File name: Pandora40s1_WallopsIslandVA_20211118_L2Fit_fout2c7d20210513p1-8.txt File generation date: 20260321T161649.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 40 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora40_OF_v2d20210309.txt Instrument calibration file used: Pandora40s1_CF_v7d20210513.txt Level 1 file used: Pandora40s1_WallopsIslandVA_20211118_L1_smca1c7d20210513p1-8.txt.bz2 Full location name: Wallops Island X-75 Station, Wallops Flight Facility Geophysical Observatory Short location name: WallopsIslandVA Country of location: USA Location latitude [deg]: 37.8439 Location longitude [deg]: -75.4775 Location altitude [m]: 11 Local noon date: 20211118 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 6 suggested by BP "AnaLab+Fld 1.8 VP 20210513" First and last pixel inside fitting window: 231 372 Nominal wavelengths inside fitting window [nm]: 305.1141 305.2550 305.3959 305.5368 305.6777 305.8186 305.9595 306.1003 306.2412 306.3820 306.5228 306.6636 306.8044 306.9452 307.0860 307.2267 307.3675 307.5082 307.6489 307.7897 307.9304 308.0711 308.2117 308.3524 308.4931 308.6337 308.7743 308.9150 309.0556 309.1962 309.3368 309.4773 309.6179 309.7584 309.8990 310.0395 310.1800 310.3205 310.4610 310.6015 310.7420 310.8824 311.0229 311.1633 311.3037 311.4442 311.5846 311.7249 311.8653 312.0057 312.1460 312.2864 312.4267 312.5670 312.7073 312.8476 312.9879 313.1282 313.2684 313.4087 313.5489 313.6892 313.8294 313.9696 314.1098 314.2499 314.3901 314.5303 314.6704 314.8105 314.9506 315.0908 315.2308 315.3709 315.5110 315.6511 315.7911 315.9312 316.0712 316.2112 316.3512 316.4912 316.6312 316.7711 316.9111 317.0510 317.1910 317.3309 317.4708 317.6107 317.7506 317.8904 318.0303 318.1701 318.3100 318.4498 318.5896 318.7294 318.8692 319.0090 319.1488 319.2885 319.4283 319.5680 319.7077 319.8474 319.9871 320.1268 320.2665 320.4061 320.5458 320.6854 320.8250 320.9646 321.1042 321.2438 321.3834 321.5230 321.6625 321.8021 321.9416 322.0811 322.2206 322.3601 322.4996 322.6391 322.7785 322.9180 323.0574 323.1968 323.3363 323.4757 323.6150 323.7544 323.8938 324.0331 324.1725 324.3118 324.4511 324.5904 324.7297 324.8690 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211118T123052.9Z 7992.521446 268 1 49.41 2 82.96 121.24 106.54 304.97 0.00 1 0.00 1 0 17 4.478e-01 2.526e-02 3.705e-01 1.632e-02 7.310907e-01 9.553836e-03 9.495290e-03 -6.000000e+00 2.654540e-01 223.83 -2.00 3.45 -2.00 322.10 0.00e+00 7.924015e-03 5.325575e-03 1.149246e-02 -6.000000e+00 1.206283e-02 282.56 -2.00 20.00 -2.00 321.62 0.00e+00 7.492 0.007 302.00 328.00 3 1.3890e+00 3.7083e-02 1.0212e-01 -6.0000e+00 6.5384e-01 6.7883e-01 4.9139e-02 8.4151e-02 -6.0000e+00 7.1076e-01 -1.0669e+00 4.1732e-02 3.9761e-02 -6.0000e+00 4.2192e-01 4.3616e-01 1.9435e-02 9.1787e-03 -6.0000e+00 1.8059e-01 4.0702e-05 -1.1736e-03 5.1882e-04 2.7758e-04 -6.0000e+00 1.3450e-02 7.1808e-03 -1.6641e-04 12 8 8 10 0 0 17.99 18.38 0.51 0.00718 -0.00164 44 10 1 5 0 1122.820 21.58 15.00 18.38 20.26 24.3 1023.02 -102484 -34902 -14373 -123839 900000 -63464 900000 -51612 -41350 -101531 -164768 -31540 -8613 900000 -28877 223043 69612 48471 900000 -31344 900000 -43198 40578 -47686 43097 -31240 -52339 70200 -71865 14936 7967 27072 -18938 14164 118044 16137 186460 -6371 37930 23464 23165 57614 50596 63505 14869 46885 6538 39388 69188 3041 62067 31353 103263 26431 35199 23286 15297 32854 -17365 88728 21451 39433 12330 31885 23532 -4864 24231 -5 24714 5154 17273 8503 -1657 24659 3759 19785 -2595 -2103 -9056 -5713 -4137 -4906 4385 -1590 981 -1849 -723 3873 -2782 5437 -6815 -3451 -6606 -6414 270 -7358 638 -1553 -221 -2930 -1833 -5497 -5164 -4681 -3796 427 -254 1378 915 3293 2735 -594 393 -2602 -235 -1892 63 443 821 2083 1199 2258 1764 1588 1333 -402 7 -1484 633 -599 132 -683 -346 -496 -207 483 988 1236 298 829 -1568 -2355 -3529 -706 -228 -4756 900000 -1192 900000 -895 -657 -2934 -8511 -547 -149 900000 -918 3545 1106 910 900000 -1313 900000 -1872 762 -2205 809 -1219 -2420 1116 -3946 388 265 861 -1040 553 1876 583 2963 -368 1644 1322 1406 2581 2485 2753 1053 2439 520 2333 3199 294 3677 2763 4774 2788 3509 2658 1722 3275 -2530 4871 2448 4216 1796 4181 3428 -928 3498 -1 4255 1208 3820 2072 -428 4507 762 3402 -502 -437 -2363 -1718 -1425 -1917 1690 -693 444 -911 -367 1903 -1437 2463 -3277 -1536 -3062 -3245 148 -5126 478 -1343 -199 -2651 -1515 -4274 -3816 -3571 -3072 352 -227 1331 1001 3982 3659 -859 562 -3715 -315 -2558 86 641 1245 3170 1800 3236 2465 2156 1760 -527 9 -2196 1050 -1134 271 -1515 -817 -1256 -556 1339 2783 3497 833 2193 -3985 -5739 SS 20211118T124138.9Z 7992.528922 271 1 48.76 2 81.16 123.05 108.18 306.96 0.00 1 0.00 1 0 25 4.276e-01 1.245e-02 2.613e-01 5.413e-03 6.451034e-01 3.057804e-03 8.641003e-03 -6.000000e+00 2.534671e-01 223.83 -2.00 3.45 -2.00 321.63 0.00e+00 5.303573e-03 1.709106e-03 9.734638e-03 -6.000000e+00 1.197112e-02 282.56 -2.00 20.00 -2.00 321.14 0.00e+00 6.155 0.004 302.00 328.00 3 1.2750e+00 1.1444e-02 8.4780e-02 -6.0000e+00 6.2447e-01 1.3163e-02 1.6744e-02 7.1077e-02 -6.0000e+00 6.7835e-01 -1.6004e-01 1.7544e-02 3.2593e-02 -6.0000e+00 4.0160e-01 6.3448e-02 8.0624e-03 7.1917e-03 -6.0000e+00 1.7261e-01 1.9239e-04 -7.3390e-04 1.7045e-04 2.1727e-04 -6.0000e+00 1.2658e-02 5.2625e-03 -9.3795e-05 12 8 8 10 0 0 28.01 18.48 0.56 0.00526 -0.00025 107 24 1 5 0 455.630 21.69 15.00 18.48 20.68 24.1 1025.15 -186611 -224802 -137222 -24163 900000 900000 -179842 -190370 900000 -123032 -51262 900000 -68759 48848 -86530 -66411 -84770 -69238 39855 37017 2899 -122 -42384 -50936 -60625 19250 34262 10008 18475 -12852 -18187 1199 -3211 -4206 23052 7328 -972 31750 -3376 -4938 867 9551 28672 8878 11622 6239 4019 -621 -569 8543 18823 3990 6515 5403 5187 2082 -1827 2128 4399 6517 5802 4908 7399 5871 2542 3705 3563 4565 1362 3635 1833 1037 811 -365 24 -1852 -6003 -6739 -2320 -3820 968 -1041 -1695 -1583 -1601 -1268 737 1305 1516 1653 -150 -3499 -2860 -4121 -1318 -195 2145 995 668 -373 -2625 -3410 -1960 -1624 -1710 -266 21 769 1607 2199 1492 1201 551 -252 -766 -1460 -868 74 430 1232 1233 1604 1016 620 -1103 -1658 -1457 -432 -444 -563 -768 -833 -715 -390 -72 515 1000 731 399 129 -492 -775 -1610 -3233 -941 -127 900000 900000 -1897 -2510 900000 -973 -270 900000 -544 258 -1323 -981 -1699 -1314 273 273 31 -1 -760 -1074 -1503 223 343 127 224 -244 -441 28 -90 -122 498 193 -32 904 -151 -260 48 517 1347 524 685 401 274 -46 -45 680 1516 415 725 655 664 285 -264 293 582 856 823 793 1327 1174 539 765 746 1011 353 1040 576 336 256 -109 7 -467 -1540 -1861 -711 -1408 395 -487 -866 -863 -936 -785 468 839 959 995 -86 -1978 -1602 -2519 -896 -153 1896 997 705 -388 -2586 -3085 -1676 -1439 -1622 -264 23 877 2025 3078 2287 1751 800 -387 -1127 -2128 -1294 115 704 2044 2010 2519 1557 921 -1611 -2361 -2085 -665 -772 -1003 -1487 -1714 -1558 -905 -176 1311 2591 1919 1035 320 -1163 -1757 SS 20211118T125536.6Z 7992.538617 276 1 48.50 2 78.89 125.47 110.23 309.61 0.00 1 0.00 1 0 25 2.639e-01 1.028e-02 7.536e-02 2.224e-03 5.448929e-01 1.212279e-03 7.337092e-03 -6.000000e+00 1.545215e-01 223.83 -2.00 3.45 -2.00 321.02 0.00e+00 4.814324e-03 5.540177e-04 6.379675e-03 -6.000000e+00 6.885292e-03 282.56 -2.00 20.00 -2.00 320.45 0.00e+00 5.005 0.002 302.00 328.00 3 1.0760e+00 4.0332e-03 6.3949e-02 -6.0000e+00 3.8031e-01 -3.8842e-02 5.3427e-03 4.7009e-02 -6.0000e+00 4.1243e-01 -4.4221e-02 5.1848e-03 2.3318e-02 -6.0000e+00 2.4642e-01 8.6121e-03 2.5101e-03 6.0912e-03 -6.0000e+00 1.0635e-01 7.5341e-04 -3.1039e-04 7.0470e-05 1.5797e-04 -6.0000e+00 7.7628e-03 2.4703e-03 -6.0789e-05 12 8 8 10 0 0 20.54 18.56 0.36 0.00247 0.00014 229 51 1 5 0 211.760 21.69 15.00 18.56 21.23 24.2 1029.06 -69661 -57457 -89181 -115119 -93302 -100488 -97355 -79315 -67569 -69706 -68159 -66944 -53806 -63655 -3736 -19672 5520 -7012 -17090 -29890 -8825 -9667 -21572 -7563 -8067 -13869 -9732 -21790 -21114 -10838 -2324 548 1228 -892 -12990 -12855 -9788 66 1165 -14 2531 2701 3158 -722 2373 3337 5240 2395 1763 3230 3351 3608 2102 3993 3583 3041 1673 -1773 81 442 2481 4435 5315 4523 2106 602 -533 1025 1435 2680 2087 1552 613 -984 -2178 -3239 -4997 -4044 -3626 -2230 -1503 -2239 -2341 -1137 -37 798 1447 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