File name: Pandora218s1_Vientiane_20250827_L2Fit_fout2c3d20230614p1-8.txt File generation date: 20250827T172206.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Virasith Phomsouvanh Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 218 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora218_OF_v3d20220124.txt Instrument calibration file used: Pandora218s1_CF_v3d20230614.txt Level 1 file used: Pandora218s1_Vientiane_20250827_L1_smca1c3d20230614p1-8.txt Full location name: Laos Ministry of Natural Resources and Environment Short location name: Vientiane Country of location: Lao People's Democratic Republic Location latitude [deg]: 17.9979 Location longitude [deg]: 102.5821 Location altitude [m]: 169 Local noon date: 20250827 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 201 342 Nominal wavelengths inside fitting window [nm]: 305.0591 305.2004 305.3416 305.4829 305.6241 305.7654 305.9066 306.0478 306.1890 306.3302 306.4714 306.6125 306.7537 306.8949 307.0360 307.1771 307.3182 307.4593 307.6004 307.7415 307.8826 308.0236 308.1647 308.3057 308.4467 308.5877 308.7287 308.8697 309.0107 309.1517 309.2926 309.4336 309.5745 309.7154 309.8564 309.9973 310.1381 310.2790 310.4199 310.5607 310.7016 310.8424 310.9832 311.1241 311.2649 311.4056 311.5464 311.6872 311.8279 311.9687 312.1094 312.2501 312.3908 312.5315 312.6722 312.8129 312.9536 313.0942 313.2349 313.3755 313.5161 313.6567 313.7973 313.9379 314.0785 314.2190 314.3596 314.5001 314.6407 314.7812 314.9217 315.0622 315.2026 315.3431 315.4836 315.6240 315.7645 315.9049 316.0453 316.1857 316.3261 316.4665 316.6068 316.7472 316.8875 317.0279 317.1682 317.3085 317.4488 317.5891 317.7294 317.8696 318.0099 318.1501 318.2904 318.4306 318.5708 318.7110 318.8512 318.9913 319.1315 319.2716 319.4118 319.5519 319.6920 319.8321 319.9722 320.1123 320.2524 320.3924 320.5325 320.6725 320.8125 320.9525 321.0925 321.2325 321.3725 321.5125 321.6524 321.7924 321.9323 322.0722 322.2121 322.3520 322.4919 322.6318 322.7716 322.9115 323.0513 323.1911 323.3310 323.4708 323.6106 323.7503 323.8901 324.0299 324.1696 324.3093 324.4491 324.5888 324.7285 324.8682 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250827T015901.7Z 9370.082658 148 1 31.72 2 47.18 92.97 91.89 99.78 0.00 1 0.00 1 0 17 7.997e-03 6.256e-03 6.048e-04 3.876e-04 1.791284e-01 2.086600e-04 1.954390e-03 -6.000000e+00 4.845950e-03 227.26 -2.00 3.11 -2.00 315.24 0.00e+00 3.059992e-04 1.978608e-05 6.112225e-05 -6.000000e+00 2.247286e-04 294.31 -2.00 20.00 -2.00 314.47 0.00e+00 1.469 0.000 302.00 328.00 3 2.1801e+00 5.3378e-04 1.6451e-02 -6.0000e+00 1.1964e-02 5.7943e-03 5.9109e-04 8.1919e-03 -6.0000e+00 1.2905e-02 -1.6201e-03 3.3968e-04 4.0056e-03 -6.0000e+00 7.7495e-03 -2.1858e-03 1.5250e-04 1.1232e-03 -6.0000e+00 3.3335e-03 1.2020e-02 -1.4298e-04 1.2253e-05 1.7059e-05 -6.0000e+00 2.4856e-04 4.5676e-03 0.0000e+00 12 1 1 12 1 1 99.97 23.69 0.28 0.00457 0.00349 302 101 1 5 0 104.670 26.00 20.00 23.69 33.68 15.4 978.55 258 -644 -1271 -2588 -2192 -1266 -462 935 493 -836 -1274 -582 119 177 774 -166 126 349 827 1001 984 724 1223 892 678 826 -529 -672 91 983 1276 1112 1030 -1326 -2298 -1545 -1501 -665 228 -635 -992 -634 -693 -786 -429 -383 -837 -438 -479 176 757 578 951 900 532 817 965 238 595 733 1221 1572 1356 1144 -127 -203 -323 -141 1041 749 231 135 -3 148 49 -506 -603 -810 -317 -782 -1262 -1503 -2125 -1375 -933 -554 20 258 188 185 410 91 37 511 547 338 551 524 45 -382 -557 -913 -519 -23 -798 -898 -726 -516 25 466 440 280 241 35 310 251 502 337 388 32 -37 308 307 343 784 427 302 880 373 211 -48 -447 -74 -35 25 -190 14 8 -274 -152 -334 -659 77 -190 -379 -799 -613 -335 -126 276 159 -283 -433 -200 41 67 322 -75 59 153 370 458 456 336 574 437 346 430 -274 -329 45 469 624 574 515 -680 -1237 -824 -803 -409 152 -452 -766 -509 -532 -607 -351 -310 -661 -333 -355 130 577 465 801 738 449 698 830 205 506 625 1076 1472 1276 1113 -122 -192 -284 -122 948 711 237 143 -3 150 46 -461 -536 -696 -284 -728 -1228 -1593 -2270 -1540 -1054 -665 25 313 238 223 481 98 39 526 593 378 641 659 56 -486 -665 -1084 -603 -28 -989 -1175 -943 -697 34 652 633 398 325 46 394 306 616 437 510 45 -52 430 415 443 1007 523 379 1119 476 284 -63 -605 -103 -51 37 -286 21 11 -411 -233 -497 -960 SS 20250827T020356.2Z 9370.086068 151 1 49.49 2 46.02 93.41 90.78 100.17 0.00 1 0.00 1 0 17 7.824e-03 6.023e-03 9.050e-04 5.221e-04 1.756780e-01 2.796419e-04 1.914178e-03 -6.000000e+00 4.740947e-03 227.26 -2.00 3.11 -2.00 315.64 0.00e+00 3.124718e-04 2.884706e-05 8.035546e-05 -6.000000e+00 2.198614e-04 294.31 -2.00 20.00 -2.00 314.83 0.00e+00 1.438 0.000 302.00 328.00 3 3.0823e+00 7.1921e-04 1.6115e-02 -6.0000e+00 1.1705e-02 1.4586e-02 8.0057e-04 8.0396e-03 -6.0000e+00 1.2626e-02 5.0647e-04 4.5929e-04 3.9323e-03 -6.0000e+00 7.5816e-03 -4.0764e-03 2.0826e-04 1.1035e-03 -6.0000e+00 3.2612e-03 5.0383e-03 -1.3061e-04 1.6589e-05 1.6244e-05 -6.0000e+00 2.4318e-04 4.7139e-03 0.0000e+00 10 0 0 10 0 0 99.99 23.70 0.33 0.00471 0.00373 484 103 1 5 0 102.230 26.00 19.99 23.70 34.05 15.4 982.02 44 -492 -1517 -2446 -2003 -1220 -107 852 754 -786 -1048 -511 60 255 609 -216 59 364 643 1092 607 559 1157 651 394 819 -354 -780 157 789 1319 1011 1093 -1285 -2442 -1468 -1506 -718 190 -459 -1196 -726 -694 -883 -508 -484 -894 -528 -387 97 791 592 1068 814 576 920 846 416 602 752 1136 1549 1331 1147 -5 -282 -454 -233 1057 792 326 184 70 175 -10 -538 -623 -834 -506 -777 -1191 -1515 -2093 -1331 -863 -469 85 271 209 231 523 -34 6 426 468 325 566 426 -33 -303 -582 -881 -598 22 -852 -838 -666 -521 128 482 432 269 339 -45 162 224 363 383 314 70 11 283 266 326 686 382 238 830 366 134 -32 -513 -132 0 161 -152 50 45 -254 -135 -313 -573 11 -124 -385 -645 -478 -276 -25 215 207 -228 -303 -150 19 89 214 -82 23 145 263 455 257 237 495 291 184 388 -166 -348 65 347 593 437 494 -596 -1099 -653 -728 -399 123 -311 -883 -556 -543 -695 -396 -373 -673 -382 -273 68 573 452 852 676 491 794 736 361 516 648 1012 1352 1238 1102 -5 -247 -401 -203 967 740 330 193 73 175 -9 -492 -520 -672 -426 -724 -1136 -1574 -2319 -1436 -990 -571 109 351 269 283 590 -38 6 428 495 377 667 542 -44 -389 -703 -1001 -718 26 -1068 -1107 -857 -699 179 702 646 398 474 -62 207 274 449 498 438 96 16 389 355 445 886 471 284 1004 469 180 -44 -733 -180 0 240 -237 80 69 -386 -214 -481 -862 SS 20250827T020851.0Z 9370.089479 154 1 49.38 2 44.85 93.87 89.67 100.56 0.00 1 0.00 1 0 17 7.853e-03 6.185e-03 7.229e-04 4.711e-04 1.728858e-01 2.529680e-04 1.885423e-03 -6.000000e+00 4.758701e-03 227.26 -2.00 3.11 -2.00 315.15 0.00e+00 3.215592e-04 2.344404e-05 5.644181e-05 -6.000000e+00 2.206797e-04 294.31 -2.00 20.00 -2.00 314.38 0.00e+00 1.409 0.000 302.00 328.00 3 3.0467e+00 6.4683e-04 1.5799e-02 -6.0000e+00 1.1749e-02 1.9632e-02 7.1698e-04 7.8959e-03 -6.0000e+00 1.2673e-02 -1.7507e-03 4.1105e-04 3.8610e-03 -6.0000e+00 7.6099e-03 -2.5646e-03 1.8382e-04 1.0850e-03 -6.0000e+00 3.2735e-03 5.3913e-03 -1.3578e-04 1.4822e-05 1.6258e-05 -6.0000e+00 2.4408e-04 4.3945e-03 0.0000e+00 10 0 0 10 0 0 99.96 23.70 0.29 0.00439 0.00337 244 52 1 5 0 202.360 26.00 20.00 23.70 34.49 15.4 984.53 326 -741 -1185 -2682 -1975 -1175 -58 1098 369 -906 -1457 -356 5 272 674 -142 311 288 857 926 890 558 1121 626 584 885 -442 -653 101 921 1100 1264 983 -1387 -2276 -1441 -1421 -622 294 -710 -1005 -808 -644 -866 -519 -404 -819 -444 -469 111 717 619 871 831 595 767 991 348 784 834 1240 1514 1377 1085 -42 -114 -411 -102 918 837 228 155 -30 159 -49 -462 -625 -856 -369 -790 -1239 -1415 -2036 -1327 -903 -470 11 291 161 174 333 152 -21 523 466 349 591 485 18 -348 -529 -925 -515 12 -889 -841 -671 -508 75 489 366 169 246 53 282 289 525 290 321 74 45 305 249 293 742 468 330 922 343 163 -36 -433 -107 -44 54 -143 37 2 -229 -209 -339 -653 98 -241 -387 -833 -553 -311 -16 324 119 -307 -495 -122 2 111 277 -63 142 134 409 451 439 276 560 326 316 488 -242 -338 49 427 523 632 516 -745 -1183 -741 -793 -369 203 -521 -799 -624 -506 -686 -407 -313 -663 -346 -355 83 557 508 698 691 508 663 861 303 671 718 1103 1431 1299 1058 -40 -107 -362 -88 837 791 233 164 -32 161 -50 -420 -557 -736 -330 -731 -1271 -1479 -2272 -1462 -1058 -552 14 364 200 206 385 169 -22 528 496 381 708 593 23 -429 -649 -1070 -583 14 -1134 -1068 -889 -664 102 693 533 243 334 71 366 358 657 362 428 98 62 432 341 384 971 584 399 1129 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