File name: Pandora255s1_VirginiaBeachVA-CBBT_20251210_L2Fit_fout2c3d20240302p1-8.txt File generation date: 20251211T051451.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Anderson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 255 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora255_OF_v2d20221206.txt Instrument calibration file used: Pandora255s1_CF_v3d20240302.txt Level 1 file used: Pandora255s1_VirginiaBeachVA-CBBT_20251210_L1_smca1c3d20240302p1-8.txt Full location name: Chesapeake Bay Bridge Tunnel Virginia Short location name: VirginiaBeachVA-CBBT Country of location: United States Location latitude [deg]: 37.0367 Location longitude [deg]: -76.0766 Location altitude [m]: 20 Local noon date: 20251210 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 195 336 Nominal wavelengths inside fitting window [nm]: 305.1318 305.2728 305.4137 305.5546 305.6955 305.8364 305.9773 306.1182 306.2590 306.3999 306.5407 306.6815 306.8224 306.9632 307.1040 307.2447 307.3855 307.5263 307.6670 307.8078 307.9485 308.0892 308.2299 308.3706 308.5113 308.6520 308.7926 308.9333 309.0739 309.2146 309.3552 309.4958 309.6364 309.7770 309.9175 310.0581 310.1986 310.3392 310.4797 310.6202 310.7607 310.9012 311.0417 311.1822 311.3227 311.4631 311.6035 311.7440 311.8844 312.0248 312.1652 312.3056 312.4459 312.5863 312.7267 312.8670 313.0073 313.1476 313.2880 313.4282 313.5685 313.7088 313.8491 313.9893 314.1296 314.2698 314.4100 314.5502 314.6904 314.8306 314.9707 315.1109 315.2511 315.3912 315.5313 315.6714 315.8115 315.9516 316.0917 316.2318 316.3718 316.5119 316.6519 316.7920 316.9320 317.0720 317.2120 317.3519 317.4919 317.6319 317.7718 317.9117 318.0517 318.1916 318.3315 318.4714 318.6113 318.7511 318.8910 319.0308 319.1706 319.3105 319.4503 319.5901 319.7299 319.8696 320.0094 320.1492 320.2889 320.4286 320.5684 320.7081 320.8478 320.9874 321.1271 321.2668 321.4064 321.5461 321.6857 321.8253 321.9649 322.1045 322.2441 322.3837 322.5232 322.6628 322.8023 322.9418 323.0813 323.2208 323.3603 323.4998 323.6393 323.7787 323.9182 324.0576 324.1970 324.3364 324.4758 324.6152 324.7546 324.8940 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251210T130044.2Z 9475.542178 285 1 35.84 2 81.82 127.02 47.28 247.67 0.00 1 0.00 1 0 17 6.701e-01 3.031e-02 2.521e-01 5.827e-03 8.576107e-01 3.225965e-03 1.035297e-02 -6.000000e+00 3.877575e-01 223.61 -2.00 3.43 -2.00 321.36 0.00e+00 -1.775148e-03 1.594576e-03 8.626115e-03 -6.000000e+00 1.830444e-02 280.90 -2.00 20.00 -2.00 320.84 0.00e+00 6.593 0.005 302.00 328.00 3 2.0380e+00 1.1032e-02 9.1366e-02 -6.0000e+00 9.5748e-01 6.4051e-01 1.5110e-02 7.6512e-02 -6.0000e+00 1.0450e+00 -8.1153e-01 1.4662e-02 3.0131e-02 -6.0000e+00 6.1744e-01 3.2758e-01 6.9430e-03 7.6293e-03 -6.0000e+00 2.6461e-01 3.9681e-05 -1.5440e-03 1.5228e-04 1.4229e-04 -6.0000e+00 1.9555e-02 4.3991e-02 0.0000e+00 12 9 9 12 1 1 99.65 24.16 0.52 0.04399 0.03239 28 4 1 5 0 1235.490 32.75 20.16 24.16 9.57 5.2 939.39 206089 -160238 -148798 -162827 -180142 900000 -203235 900000 -62161 -50740 900000 -159920 -144856 -67808 211679 139304 53594 -57283 -9808 900000 -55636 -61941 33187 -41784 -54988 -36509 128409 169482 10617 900000 2256 420127 -22946 -2001 -44299 900000 -21979 -17330 25285 40477 -2451 16689 2673 2304 21852 69127 7234 2906 80154 41552 35234 -3099 1904 19070 7334 19114 2922 17262 -1159 6794 3093 17835 22579 3351 18072 11449 8630 10259 5204 5173 13325 14856 1947 -4574 -2509 -8906 -7856 -3113 -180 5047 -641 159 -2421 -4694 -347 6193 -702 747 -2264 -2349 -945 -3363 -3818 -4582 -5809 719 -2609 -3309 -2179 -1842 -506 2535 -601 -2110 -5314 -2868 -1772 22923 -1613 -2745 -1273 105 312 797 1682 166 371 435 1670 2368 44 1686 864 -238 -732 -826 170 210 902 -118 -607 39 8 -247 -143 -80 976 -361 64 -1056 227 -670 1170 -3389 -2687 -3024 -3717 900000 -6081 900000 -545 -419 900000 -5363 -5306 -1434 1201 791 547 -1714 -206 900000 -1800 -2179 490 -1423 -2247 -1243 802 962 217 900000 72 2384 -1185 -82 -2665 900000 -1297 -1190 1363 2136 -214 1250 232 199 1550 3099 624 277 3821 3254 3319 -475 304 2749 1249 2983 532 2606 -201 1083 551 3127 4318 844 3979 2703 2194 2835 1579 1743 4338 4706 657 -1487 -782 -2749 -2452 -1046 -64 2036 -318 88 -1470 -3099 -232 4071 -507 530 -1596 -1555 -582 -2076 -2488 -3420 -4747 649 -2608 -3699 -2465 -1969 -519 2262 -538 -2027 -5599 -3119 -1901 23187 -2208 -4015 -2005 168 494 1209 2441 245 568 701 2745 3798 68 2475 1238 -334 -1074 -1183 235 332 1529 -228 -1198 81 19 -560 -341 -194 2379 -884 149 -2457 483 -1372 SS 20251210T131104.2Z 9475.549354 288 1 21.50 2 80.20 128.78 49.19 249.80 0.00 1 0.00 1 0 25 4.414e-01 1.003e-02 1.682e-01 3.305e-03 7.525717e-01 1.742360e-03 8.327814e-03 -6.000000e+00 2.523328e-01 223.61 -2.00 3.43 -2.00 320.71 0.00e+00 8.316327e-04 7.468705e-04 1.635917e-03 -6.000000e+00 1.130188e-02 280.90 -2.00 20.00 -2.00 320.15 0.00e+00 5.612 0.003 302.00 328.00 3 1.7680e+00 5.4498e-03 6.7697e-02 -6.0000e+00 6.2119e-01 1.5384e-01 7.3260e-03 3.9315e-02 -6.0000e+00 6.7638e-01 -1.8394e-01 7.5146e-03 2.0807e-02 -6.0000e+00 4.0376e-01 6.8820e-02 3.6873e-03 6.4389e-03 -6.0000e+00 1.7299e-01 1.5807e-04 -3.1495e-04 8.6156e-05 8.1288e-05 -6.0000e+00 1.2550e-02 4.4051e-02 0.0000e+00 12 9 9 12 1 1 99.10 24.17 0.37 0.04405 0.04168 41 10 1 5 0 511.670 32.75 19.78 24.17 9.48 5.2 938.93 -159083 -119387 -96809 -202026 -177524 -76775 -158932 -48737 -99524 -95291 -99574 -164580 -119380 -92409 12090 12953 -6448 -67543 -27240 66089 -32350 -65285 8923 -48212 -38978 -37084 12807 -29514 -28336 -34651 13576 41913 -8962 -12982 -28454 38943 -11101 -17383 -1371 9719 -6122 175 -4869 -6029 9672 6628 2872 2389 11275 11397 8834 -1348 -2374 4257 3243 4565 -1341 5646 -871 4200 313 2255 3361 2734 2001 1858 555 2456 2522 2990 1940 1776 -268 -851 -934 -2362 -2543 146 -384 113 -1090 -2408 -1821 -1406 -757 1550 -536 688 216 482 590 -292 -196 -853 -617 778 -110 -991 -874 -658 -414 500 375 -1568 -1568 -951 -357 -394 47 -24 128 -86 261 360 602 1477 -40 508 -99 39 -181 439 734 502 217 -141 695 950 453 44 -431 -325 -112 -110 -143 183 179 -532 -90 -394 18 104 -1258 -700 -454 -2545 -1716 -292 -1583 -204 -770 -768 -963 -3872 -2347 -1787 101 125 -85 -1807 -518 511 -678 -1999 144 -1523 -1206 -1159 239 -837 -858 -1340 398 1094 -427 -640 -1623 1230 -687 -1417 -116 846 -683 19 -585 -744 1044 760 358 319 1497 1697 1532 -262 -513 928 753 1086 -339 1295 -208 973 82 668 1124 993 737 685 216 952 1125 1477 1019 928 -135 -393 -388 -930 -1022 64 -203 65 -733 -1693 -1362 -1117 -636 1337 -486 616 187 391 450 -218 -152 -750 -591 805 -132 -1243 -1111 -788 -472 512 405 -1719 -1824 -1162 -439 -535 67 -37 201 -138 429 563 903 2199 -64 840 -162 64 -296 681 1098 765 321 -203 1037 1519 790 81 -825 -658 -232 -231 -319 416 411 -1225 -197 -848 37 210 SS 20251210T131802.4Z 9475.554194 292 1 6.38 2 79.12 129.99 50.49 251.18 0.00 1 0.00 1 0 17 3.389e-01 9.204e-03 1.190e-01 4.131e-03 6.914910e-01 2.152538e-03 7.802605e-03 -6.000000e+00 1.937586e-01 223.61 -2.00 3.43 -2.00 320.25 0.00e+00 3.060657e-03 7.989455e-04 1.243800e-03 -6.000000e+00 8.677613e-03 280.89 -2.00 20.00 -2.00 319.66 0.00e+00 5.106 0.002 302.00 328.00 3 1.5788e+00 6.3810e-03 6.1503e-02 -6.0000e+00 4.7699e-01 1.2712e-01 8.0699e-03 3.5049e-02 -6.0000e+00 5.1935e-01 -1.4806e-01 7.7014e-03 1.8830e-02 -6.0000e+00 3.1002e-01 5.5117e-02 3.9074e-03 6.7965e-03 -6.0000e+00 1.3285e-01 3.2466e-04 -3.5748e-04 1.0950e-04 7.9504e-05 -6.0000e+00 9.6355e-03 4.3156e-02 0.0000e+00 12 9 1 12 1 1 86.49 24.18 0.44 0.04316 0.04047 17 15 1 5 0 354.400 32.75 20.23 24.18 9.51 5.2 939.10 -78770 -96651 -74167 -150185 -179365 -114916 -99010 -62198 -119954 -86469 -70708 -101725 -81898 -29888 -13875 -13140 -13999 -25534 -29636 2821 -12702 -25174 -16780 -41414 -11774 -318 -6210 -28431 -25493 481 5495 16822 -12954 -4759 -11592 1695 -10752 -4929 703 2021 -1992 1232 -237 -3241 3549 5474 -3285 3549 4013 5681 5384 882 -188 2057 1428 2350 1759 3974 3085 2420 1063 4102 4365 2625 1724 2212 530 1907 540 1019 847 1735 -262 -1093 -1383 -2886 -1689 -162 -1436 -847 -297 -2385 -1904 -1684 -1185 -290 373 -32 759 1342 482 -630 -358 -727 -477 244 320 -491 -1043 -949 -213 242 126 -533 -1197 -606 -387 447 241 -396 77 285 345 456 1056 449 496 453 295 -137 83 230 294 -524 15 381 593 719 506 -58 -128 -332 -34 -56 -534 33 95 -209 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