File name: Pandora159s1_Wakkerstroom_20210910_L2Fit_fout2c3d20201207p1-8.txt File generation date: 20251121T032622.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Refilwe Kai Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 159 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora159_OF_v6d20191004.txt Instrument calibration file used: Pandora159s1_CF_v3d20201207.txt Level 1 file used: Pandora159s1_Wakkerstroom_20210910_L1_smca1c3d20201207p1-8.txt Full location name: Global Change Institute, University of Witwatersrand field site in Wakkerstroom Short location name: Wakkerstroom Country of location: South Africa Location latitude [deg]: -27.3493 Location longitude [deg]: 30.1438 Location altitude [m]: 1760 Local noon date: 20210910 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 222 364 Nominal wavelengths inside fitting window [nm]: 305.0731 305.2139 305.3547 305.4955 305.6363 305.7770 305.9178 306.0585 306.1992 306.3399 306.4806 306.6213 306.7620 306.9026 307.0433 307.1839 307.3246 307.4652 307.6058 307.7464 307.8869 308.0275 308.1681 308.3086 308.4492 308.5897 308.7302 308.8707 309.0112 309.1517 309.2921 309.4326 309.5730 309.7135 309.8539 309.9943 310.1347 310.2751 310.4155 310.5558 310.6962 310.8365 310.9769 311.1172 311.2575 311.3978 311.5381 311.6784 311.8186 311.9589 312.0991 312.2393 312.3795 312.5198 312.6599 312.8001 312.9403 313.0805 313.2206 313.3607 313.5009 313.6410 313.7811 313.9212 314.0612 314.2013 314.3414 314.4814 314.6214 314.7615 314.9015 315.0415 315.1814 315.3214 315.4614 315.6013 315.7413 315.8812 316.0211 316.1610 316.3009 316.4408 316.5807 316.7205 316.8604 317.0002 317.1400 317.2798 317.4196 317.5594 317.6992 317.8389 317.9787 318.1184 318.2582 318.3979 318.5376 318.6773 318.8170 318.9566 319.0963 319.2359 319.3756 319.5152 319.6548 319.7944 319.9340 320.0736 320.2131 320.3527 320.4922 320.6318 320.7713 320.9108 321.0503 321.1898 321.3292 321.4687 321.6081 321.7476 321.8870 322.0264 322.1658 322.3052 322.4446 322.5839 322.7233 322.8626 323.0019 323.1413 323.2806 323.4199 323.5591 323.6984 323.8377 323.9769 324.1162 324.2554 324.3946 324.5338 324.6730 324.8121 324.9513 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Spectrometer control temperature [°C], 999=no temperature signal Column 94: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 95: Temperature in head sensor [°C], 999=no temperature signal Column 96: Temperature at electronics board 1 [°C], 999=no temperature signal Column 97: Temperature at electronics board 2 [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210910T081637.5Z 7923.344878 4 1 51.79 2 40.17 40.65 65.59 87.56 0.00 1 0.00 1 0 25 9.734e-03 7.398e-03 2.124e-04 1.221e-04 1.725408e-01 6.129211e-05 1.865364e-03 -6.000000e+00 5.515098e-03 227.32 -2.00 3.06 -2.00 315.68 0.00e+00 2.361101e-04 5.961106e-06 4.000476e-05 -6.000000e+00 2.395297e-04 277.28 -2.00 20.00 -2.00 315.10 0.00e+00 1.307 0.000 302.00 328.00 3 2.5772e-01 1.5842e-04 1.3188e-02 -6.0000e+00 1.3716e-02 -4.8442e-03 1.7675e-04 7.7735e-03 -6.0000e+00 1.4923e-02 5.4170e-04 1.0151e-04 3.8345e-03 -6.0000e+00 8.8636e-03 -1.9790e-03 4.6060e-05 1.0943e-03 -6.0000e+00 3.7485e-03 1.1947e-01 -2.3250e-04 3.4499e-06 1.3670e-05 -6.0000e+00 2.6024e-04 2.3400e-03 11 8 0 10 0 0 19.57 14.82 0.32 0.00234 0.00059 3218 692 2 8 0 14.910 14.92 14.82 26.34 17.91 17.91 20.3 936.05 -1616 -1794 -2762 -3426 -854 153 1142 1578 804 -1000 3 1450 157 508 262 -1163 -10 22 318 540 -129 1073 1523 650 718 140 -719 21 1286 2473 2024 2429 1233 -1716 -246 705 -196 488 -149 -1431 -1562 -1023 -1240 -1249 -535 -1211 -919 -539 -560 736 809 602 917 554 480 1103 426 458 792 1088 1498 1132 904 309 -972 204 220 931 1747 134 -202 -453 -345 -156 -317 466 575 1147 1342 -293 -646 -1287 -2010 -821 -1087 -995 -664 -609 -443 -418 345 306 1029 1918 1366 703 758 145 -808 -576 -288 -124 930 729 -988 -627 -625 -685 -54 -99 -280 -327 -97 117 461 1131 760 632 220 -555 -722 -191 -153 96 925 460 1287 1677 574 373 106 -3 107 409 -236 -401 -24 -143 -583 -221 -232 -370 -81 -410 -486 -755 -866 -204 34 268 414 213 -278 1 384 46 167 96 -463 -4 9 133 233 -57 460 657 296 343 69 -351 9 529 971 825 1048 573 -825 -108 300 -92 265 -89 -996 -1175 -794 -985 -995 -420 -951 -699 -393 -393 506 579 459 731 461 408 948 345 398 674 920 1302 976 840 303 -948 179 190 769 1522 124 -204 -478 -362 -158 -300 425 469 873 1055 -262 -595 -1305 -2174 -917 -1210 -1188 -835 -789 -574 -520 393 341 1026 1816 1361 772 852 180 -1068 -745 -347 -148 1047 859 -1197 -801 -832 -949 -77 -140 -414 -484 -136 162 581 1426 956 774 291 -796 -1068 -279 -217 130 1180 560 1578 2040 747 480 142 -4 148 584 -358 -600 -36 -225 -926 -343 -349 -538 -123 SS 20210910T082333.5Z 7923.349693 7 1 51.78 2 39.19 38.43 64.09 86.78 0.00 1 0.00 1 0 25 9.713e-03 7.380e-03 2.039e-04 1.188e-04 1.702800e-01 5.972606e-05 1.841871e-03 -6.000000e+00 5.502691e-03 227.32 -2.00 3.06 -2.00 315.61 0.00e+00 2.176450e-04 5.730038e-06 3.701187e-05 -6.000000e+00 2.389924e-04 277.28 -2.00 20.00 -2.00 315.04 0.00e+00 1.289 0.000 302.00 328.00 3 2.2660e-01 1.5425e-04 1.3007e-02 -6.0000e+00 1.3685e-02 -3.9277e-03 1.7219e-04 7.6693e-03 -6.0000e+00 1.4889e-02 6.2206e-04 9.8652e-05 3.7848e-03 -6.0000e+00 8.8437e-03 -2.0653e-03 4.4569e-05 1.0774e-03 -6.0000e+00 3.7400e-03 1.2562e-01 -2.4602e-04 3.3515e-06 1.3507e-05 -6.0000e+00 2.5966e-04 2.5082e-03 11 8 0 10 0 0 16.75 16.00 0.31 0.00251 0.00066 3320 714 2 8 0 14.440 14.96 16.00 27.71 18.94 18.94 19.6 940.29 -1624 -1753 -2809 -3445 -793 286 1188 1572 795 -952 69 1430 259 494 248 -1198 2 10 310 528 -98 1127 1506 673 699 157 -708 42 1306 2470 1970 2459 1233 -1690 -231 698 -207 513 -173 -1403 -1549 -1025 -1194 -1238 -533 -1214 -937 -540 -571 760 852 595 902 561 493 1123 458 474 791 1095 1502 1131 900 290 -938 169 210 908 1765 134 -191 -443 -327 -146 -277 456 587 1124 1329 -306 -675 -1288 -2024 -818 -1078 -1000 -660 -616 -434 -433 354 280 1023 1905 1316 690 760 158 -781 -536 -292 -103 887 712 -981 -624 -609 -686 -51 -114 -269 -338 -91 117 453 1107 739 642 226 -554 -705 -194 -163 89 909 470 1259 1668 572 364 104 -20 97 408 -253 -401 -33 -134 -588 -215 -227 -373 -93 -423 -488 -788 -894 -195 66 285 384 216 -271 19 388 78 166 93 -487 1 4 133 232 -44 492 662 312 340 79 -352 19 547 986 816 1077 581 -825 -103 301 -98 282 -105 -989 -1182 -807 -960 -999 -425 -965 -721 -398 -405 528 616 458 727 471 424 899 374 384 679 934 1317 984 845 287 -921 150 183 755 1548 125 -194 -470 -346 -148 -264 419 482 861 1051 -274 -626 -1312 -2200 -918 -1205 -1201 -834 -802 -565 -542 406 313 1024 1810 1317 760 856 196 -1034 -695 -352 -122 1002 842 -1192 -799 -813 -953 -68 -162 -399 -502 -128 163 570 1396 931 787 299 -795 -974 -283 -232 121 1160 573 1547 2031 744 468 140 -27 134 581 -358 -599 -50 -211 -934 -333 -341 -542 -141 SS 20210910T082840.6Z 7923.353248 9 1 51.89 2 38.50 36.72 62.97 86.20 0.00 1 0.00 1 0 25 9.705e-03 7.394e-03 2.011e-04 1.184e-04 1.687170e-01 5.968006e-05 1.828396e-03 -6.000000e+00 5.498453e-03 227.32 -2.00 3.06 -2.00 315.58 0.00e+00 2.209588e-04 5.659737e-06 3.821005e-05 -6.000000e+00 2.388098e-04 277.28 -2.00 20.00 -2.00 315.01 0.00e+00 1.277 0.000 302.00 328.00 3 2.3460e-01 1.5402e-04 1.2888e-02 -6.0000e+00 1.3674e-02 -4.2622e-03 1.7179e-04 7.6063e-03 -6.0000e+00 1.4878e-02 6.1873e-04 9.8492e-05 3.7540e-03 -6.0000e+00 8.8369e-03 -1.9821e-03 4.4425e-05 1.0699e-03 -6.0000e+00 3.7370e-03 1.2629e-01 -2.4808e-04 3.3377e-06 1.3498e-05 -6.0000e+00 2.5947e-04 2.6613e-03 11 8 0 10 0 0 15.80 16.58 0.31 0.00266 0.00080 3302 710 2 8 0 14.520 15.00 16.58 28.41 19.44 19.44 19.1 942.27 -1597 -1798 -2777 -3348 -862 287 1187 1625 775 -944 93 1383 313 466 264 -1227 36 20 344 534 -107 1114 1505 721 731 170 -673 48 1306 2459 1936 2469 1225 -1713 -260 667 -187 513 -140 -1409 -1577 -1042 -1204 -1196 -536 -1244 -939 -489 -575 742 844 592 924 573 484 1140 445 476 820 1123 1488 1136 928 305 -946 171 216 908 1770 134 -167 -429 -336 -131 -280 485 601 1157 1317 -296 -679 -1281 -2017 -810 -1088 -999 -662 -599 -419 -411 355 271 1024 1886 1335 708 769 161 -800 -530 -280 -102 876 727 -997 -624 -645 -693 -64 -104 -265 -328 -89 127 462 1125 746 635 241 -554 -693 -199 -144 86 915 482 1262 1654 561 382 130 -2 98 405 -248 -403 -43 -126 -587 -215 -220 -400 -92 -423 -509 -792 -881 -215 67 289 403 213 -273 26 380 95 159 100 -505 15 8 149 237 -49 492 669 338 359 86 -338 22 552 991 810 1090 582 -843 -117 290 -89 285 -86 -1001 -1212 -826 -975 -971 -430 -997 -727 -363 -411 519 614 459 748 484 386 917 365 388 707 962 1211 993 875 303 -932 151 188 757 1558 125 -170 -456 -357 -134 -268 446 495 888 1045 -266 -631 -1308 -2196 -910 -1219 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