File name: Pandora255s1_VirginiaBeachVA-CBBT_20260324_L2Fit_fout2c3d20240302p1-8.txt File generation date: 20260325T052359.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: John Anderson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 255 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora255_OF_v2d20221206.txt Instrument calibration file used: Pandora255s1_CF_v3d20240302.txt Level 1 file used: Pandora255s1_VirginiaBeachVA-CBBT_20260324_L1_smca1c3d20240302p1-8.txt Full location name: Chesapeake Bay Bridge Tunnel Virginia Short location name: VirginiaBeachVA-CBBT Country of location: United States Location latitude [deg]: 37.0367 Location longitude [deg]: -76.0766 Location altitude [m]: 20 Local noon date: 20260324 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 195 336 Nominal wavelengths inside fitting window [nm]: 305.1318 305.2728 305.4137 305.5546 305.6955 305.8364 305.9773 306.1182 306.2590 306.3999 306.5407 306.6815 306.8224 306.9632 307.1040 307.2447 307.3855 307.5263 307.6670 307.8078 307.9485 308.0892 308.2299 308.3706 308.5113 308.6520 308.7926 308.9333 309.0739 309.2146 309.3552 309.4958 309.6364 309.7770 309.9175 310.0581 310.1986 310.3392 310.4797 310.6202 310.7607 310.9012 311.0417 311.1822 311.3227 311.4631 311.6035 311.7440 311.8844 312.0248 312.1652 312.3056 312.4459 312.5863 312.7267 312.8670 313.0073 313.1476 313.2880 313.4282 313.5685 313.7088 313.8491 313.9893 314.1296 314.2698 314.4100 314.5502 314.6904 314.8306 314.9707 315.1109 315.2511 315.3912 315.5313 315.6714 315.8115 315.9516 316.0917 316.2318 316.3718 316.5119 316.6519 316.7920 316.9320 317.0720 317.2120 317.3519 317.4919 317.6319 317.7718 317.9117 318.0517 318.1916 318.3315 318.4714 318.6113 318.7511 318.8910 319.0308 319.1706 319.3105 319.4503 319.5901 319.7299 319.8696 320.0094 320.1492 320.2889 320.4286 320.5684 320.7081 320.8478 320.9874 321.1271 321.2668 321.4064 321.5461 321.6857 321.8253 321.9649 322.1045 322.2441 322.3837 322.5232 322.6628 322.8023 322.9418 323.0813 323.2208 323.3603 323.4998 323.6393 323.7787 323.9182 324.0576 324.1970 324.3364 324.4758 324.6152 324.7546 324.8940 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260324T133614.6Z 9579.566835 116 1 2.50 2 60.65 112.65 98.51 46.15 0.00 1 0.00 1 0 17 9.043e-03 5.887e-03 2.913e-03 1.420e-03 3.104076e-01 7.306595e-04 3.650070e-03 -6.000000e+00 5.242165e-03 227.31 -2.00 3.43 -2.00 316.30 0.00e+00 1.686751e-04 8.209179e-05 4.816606e-05 -6.000000e+00 2.314587e-04 280.82 -2.00 20.00 -2.00 315.63 0.00e+00 2.031 0.000 302.00 328.00 3 2.0348e+00 1.8945e-03 2.5573e-02 -6.0000e+00 1.3015e-02 3.6504e-02 2.1181e-03 1.5422e-02 -6.0000e+00 1.4133e-02 -1.6253e-02 1.2273e-03 7.5950e-03 -6.0000e+00 8.4115e-03 4.1305e-03 5.7425e-04 2.1362e-03 -6.0000e+00 3.5765e-03 6.0967e-03 5.5025e-05 4.1034e-05 2.6333e-05 -6.0000e+00 2.5731e-04 4.1882e-02 0.0000e+00 12 1 1 12 1 1 98.25 24.44 0.29 0.04188 0.04230 21 47 1 5 0 113.520 32.75 19.97 24.44 11.29 5.4 956.89 -1817 -1085 -3070 -3376 -2930 -1463 -380 29 -1975 -936 -2334 -304 391 -375 100 -520 444 312 1298 755 307 1905 1079 1021 286 -348 -819 564 1311 1222 1539 1500 -1024 -1808 -571 -801 -536 312 -483 -1017 -819 -916 -884 -98 -106 -928 -605 -115 178 670 753 472 1042 436 865 565 105 227 983 1246 1271 1443 688 -33 -686 131 200 1074 891 -295 -202 -98 355 -65 105 226 198 39 -424 -1094 -1239 -1777 -1406 -1061 -950 -555 -531 -104 -186 294 326 451 1148 971 334 358 211 -211 -467 -136 -332 263 362 -607 -898 -487 -633 -166 245 -129 14 -81 12 228 828 741 662 506 -333 -447 -114 36 263 561 380 506 1266 811 59 1 -190 -171 167 -18 -207 -140 190 -224 -286 -279 -370 -265 -353 -218 -603 -602 -491 -251 -72 6 -422 -200 -522 -74 102 -107 32 -178 148 109 465 279 114 707 402 405 119 -146 -331 211 506 470 647 651 -476 -813 -246 -370 -259 171 -287 -649 -530 -613 -600 -66 -71 -622 -397 -77 120 455 529 342 794 335 679 454 85 179 764 988 1040 1243 621 -30 -601 109 168 913 801 -287 -201 -97 349 -61 92 193 160 33 -376 -1039 -1272 -1869 -1510 -1179 -1101 -660 -637 -125 -222 341 355 476 1166 1038 375 428 267 -273 -605 -170 -399 310 422 -750 -1128 -638 -850 -224 345 -189 21 -118 17 307 1088 963 873 698 -470 -647 -163 50 365 755 500 648 1609 1078 81 1 -276 -249 252 -28 -329 -224 308 -367 -459 -439 -569 -405 SS 20260324T134729.1Z 9579.574642 125 1 29.35 2 58.60 114.87 96.93 47.94 0.00 1 0.00 1 0 17 8.940e-03 5.671e-03 1.939e-03 9.418e-04 2.939439e-01 4.853750e-04 3.466536e-03 -6.000000e+00 5.183129e-03 227.31 -2.00 3.43 -2.00 316.24 0.00e+00 1.364991e-04 5.416764e-05 5.067680e-05 -6.000000e+00 2.288367e-04 280.82 -2.00 20.00 -2.00 315.58 0.00e+00 1.912 0.000 302.00 328.00 3 3.8080e+00 1.2571e-03 2.4148e-02 -6.0000e+00 1.2869e-02 4.7067e-02 1.4060e-03 1.4640e-02 -6.0000e+00 1.3974e-02 -1.3217e-02 8.1517e-04 7.2140e-03 -6.0000e+00 8.3165e-03 2.6629e-03 3.8122e-04 2.0265e-03 -6.0000e+00 3.5365e-03 1.1853e-03 5.3973e-05 2.7323e-05 2.5408e-05 -6.0000e+00 2.5439e-04 4.1180e-02 0.0000e+00 12 1 1 12 1 1 99.99 24.47 0.34 0.04118 0.04159 58 11 1 5 0 497.320 33.00 19.93 24.47 11.62 5.4 960.07 -2567 -2934 -3342 -3285 -1855 -430 -1120 622 -1437 -1222 -233 -1217 -749 162 538 61 1251 149 712 1506 -58 1563 1405 669 119 -363 -201 213 964 1366 1885 1828 -615 -1759 -974 -454 -475 -186 -435 -912 -939 -637 -642 -546 -218 -817 -494 -611 287 693 456 283 412 400 553 496 425 455 805 1193 1277 1251 984 13 -267 70 192 1065 738 -4 -84 20 17 26 9 104 -127 327 -201 -876 -1235 -1897 -1536 -1060 -917 -527 -440 -311 81 177 381 417 929 784 573 529 452 -324 -468 -251 -245 256 362 -334 -980 -628 -494 -206 221 29 45 -60 71 272 766 795 501 326 -98 -449 -153 53 260 372 381 471 1141 735 184 0 -327 -172 106 -101 -247 -5 118 -323 -73 -148 -288 -336 -496 -591 -648 -575 -301 -71 -209 127 -320 -274 -53 -286 -202 46 170 21 436 51 252 541 -21 569 539 274 48 -147 -83 82 360 533 797 787 -283 -785 -418 -207 -236 -104 -271 -601 -623 -435 -444 -377 -150 -557 -329 -401 197 473 335 211 311 313 442 405 347 364 635 959 1048 1073 905 12 -237 60 160 922 691 -4 -85 21 17 25 8 87 -105 279 -177 -846 -1277 -2048 -1679 -1187 -1062 -643 -537 -381 98 207 421 437 970 828 645 622 571 -427 -616 -321 -297 300 430 -402 -1263 -818 -654 -278 308 41 66 -88 100 364 985 1009 662 446 -139 -639 -215 74 360 503 491 595 1428 952 251 1 -474 -247 159 -154 -389 -7 190 -524 -116 -231 -445 -507 SS 20260324T135130.2Z 9579.577433 128 1 46.39 2 57.87 115.69 96.36 48.57 0.00 1 0.00 1 0 17 8.546e-03 5.726e-03 6.750e-04 3.616e-04 2.887567e-01 1.863584e-04 3.402915e-03 -6.000000e+00 4.954649e-03 227.31 -2.00 3.43 -2.00 316.01 0.00e+00 2.686771e-04 1.972949e-05 4.146426e-05 -6.000000e+00 2.187506e-04 280.82 -2.00 20.00 -2.00 315.37 0.00e+00 1.873 0.000 302.00 328.00 3 2.4456e+00 4.8161e-04 2.3669e-02 -6.0000e+00 1.2301e-02 3.7130e-02 5.3789e-04 1.4351e-02 -6.0000e+00 1.3358e-02 -1.4653e-02 3.1015e-04 7.0645e-03 -6.0000e+00 7.9499e-03 3.5678e-03 1.4299e-04 1.9931e-03 -6.0000e+00 3.3806e-03 4.8700e-03 9.4524e-05 1.0472e-05 2.4916e-05 -6.0000e+00 2.4318e-04 4.1238e-02 0.0000e+00 12 1 1 12 9 1 99.92 24.49 0.32 0.04124 0.04195 313 36 1 5 0 147.730 33.00 20.04 24.49 11.89 5.4 962.31 -1986 -2235 -3144 -3561 -1761 -1096 -113 -59 -1189 -1473 -897 -439 -334 292 217 -100 793 844 1064 1143 770 1598 1213 795 415 -273 -453 414 882 1476 1484 1237 -547 -1804 -722 -679 -226 15 -531 -944 -804 -842 -916 -487 -405 -701 -610 -529 162 688 559 513 721 508 750 681 375 370 805 1241 1291 1211 947 -55 -514 73 183 920 734 -160 -108 -143 -70 13 -32 203 124 333 -271 -925 -1295 -1778 -1537 -1006 -1043 -546 -347 -191 55 174 407 401 1028 846 352 477 299 -250 -495 -291 -305 225 437 -415 -947 -543 -509 -175 182 18 -36 29 98 317 674 804 605 346 -167 -466 -159 54 200 418 515 520 1243 605 108 -3 -210 -72 70 -86 -202 -74 111 -298 -221 -155 -346 -286 -431 -504 -686 -758 -347 -222 -25 -14 -296 -371 -230 -116 -101 95 74 -36 297 329 405 445 300 627 503 332 181 -120 -191 171 354 618 641 581 -258 -828 -334 -318 -116 8 -336 -639 -552 -596 -658 -348 -289 -494 -420 -358 109 484 407 384 568 402 606 561 309 300 642 1009 1082 1069 868 -51 -456 64 154 811 683 -156 -107 -142 -70 12 -30 173 104 287 -246 -894 -1313 -1893 -1671 -1129 -1221 -656 -420 -231 66 199 448 429 1051 908 396 566 374 -320 -634 -368 -363 264 506 -509 -1210 -706 -677 -238 259 26 -54 41 137 425 864 1042 797 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