File name: Pandora40s1_WallopsIslandVA_20220721_L2Fit_fout2c9d20220711p1-8.txt File generation date: 20260321T164249.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: John Moisan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 40 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora40_OF_v3d20210309.txt Instrument calibration file used: Pandora40s1_CF_v9d20220711.txt Level 1 file used: Pandora40s1_WallopsIslandVA_20220721_L1_smca1c9d20220711p1-8.txt.bz2 Full location name: Wallops Island X-75 Station, Wallops Flight Facility Geophysical Observatory Short location name: WallopsIslandVA Country of location: USA Location latitude [deg]: 37.8439 Location longitude [deg]: -75.4775 Location altitude [m]: 11 Local noon date: 20220721 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 8 "New VP from L6 L7" update Field Cal First and last pixel inside fitting window: 231 372 Nominal wavelengths inside fitting window [nm]: 305.1289 305.2698 305.4107 305.5516 305.6924 305.8333 305.9741 306.1150 306.2558 306.3966 306.5374 306.6782 306.8189 306.9597 307.1004 307.2412 307.3819 307.5226 307.6633 307.8040 307.9447 308.0853 308.2260 308.3666 308.5073 308.6479 308.7885 308.9291 309.0697 309.2103 309.3508 309.4914 309.6319 309.7724 309.9129 310.0535 310.1939 310.3344 310.4749 310.6154 310.7558 310.8962 311.0367 311.1771 311.3175 311.4579 311.5982 311.7386 311.8789 312.0193 312.1596 312.2999 312.4402 312.5805 312.7208 312.8611 313.0014 313.1416 313.2818 313.4221 313.5623 313.7025 313.8427 313.9828 314.1230 314.2632 314.4033 314.5434 314.6836 314.8237 314.9638 315.1039 315.2439 315.3840 315.5240 315.6641 315.8041 315.9441 316.0841 316.2241 316.3641 316.5041 316.6440 316.7840 316.9239 317.0638 317.2037 317.3436 317.4835 317.6234 317.7633 317.9031 318.0430 318.1828 318.3226 318.4624 318.6022 318.7420 318.8818 319.0215 319.1613 319.3010 319.4407 319.5804 319.7201 319.8598 319.9995 320.1392 320.2788 320.4185 320.5581 320.6977 320.8373 320.9769 321.1165 321.2561 321.3956 321.5352 321.6747 321.8142 321.9538 322.0933 322.2328 322.3722 322.5117 322.6512 322.7906 322.9300 323.0695 323.2089 323.3483 323.4876 323.6270 323.7664 323.9057 324.0451 324.1844 324.3237 324.4630 324.6023 324.7416 324.8809 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220721T120317.0Z 8237.502280 250 1 49.18 2 67.07 81.32 25.45 197.35 0.00 1 0.00 1 0 25 4.659e-02 1.380e-02 2.918e-02 3.798e-03 3.266323e-01 2.021010e-03 4.226202e-03 -6.000000e+00 2.812778e-02 232.45 -2.00 3.45 -2.00 319.00 0.00e+00 9.517179e-04 4.685708e-04 2.010380e-03 -6.000000e+00 1.254447e-03 291.32 -2.00 20.00 -2.00 318.13 0.00e+00 2.546 0.000 302.00 328.00 3 4.5065e+00 5.6238e-03 3.1675e-02 -6.0000e+00 7.0454e-02 -1.7612e-02 6.4777e-03 2.0504e-02 -6.0000e+00 7.5740e-02 9.5864e-03 4.4414e-03 8.7355e-03 -6.0000e+00 4.5182e-02 -1.4361e-02 2.3177e-03 2.4451e-03 -6.0000e+00 1.9418e-02 3.0973e-04 -5.5849e-04 1.1915e-04 2.5334e-05 -6.0000e+00 1.3535e-03 -2.9696e-02 8.4480e-05 12 8 8 10 0 0 97.82 23.88 0.57 -0.02970 -0.03389 16 4 1 5 0 3073.600 25.90 20.00 23.88 33.89 9.7 1077.73 -7667 17389 -18916 -2855 -21988 -2744 -13996 7632 2385 -16126 5 -14114 7455 -10502 5468 3650 700 4012 -996 -437 2745 609 2817 5281 4667 -1255 1855 -10812 -310 -5302 -1804 5256 3797 -7921 -8127 -2592 -8597 -1978 -1681 736 345 -785 2096 -208 -208 204 1249 -161 -735 -1528 -2159 2347 761 2632 561 2398 2503 -1365 1304 -1103 2763 2131 4651 2489 1050 10 -1944 514 -460 2312 188 1960 1900 255 185 -3104 -3595 -5447 -4324 -3117 -2868 -1838 -2267 -343 -499 1178 1321 1148 1587 1401 706 -2111 -2878 -3043 -959 -417 23 1522 494 -127 -1491 -1733 -1634 -1532 -1235 -1113 64 257 1939 2210 2498 1449 1141 335 -1429 -1005 -1218 577 685 714 1052 637 615 -198 18 -1024 -929 -1014 -1125 -849 -1276 -950 -1595 -53 184 392 1362 370 861 312 170 -1129 -307 593 -945 -114 -972 -101 -623 309 113 -958 0 -895 440 -852 446 329 69 404 -111 -50 318 73 340 662 624 -184 261 -1639 -41 -745 -266 798 635 -1509 -1483 -453 -1774 -453 -450 222 114 -275 737 -76 -76 75 446 -58 -265 -571 -870 975 342 1226 276 1189 1260 -710 650 -566 1426 1201 2784 1576 667 6 -1156 300 -296 1592 143 1518 1457 190 129 -2031 -2180 -3313 -2805 -2265 -2293 -1602 -2077 -326 -509 1262 1455 1298 1774 1529 719 -2071 -2666 -2829 -941 -444 27 1919 657 -166 -1846 -2030 -1846 -1802 -1557 -1451 87 365 2830 3445 4082 2363 1835 507 -2087 -1400 -1718 840 1044 1143 1696 1014 951 -301 26 -1460 -1281 -1440 -1688 -1339 -2130 -1632 -2843 -95 352 768 2714 757 1751 621 332 -2155 SS 20220721T121929.5Z 8237.513536 256 1 49.27 2 63.90 83.62 26.56 205.83 0.00 1 0.00 1 0 17 2.396e-02 1.215e-02 1.084e-02 1.987e-03 2.918914e-01 1.052931e-03 3.666407e-03 -6.000000e+00 1.447011e-02 232.45 -2.00 3.45 -2.00 318.49 0.00e+00 8.975782e-04 2.097053e-04 1.352683e-03 -6.000000e+00 6.451225e-04 291.32 -2.00 20.00 -2.00 317.60 0.00e+00 2.259 0.000 302.00 328.00 3 3.7997e+00 2.8671e-03 2.7611e-02 -6.0000e+00 3.6245e-02 -3.7497e-02 3.2583e-03 1.6528e-02 -6.0000e+00 3.8961e-02 7.9790e-03 2.1096e-03 7.4713e-03 -6.0000e+00 2.3242e-02 -1.1065e-02 1.0939e-03 2.0814e-03 -6.0000e+00 9.9913e-03 8.8194e-04 -3.1874e-04 6.2413e-05 2.2482e-05 -6.0000e+00 6.9608e-04 -3.0237e-02 1.2661e-04 12 8 8 10 0 0 98.73 23.91 0.35 -0.03024 -0.03263 37 8 1 5 0 1331.510 25.79 20.01 23.91 34.39 9.8 1082.94 4106 -2809 980 -7516 -6975 -7345 -3738 -3635 -4146 -4786 -11297 -3283 -2875 -886 -419 1905 -198 -2159 4471 -568 999 -70 964 -268 1468 2553 -622 -2149 -2527 -2110 -637 -94 -1248 -3310 -5524 -6629 -4873 -1995 305 -399 734 326 301 538 260 559 102 -207 -1608 134 236 625 1815 1562 1630 932 1013 111 -274 395 1596 2497 3744 2865 883 -575 -1456 -1107 822 982 1954 1351 1008 559 -1031 -1962 -4020 -4344 -3478 -2346 -2281 -1969 -2103 -1202 -21 355 1339 1531 1683 1389 86 -1510 -2571 -2670 -1681 -512 637 684 735 -204 -1326 -2120 -1628 -1169 -1242 -813 -204 95 1557 2115 2273 1745 1309 229 -723 -811 -1069 1 670 595 845 666 703 646 -55 -1214 -1095 -785 -628 -449 -985 -988 -760 -355 -166 234 799 731 636 461 -444 -799 221 -176 60 -467 -393 -408 -216 -236 -298 -361 -915 -261 -260 -91 -49 239 -27 -313 634 -88 155 -11 155 -46 262 465 -116 -384 -432 -363 -116 -19 -271 -739 -1203 -1473 -1181 -555 99 -150 297 139 132 238 116 248 45 -90 -700 59 110 312 951 864 929 548 549 60 -162 233 974 1485 2387 1939 600 -370 -892 -677 536 717 1530 1102 818 435 -754 -1307 -2764 -2933 -2270 -1708 -1864 -1762 -2010 -1204 -22 401 1575 1842 2008 1590 93 -1507 -2418 -2506 -1675 -560 768 905 1013 -277 -1705 -2546 -1883 -1406 -1608 -1107 -291 130 2222 3201 3597 2787 2017 333 -983 -1151 -1534 1 976 913 1312 1021 1045 921 -82 -1748 -1523 -1115 -954 -669 -1550 -1601 -1263 -616 -306 448 1562 1458 1267 897 -840 -1467 SS 20220721T122841.5Z 8237.519924 262 1 48.71 2 62.10 84.94 27.37 210.33 0.00 1 0.00 1 0 17 2.167e-02 1.221e-02 6.482e-03 1.430e-03 2.756538e-01 7.607420e-04 3.497329e-03 -6.000000e+00 1.308370e-02 232.45 -2.00 3.45 -2.00 318.16 0.00e+00 1.209900e-03 1.365316e-04 1.197904e-03 -6.000000e+00 5.832336e-04 291.32 -2.00 20.00 -2.00 317.27 0.00e+00 2.126 0.000 302.00 328.00 3 3.3862e+00 2.0570e-03 2.5974e-02 -6.0000e+00 3.2772e-02 -3.1667e-02 2.3213e-03 1.5314e-02 -6.0000e+00 3.5227e-02 5.7803e-03 1.4582e-03 7.0802e-03 -6.0000e+00 2.1015e-02 -1.2280e-02 7.4596e-04 1.8982e-03 -6.0000e+00 9.0351e-03 1.5530e-03 -4.2817e-04 4.4393e-05 2.1749e-05 -6.0000e+00 6.2931e-04 -3.1291e-02 1.1917e-04 12 8 8 10 0 0 99.28 24.00 0.44 -0.03129 -0.03451 59 13 1 5 0 825.490 26.00 20.01 24.00 35.05 9.8 1088.95 426 -1643 413 -4613 -8610 -5126 -3885 -2175 -6094 -2884 -7278 -4626 -1568 -500 1936 627 880 277 148 1528 1300 1710 483 1945 970 569 -1356 -2323 -1696 -1697 -1293 -263 -726 -5427 -5738 -6914 -4392 -2119 -689 487 220 366 802 570 1162 574 356 -360 -468 -47 443 515 1727 1777 1395 1886 496 -363 -414 101 1694 2601 3600 2820 1061 -798 -1590 -1137 462 1147 1635 1750 1073 658 -762 -2488 -3786 -4299 -3321 -2690 -1938 -2070 -2193 -1138 -400 813 1288 1789 1549 1059 52 -1625 -2154 -2300 -1397 -445 664 820 525 -163 -1297 -1981 -1479 -1170 -1382 -871 -451 114 1401 1971 2273 1648 1388 36 -631 -745 -704 173 419 606 703 889 607 299 142 -1162 -1072 -962 -904 -627 -822 -1044 -873 -149 -179 257 951 733 429 333 -197 -767 30 -127 32 -345 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