9.7479e-03 1.1782e-02 0.0000e+00 12 9 9 12 33 1 93.76 29.08 0.68 0.01178 0.00789 24 3 1 5 0 1665.780 37.25 20.01 29.08 31.86 3.6 1024.46 -113035 900000 9153 900000 900000 -138754 -79832 -94393 -54493 900000 900000 -75732 28665 8781 -74173 35193 26324 900000 -23321 900000 39652 49935 -18028 37568 -39876 -33873 34904 -50861 -32320 1775 161748 32673 -7276 -7369 3140 9927 21267 16344 16778 -1630 1405 583 5735 7208 -6359 -8703 -10004 -371 9039 1706 8786 -1548 3254 3295 7005 1413 -4301 7766 -2568 15363 4249 2215 4039 -373 -1796 2810 2848 4391 3404 -336 1482 -421 -2374 -2748 -265 1320 -4028 2101 -260 4621 -1844 -1060 -2788 -3129 -7 1407 489 487 -970 -1378 3300 -1135 237 1852 2444 -1308 1094 -1337 -1821 -1358 -1242 -105 382 -511 -776 -3360 -684 -1290 1077 -531 1125 -114 -406 405 473 1938 -141 880 163 -65 -284 1579 -171 -579 747 1039 936 730 503 162 324 -488 402 -116 -382 -145 -146 585 -344 -200 -304 -978 268 -2104 900000 62 900000 900000 -3918 -1307 -1969 -839 900000 900000 -2085 334 155 -3666 683 632 900000 -1087 900000 1078 1252 -916 1154 -2829 -2356 1232 -4237 -2270 94 1941 1649 -616 -663 258 774 1599 1500 1824 -248 233 106 1041 1333 -1255 -1796 -2135 -81 1863 400 1889 -405 887 963 2082 462 -1523 2445 -888 4442 1421 818 1620 -171 -878 1310 1303 2008 1691 -177 842 -257 -1482 -1658 -145 711 -2130 1033 -140 2483 -1219 -787 -2135 -2581 -6 1260 466 480 -975 -1354 2932 -986 193 1486 2092 -1310 1133 -1599 -2219 -1683 -1584 -123 413 -548 -873 -4121 -864 -1630 1434 -787 1673 -181 -653 627 696 2856 -210 1334 246 -103 -458 2466 -263 -865 1127 1501 1314 1037 771 258 562 -859 736 -224 -742 -296 -309 1192 -712 -428 -622 -1919 501 SS 20250913T131308.7Z 9387.550795 240 1 54.43 2 76.35 94.48 26.04 265.48 0.00 1 0.00 1 0 25 1.224e-01 8.088e-03 1.502e-02 1.055e-03 5.056590e-01 5.691277e-04 5.570251e-03 -6.000000e+00 7.592819e-02 228.97 -2.00 3.31 -2.00 319.29 0.00e+00 2.369086e-03 1.592221e-04 3.652367e-04 -6.000000e+00 3.566950e-03 291.83 -2.00 20.00 -2.00 318.45 0.00e+00 4.137 0.001 302.00 328.00 3 2.2065e+00 1.6160e-03 4.7511e-02 -6.0000e+00 1.8839e-01 2.6185e-02 1.9067e-03 2.5004e-02 -6.0000e+00 2.0313e-01 -5.7597e-02 1.4178e-03 1.2490e-02 -6.0000e+00 1.2162e-01 1.3319e-02 7.3869e-04 4.3478e-03 -6.0000e+00 5.1409e-02 5.8135e-04 -1.9079e-04 3.2731e-05 5.2246e-05 -6.0000e+00 4.0619e-03 1.1175e-02 0.0000e+00 11 8 0 10 0 0 12.55 29.09 0.51 0.01118 0.00974 210 22 1 5 0 259.150 37.25 20.01 29.09 31.87 3.6 1024.95 -61979 -24293 -38992 -41845 10767 -63373 -50429 -43161 -30817 -16766 3485 -32351 -15368 -17188 -20497 -1590 5217 8075 -9416 13243 2304 973 -5150 -819 -4913 -8458 -5056 -13079 -4547 876 5818 4162 -898 -1957 -357 2318 2990 -1514 2099 -889 -2713 -718 359 140 -273 -1134 -2616 519 1175 1263 707 948 1947 1367 998 907 -654 448 257 2854 2116 2040 1946 574 -27 1243 1856 1700 1987 838 -114 -460 -981 -941 -416 318 286 658 762 309 -1235 -1751 -2027 -1265 -727 -710 -375 -219 -557 -607 796 1195 741 1606 1620 459 332 -248 -1165 -1101 -708 -528 349 806 -556 -1497 -938 -750 -255 58 -152 -344 -390 164 411 1305 1196 873 265 -247 -675 -38 -106 -66 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