File name: Pandora255s1_VirginiaBeachVA-CBBT_20251010_L2Fit_fout2c3d20240302p1-8.txt File generation date: 20251011T050302.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Anderson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 255 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora255_OF_v2d20221206.txt Instrument calibration file used: Pandora255s1_CF_v3d20240302.txt Level 1 file used: Pandora255s1_VirginiaBeachVA-CBBT_20251010_L1_smca1c3d20240302p1-8.txt Full location name: Chesapeake Bay Bridge Tunnel Virginia Short location name: VirginiaBeachVA-CBBT Country of location: United States Location latitude [deg]: 37.0367 Location longitude [deg]: -76.0766 Location altitude [m]: 20 Local noon date: 20251010 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 195 336 Nominal wavelengths inside fitting window [nm]: 305.1318 305.2728 305.4137 305.5546 305.6955 305.8364 305.9773 306.1182 306.2590 306.3999 306.5407 306.6815 306.8224 306.9632 307.1040 307.2447 307.3855 307.5263 307.6670 307.8078 307.9485 308.0892 308.2299 308.3706 308.5113 308.6520 308.7926 308.9333 309.0739 309.2146 309.3552 309.4958 309.6364 309.7770 309.9175 310.0581 310.1986 310.3392 310.4797 310.6202 310.7607 310.9012 311.0417 311.1822 311.3227 311.4631 311.6035 311.7440 311.8844 312.0248 312.1652 312.3056 312.4459 312.5863 312.7267 312.8670 313.0073 313.1476 313.2880 313.4282 313.5685 313.7088 313.8491 313.9893 314.1296 314.2698 314.4100 314.5502 314.6904 314.8306 314.9707 315.1109 315.2511 315.3912 315.5313 315.6714 315.8115 315.9516 316.0917 316.2318 316.3718 316.5119 316.6519 316.7920 316.9320 317.0720 317.2120 317.3519 317.4919 317.6319 317.7718 317.9117 318.0517 318.1916 318.3315 318.4714 318.6113 318.7511 318.8910 319.0308 319.1706 319.3105 319.4503 319.5901 319.7299 319.8696 320.0094 320.1492 320.2889 320.4286 320.5684 320.7081 320.8478 320.9874 321.1271 321.2668 321.4064 321.5461 321.6857 321.8253 321.9649 322.1045 322.2441 322.3837 322.5232 322.6628 322.8023 322.9418 323.0813 323.2208 323.3603 323.4998 323.6393 323.7787 323.9182 324.0576 324.1970 324.3364 324.4758 324.6152 324.7546 324.8940 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251010T121010.8Z 9414.507070 272 1 41.21 2 78.71 107.64 55.94 278.16 0.00 1 0.00 1 0 17 2.171e-01 7.589e-03 6.332e-02 2.073e-03 6.101679e-01 1.085388e-03 6.823112e-03 -6.000000e+00 1.264419e-01 227.02 -2.00 3.43 -2.00 320.06 0.00e+00 -1.197495e-04 3.845735e-04 3.944834e-04 -6.000000e+00 5.742708e-03 287.55 -2.00 20.00 -2.00 319.34 0.00e+00 4.933 0.002 302.00 328.00 3 2.3203e+00 3.2294e-03 5.8012e-02 -6.0000e+00 3.1293e-01 4.0758e-02 4.0236e-03 3.1156e-02 -6.0000e+00 3.3989e-01 -5.5239e-02 3.6051e-03 1.5449e-02 -6.0000e+00 2.0239e-01 2.0768e-02 1.8415e-03 4.3856e-03 -6.0000e+00 8.6113e-02 2.0507e-04 -2.1720e-04 5.7427e-05 4.9627e-05 -6.0000e+00 6.2397e-03 5.6555e-02 0.0000e+00 12 9 1 12 1 1 99.93 25.32 0.36 0.05656 0.05492 69 9 1 5 0 588.600 33.50 20.00 25.32 22.60 5.2 1040.78 -31697 -73041 -68407 -137262 -35752 900000 -104249 -17298 -23288 -26480 -32026 -63374 -57936 -43618 30470 -21690 17809 -16460 -4419 60105 -11547 -11609 6845 -19205 -23089 -23632 14807 -15244 -10746 -16091 3006 11319 -6242 -8232 -10154 20957 -1110 -6510 -1979 3119 -5096 3135 -540 -3166 4043 7285 -1103 1432 2945 3743 4350 -1076 504 503 -683 2998 -358 1357 1313 995 818 2112 1429 889 1043 133 718 2245 578 232 802 1549 -115 -417 20 -1475 -562 -451 -296 -591 -1464 -1369 -1919 -1527 -398 1020 -121 296 506 -47 684 188 868 144 -50 1053 -37 -853 -789 -150 -423 546 -80 -1129 -1199 -729 -335 -906 375 65 -205 168 199 364 711 472 546 -204 -165 -230 -232 288 457 395 166 472 893 774 394 -48 -210 -213 63 -81 -300 9 310 -275 -131 -382 86 -187 -211 -797 -705 -2635 -246 900000 -1791 -143 -226 -284 -408 -1358 -1487 -1208 480 -653 400 -566 -143 1057 -422 -448 242 -970 -1297 -1366 569 -776 -554 -1015 186 743 -526 -695 -872 1449 -114 -872 -305 473 -908 541 -99 -606 733 1304 -221 292 632 882 1141 -328 165 161 -232 1017 -126 458 437 342 308 887 675 444 512 65 357 1118 336 150 501 956 -74 -247 10 -740 -281 -249 -192 -416 -1106 -1135 -1705 -1355 -373 992 -122 298 492 -43 618 164 769 134 -50 1206 -47 -1099 -1019 -191 -489 612 -91 -1309 -1475 -943 -436 -1232 560 102 -325 266 316 546 1068 713 820 -328 -262 -366 -375 446 681 594 240 661 1295 1193 652 -84 -388 -395 124 -163 -612 19 654 -582 -277 -765 168 -358 SS 20251010T133734.5Z 9414.567760 303 1 2.81 2 63.01 123.55 72.19 289.05 0.00 1 0.00 1 0 17 8.825e-03 5.735e-03 2.032e-03 1.039e-03 2.850948e-01 5.341363e-04 3.370201e-03 -6.000000e+00 5.103508e-03 227.01 -2.00 3.43 -2.00 316.20 0.00e+00 2.084699e-04 6.038012e-05 5.095794e-05 -6.000000e+00 2.324135e-04 287.54 -2.00 20.00 -2.00 315.42 0.00e+00 2.191 0.000 302.00 328.00 3 1.4548e+00 1.3823e-03 2.6079e-02 -6.0000e+00 1.2631e-02 1.5264e-03 1.5480e-03 1.4239e-02 -6.0000e+00 1.3712e-02 -2.6506e-03 8.9348e-04 6.9854e-03 -6.0000e+00 8.1967e-03 1.6850e-04 4.1530e-04 1.9553e-03 -6.0000e+00 3.5017e-03 9.9628e-03 3.6601e-05 3.0231e-05 2.4667e-05 -6.0000e+00 2.5118e-04 5.5394e-02 0.0000e+00 12 1 1 12 1 1 85.07 25.46 0.29 0.05539 0.05567 41 79 1 5 0 66.850 33.50 20.00 25.46 23.83 5.2 1049.50 -1160 -2894 -3242 -3558 -2619 -1343 637 -82 -1019 -1505 -474 -543 -644 568 86 349 1235 376 573 680 354 1583 1069 930 228 -312 -227 326 863 1648 1532 1507 -574 -1714 -833 -829 -485 22 -741 -1090 -817 -687 -923 -504 -264 -629 -787 -641 264 603 645 738 896 405 850 804 307 454 771 1086 1364 1363 1082 224 -290 166 243 890 672 -143 -217 -166 -147 -6 35 79 281 212 -374 -652 -1427 -1625 -1568 -919 -986 -484 -311 -356 -34 190 307 480 904 797 508 348 249 -429 -516 -280 -527 187 328 -587 -930 -564 -557 -75 268 9 120 104 192 502 626 660 382 248 -303 -541 -167 229 282 509 549 623 1115 607 264 32 -102 -84 150 33 -211 -56 75 -368 -393 -230 -234 -344 -248 -602 -694 -691 -479 -254 132 -18 -236 -353 -113 -135 -186 174 28 118 433 139 207 251 131 590 422 390 95 -131 -95 128 331 663 638 680 -260 -789 -372 -379 -245 12 -461 -720 -546 -472 -645 -350 -183 -431 -530 -424 175 420 464 544 672 316 677 631 242 363 610 882 1144 1167 961 202 -254 139 205 767 614 -140 -216 -166 -141 -6 31 67 228 181 -337 -625 -1439 -1714 -1695 -1027 -1153 -580 -375 -431 -41 215 335 507 923 836 576 408 308 -556 -663 -354 -629 214 387 -717 -1182 -731 -739 -102 381 13 176 150 265 666 817 856 507 338 -431 -771 -240 318 384 689 724 802 1436 801 368 45 -149 -123 223 52 -335 -89 121 -596 -633 -363 -362 -523 SS 20251010T134816.4Z 9414.575190 306 1 19.40 2 61.25 125.81 74.11 290.39 0.00 1 0.00 1 0 17 8.365e-03 5.864e-03 6.593e-04 3.619e-04 2.697870e-01 1.861504e-04 3.199188e-03 -6.000000e+00 4.837609e-03 227.01 -2.00 3.43 -2.00 315.97 0.00e+00 1.272353e-04 2.007946e-05 3.825471e-05 -6.000000e+00 2.203017e-04 287.54 -2.00 20.00 -2.00 315.22 0.00e+00 2.069 0.000 302.00 328.00 3 1.4466e+00 4.8065e-04 2.4652e-02 -6.0000e+00 1.1973e-02 1.6729e-03 5.3757e-04 1.3482e-02 -6.0000e+00 1.2997e-02 -1.2645e-03 3.0914e-04 6.6117e-03 -6.0000e+00 7.7696e-03 -5.3048e-04 1.4224e-04 1.8459e-03 -6.0000e+00 3.3193e-03 1.1578e-02 4.8935e-05 1.0540e-05 2.3773e-05 -6.0000e+00 2.3809e-04 5.5328e-02 0.0000e+00 12 1 1 12 1 1 99.26 25.50 0.31 0.05533 0.05570 319 87 1 5 0 60.610 33.50 20.01 25.50 24.09 5.2 1050.94 -2068 -2094 -3284 -3256 -1440 -696 346 -122 -1165 -1568 -692 -299 -117 501 153 -100 709 671 925 706 621 1436 1090 808 271 49 -288 361 1116 1487 1471 1289 -607 -1701 -548 -733 -423 -144 -626 -1131 -853 -728 -844 -440 -395 -710 -515 -566 133 746 526 567 767 443 669 625 324 429 812 1157 1236 1224 840 38 -309 181 323 1058 676 -109 -88 -186 11 -19 33 285 160 409 -284 -984 -1334 -1907 -1500 -984 -1014 -578 -360 -206 -12 194 362 525 1097 900 421 475 317 -244 -501 -336 -441 189 321 -584 -1013 -502 -552 -95 192 112 -51 21 128 279 753 755 468 243 -252 -524 -207 85 244 523 595 587 1252 688 250 101 -104 -16 181 -73 -234 -87 25 -330 -303 -232 -364 -295 -484 -504 -759 -679 -301 -151 77 -31 -291 -395 -177 -85 -36 163 55 -36 264 260 370 289 254 594 452 356 119 21 -127 148 469 619 665 599 -297 -802 -249 -360 -219 -85 -400 -770 -587 -516 -605 -314 -281 -499 -353 -381 90 525 384 424 603 350 540 513 266 346 648 947 1047 1092 777 34 -271 156 271 905 633 -106 -87 -186 11 -18 30 241 134 343 -260 -961 -1364 -2046 -1643 -1116 -1172 -686 -440 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