File name: Pandora259s1_TylerTX_20251130_L2Fit_fout2c3d20230310p1-8.txt File generation date: 20251201T062423.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: James Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 259 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora259_OF_v4d20221229.txt Instrument calibration file used: Pandora259s1_CF_v3d20230310.txt Level 1 file used: Pandora259s1_TylerTX_20251130_L1_smca1c3d20230310p1-8.txt Full location name: Tyler Pounds Regional Airport Short location name: TylerTX Country of location: United States Location latitude [deg]: 32.3440 Location longitude [deg]: -95.4159 Location altitude [m]: 164 Local noon date: 20251130 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 195 337 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1851 305.3256 305.4661 305.6066 305.7470 305.8875 306.0279 306.1684 306.3088 306.4492 306.5896 306.7300 306.8704 307.0108 307.1511 307.2915 307.4318 307.5721 307.7125 307.8528 307.9930 308.1333 308.2736 308.4139 308.5541 308.6943 308.8346 308.9748 309.1150 309.2552 309.3954 309.5355 309.6757 309.8158 309.9560 310.0961 310.2362 310.3763 310.5164 310.6565 310.7966 310.9366 311.0767 311.2167 311.3567 311.4967 311.6367 311.7767 311.9167 312.0567 312.1966 312.3366 312.4765 312.6164 312.7563 312.8962 313.0361 313.1760 313.3159 313.4557 313.5955 313.7354 313.8752 314.0150 314.1548 314.2946 314.4344 314.5741 314.7139 314.8536 314.9934 315.1331 315.2728 315.4125 315.5522 315.6918 315.8315 315.9711 316.1108 316.2504 316.3900 316.5296 316.6692 316.8088 316.9484 317.0879 317.2275 317.3670 317.5065 317.6460 317.7855 317.9250 318.0645 318.2040 318.3434 318.4829 318.6223 318.7617 318.9011 319.0405 319.1799 319.3193 319.4587 319.5980 319.7373 319.8767 320.0160 320.1553 320.2946 320.4339 320.5731 320.7124 320.8516 320.9909 321.1301 321.2693 321.4085 321.5477 321.6869 321.8261 321.9652 322.1044 322.2435 322.3826 322.5217 322.6608 322.7999 322.9390 323.0780 323.2171 323.3561 323.4952 323.6342 323.7732 323.9122 324.0512 324.1901 324.3291 324.4680 324.6070 324.7459 324.8848 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251130T140806.9Z 9465.588969 133 1 35.19 2 79.21 124.54 143.35 0.19 0.00 1 0.00 1 0 25 4.741e-01 1.322e-02 1.767e-01 3.567e-03 5.720585e-01 1.935808e-03 6.287418e-03 -6.000000e+00 2.889529e-01 224.35 -2.00 3.31 -2.00 320.19 0.00e+00 7.510388e-03 7.287762e-04 7.511709e-04 -6.000000e+00 1.421136e-02 284.68 -2.00 20.00 -2.00 319.54 0.00e+00 5.142 0.002 302.00 328.00 3 2.9320e+00 5.8277e-03 5.7400e-02 -6.0000e+00 7.1062e-01 1.5136e-01 7.2589e-03 2.8540e-02 -6.0000e+00 7.7072e-01 -1.0320e-01 6.4321e-03 1.7173e-02 -6.0000e+00 4.6038e-01 2.5517e-02 3.2462e-03 1.0221e-02 -6.0000e+00 1.9469e-01 9.6440e-05 -1.0975e-05 1.1113e-04 1.1070e-04 -6.0000e+00 1.5822e-02 3.1357e-02 0.0000e+00 12 9 9 12 1 1 99.96 24.06 0.65 0.03136 0.03127 29 5 1 5 0 1172.920 33.25 20.21 24.06 8.76 3.9 856.20 -147650 179981 -4000 -57250 900000 -125523 -85732 -110394 -46119 318930 900000 -77974 37820 31826 -59885 25957 173711 176437 -737 150787 35122 12265 -25099 3524 -22546 1471 -12360 -43711 -19081 4614 30531 15758 -6200 -5578 1725 1439 8842 -12543 21083 7036 -2927 -609 -1692 1559 -5687 -11197 -3800 3118 12058 2974 1827 -917 249 3282 2059 1721 -3073 5272 -586 11705 4506 2542 2583 -907 1006 1854 3853 3107 3515 -585 -275 -1033 -2095 -2243 -1609 1276 -2219 1778 3267 6372 -1160 -979 -2921 -2119 -71 106 -1264 -694 -916 -1593 2909 1312 421 2663 2398 -773 912 -1184 -1472 -860 -265 1 1509 570 -1362 -2583 -573 -1493 709 -551 63 -652 -749 572 254 2199 888 1189 -1 -501 -758 394 -202 -680 1175 976 1081 1608 899 -108 56 -314 -56 268 -109 -301 -177 480 -779 -316 -303 -68 128 -3221 626 -25 -615 900000 -2540 -1342 -2419 -577 1109 900000 -1817 342 387 -2249 487 846 920 -24 1154 879 392 -1196 132 -1160 61 -597 -2919 -1029 213 1253 877 -483 -456 133 113 704 -1444 2053 910 -466 -102 -304 281 -1133 -2422 -785 621 2298 662 449 -232 68 928 619 537 -1023 1612 -188 3338 1444 909 1028 -410 466 850 1713 1430 1752 -311 -158 -625 -1275 -1304 -860 661 -1120 869 1723 3444 -781 -742 -2281 -1758 -61 97 -1236 -694 -917 -1555 2563 1101 342 2154 2123 -804 991 -1480 -1859 -1090 -318 1 1636 620 -1584 -3224 -694 -1948 983 -799 99 -1084 -1179 914 386 3150 1284 1775 -1 -835 -1274 640 -319 -1043 1698 1452 1567 2379 1370 -174 99 -589 -103 525 -216 -627 -380 1041 -1713 -673 -615 -137 251 SS 20251130T142219.2Z 9465.598834 142 1 3.08 2 76.77 126.81 143.14 5.83 0.00 1 0.00 1 0 25 1.458e-01 1.203e-02 1.048e-01 7.301e-03 4.825005e-01 3.852002e-03 5.390402e-03 -6.000000e+00 8.850624e-02 224.35 -2.00 3.31 -2.00 319.15 0.00e+00 2.661472e-03 1.018127e-03 1.998190e-04 -6.000000e+00 4.120649e-03 284.68 -2.00 20.00 -2.00 318.42 0.00e+00 4.261 0.001 302.00 328.00 3 2.8179e+00 1.0703e-02 4.7688e-02 -6.0000e+00 2.1775e-01 9.1170e-02 1.2496e-02 2.3659e-02 -6.0000e+00 2.3627e-01 -7.8703e-02 9.2241e-03 1.1696e-02 -6.0000e+00 1.4134e-01 2.5660e-02 4.8061e-03 4.0025e-03 -6.0000e+00 5.9469e-02 2.8109e-04 -2.1174e-03 2.2896e-04 4.9587e-05 -6.0000e+00 4.8365e-03 4.7416e-02 0.0000e+00 12 9 9 12 5 1 81.17 24.02 0.35 0.04742 0.03150 3 7 1 5 0 767.500 33.25 20.21 24.02 9.03 4.0 858.49 -59615 65926 -23244 -39364 58027 -86618 -13126 -28584 -46960 -14965 -26082 -31585 283 -17841 -23922 11559 13479 24628 4061 3393 2003 3949 -8154 -5217 -6197 -9634 -7707 -3713 -881 3092 -5113 9720 -12051 1054 -125 1217 7465 -3008 13720 6944 -850 -1655 -4139 -1477 -828 64 -2800 1245 6574 1847 191 -299 3100 2788 -90 380 -534 1003 1163 3097 3507 2510 2310 -636 95 524 1772 2424 1988 -1472 -343 -1504 -889 -762 225 -39 -561 717 2276 833 -2126 -2933 -1525 -1773 428 -1663 -851 -875 -998 606 957 1664 711 2505 1325 373 650 -614 -2096 -871 271 -1248 911 1541 223 -1856 -1926 -1247 707 -118 44 -240 -802 425 -111 1520 1656 1613 -157 -985 311 -386 457 256 304 174 1053 529 863 -219 476 -483 360 364 461 -224 -345 339 -732 -742 -108 -403 136 -1995 704 -629 -1233 661 -4132 -318 -895 -1939 -479 -1003 -1439 11 -1016 -1720 667 844 1490 321 283 174 343 -824 -542 -693 -1152 -905 -415 -96 339 -674 1253 -1934 170 -21 201 1265 -602 2753 1721 -253 -533 -1309 -466 -264 21 -932 404 2268 643 73 -125 1357 1305 -42 183 -264 488 559 1462 1711 1338 1355 -385 59 318 1038 1434 1275 -1086 -255 -1178 -691 -567 165 -26 -353 442 1486 627 -1758 -2568 -1436 -1683 424 -1787 -901 -954 -1090 667 990 1594 694 2413 1308 394 775 -784 -2768 -1145 353 -1525 1081 1817 265 -2398 -2499 -1708 973 -178 69 -389 -1304 655 -171 2187 2362 2381 -238 -1572 497 -611 696 394 450 246 1511 775 1293 -347 775 -839 620 660 847 -436 -667 664 -1454 -1438 -207 -740 252 SS 20251130T143256.6Z 9465.606210 145 1 7.54 2 75.00 128.58 142.79 9.98 0.00 1 0.00 1 0 25 4.383e-02 8.349e-03 8.762e-03 1.387e-03 4.405653e-01 7.310651e-04 4.901522e-03 -6.000000e+00 2.666034e-02 224.35 -2.00 3.31 -2.00 318.32 0.00e+00 8.847411e-04 1.498731e-04 1.397505e-04 -6.000000e+00 1.239678e-03 284.68 -2.00 20.00 -2.00 317.56 0.00e+00 3.788 0.001 302.00 328.00 3 1.2853e+00 1.9671e-03 4.2561e-02 -6.0000e+00 6.5593e-02 5.8137e-02 2.2453e-03 2.1195e-02 -6.0000e+00 7.1113e-02 -4.8700e-02 1.4794e-03 1.0465e-02 -6.0000e+00 4.2544e-02 1.3690e-02 7.6261e-04 3.1877e-03 -6.0000e+00 1.7950e-02 2.1557e-03 2.1061e-04 4.3887e-05 4.1226e-05 -6.0000e+00 1.4531e-03 3.1476e-02 0.0000e+00 12 9 1 12 5 1 92.58 24.00 0.41 0.03148 0.03306 63 47 1 5 0 117.610 33.25 20.30 24.00 9.28 3.9 859.69 -22277 -14272 -15340 -17749 -8723 -15833 -16579 -12665 -12114 -9102 -10008 -7084 -4226 -6261 -3476 -1463 643 -1509 306 1010 593 1053 -333 -805 -968 -1446 -3028 -1987 1138 2257 1267 479 -1025 -2155 -152 2435 2180 1123 1219 -1318 -2322 -616 -825 -404 -60 -735 -287 352 1182 1660 1375 1223 1456 1297 86 1183 32 347 1080 1829 2341 2349 1194 -331 -897 654 971 1146 2182 1078 -702 -1178 -1113 -931 -542 244 943 784 929 -344 -1202 -1709 -2211 -1235 -803 -1141 -443 -489 -731 -585 176 878 862 1837 1509 710 434 -183 -1279 -1030 -499 -322 1048 1092 -831 -1301 -607 -583 -92 292 -348 -538 -432 297 520 1491 1601 896 97 -544 -804 -259 -65 75 670 657 691 1691 833 -17 124 -246 -112 264 -119 -377 -38 179 -460 -200 -63 -458 -232 -1046 -685 -768 -893 -386 -743 -834 -684 -716 -558 -661 -503 -339 -612 -351 -164 77 -199 42 143 87 157 -52 -134 -173 -269 -571 -364 201 406 251 98 -233 -515 -36 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