File name: Pandora40s1_WallopsIslandVA_20220821_L2Fit_fwvt1c9d20220711p1-8.txt File generation date: 20260321T165038.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: John Moisan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 40 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora40_OF_v3d20210309.txt Instrument calibration file used: Pandora40s1_CF_v9d20220711.txt Level 1 file used: Pandora40s1_WallopsIslandVA_20220821_L1_smca1c9d20220711p1-8.txt.bz2 Full location name: Wallops Island X-75 Station, Wallops Flight Facility Geophysical Observatory Short location name: WallopsIslandVA Country of location: USA Location latitude [deg]: 37.8439 Location longitude [deg]: -75.4775 Location altitude [m]: 11 Local noon date: 20220821 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 8 "New VP from L6 L7" update Field Cal First and last pixel inside fitting window: 1651 1801 Nominal wavelengths inside fitting window [nm]: 492.0076 492.1285 492.2494 492.3702 492.4910 492.6119 492.7327 492.8534 492.9742 493.0949 493.2157 493.3364 493.4571 493.5777 493.6984 493.8190 493.9396 494.0603 494.1808 494.3014 494.4220 494.5425 494.6630 494.7835 494.9040 495.0244 495.1449 495.2653 495.3857 495.5061 495.6265 495.7468 495.8672 495.9875 496.1078 496.2281 496.3483 496.4686 496.5888 496.7090 496.8292 496.9494 497.0695 497.1897 497.3098 497.4299 497.5500 497.6700 497.7901 497.9101 498.0301 498.1501 498.2701 498.3901 498.5100 498.6300 498.7499 498.8697 498.9896 499.1095 499.2293 499.3491 499.4689 499.5887 499.7085 499.8282 499.9479 500.0676 500.1873 500.3070 500.4267 500.5463 500.6659 500.7855 500.9051 501.0247 501.1442 501.2638 501.3833 501.5028 501.6222 501.7417 501.8611 501.9805 502.0999 502.2193 502.3387 502.4580 502.5774 502.6967 502.8160 502.9353 503.0545 503.1738 503.2930 503.4122 503.5314 503.6505 503.7697 503.8888 504.0079 504.1270 504.2461 504.3651 504.4842 504.6032 504.7222 504.8412 504.9602 505.0791 505.1980 505.3170 505.4358 505.5547 505.6736 505.7924 505.9112 506.0300 506.1488 506.2676 506.3863 506.5051 506.6238 506.7425 506.8611 506.9798 507.0984 507.2170 507.3356 507.4542 507.5728 507.6913 507.8099 507.9284 508.0469 508.1653 508.2838 508.4022 508.5206 508.6390 508.7574 508.8758 508.9941 509.1124 509.2308 509.3490 509.4673 509.5856 509.7038 509.8220 509.9402 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20220821T103904.8Z 8268.443805 213 1 50.17 2 87.68 76.53 26.94 107.60 0.00 1 0.00 1 0 22 5.162e-03 5.086e-03 1.022e-03 1.017e-03 2.785453e+04 8.654406e+01 1.741511e+03 -6.000000e+00 3.057748e+02 291.51 -2.00 20.00 -2.00 505.41 0.00e+00 1.903190e-03 2.931358e-05 1.344893e-04 -6.000000e+00 1.497787e-04 291.51 -2.00 20.00 -2.00 500.51 0.00e+00 1.750824e+00 2.047936e-02 1.447366e-01 -6.000000e+00 1.035042e-01 231.20 -2.00 3.45 -2.00 502.11 0.00e+00 15.112 0.059 489.00 513.00 1 5.1007e+00 1.5749e-03 2.6517e-02 -6.0000e+00 7.9803e-03 -4.7045e-03 3.8650e-04 3.9087e-03 -6.0000e+00 2.0372e-03 1.1276e-03 5.5916e-04 9.1690e-05 1.1710e-04 -6.0000e+00 5.8150e-04 7.4607e-03 -3.6412e-05 12 9 9 12 4 4 71.18 44.04 2.95 0.00746 0.01134 15 3 1 4 0 3344.420 -99.00 20.00 44.04 29.80 10.4 1043.74 -1142 -665 -150 155 162 466 791 785 548 678 35 -144 -439 -521 -551 -782 -366 -179 210 455 217 242 478 428 525 866 555 40 -115 -495 -544 -822 -74 41 208 267 119 -161 -394 -300 -307 204 150 325 493 486 361 230 -231 -196 -828 -998 -1215 -961 -544 -69 79 -137 81 289 499 337 750 253 636 499 -37 -83 -420 -194 -515 -120 -239 -12 278 -159 -174 -847 -593 -508 -115 -288 -33 -25 -98 113 -484 31 360 485 715 965 941 900 942 291 605 -33 -285 -848 -708 -976 -1034 -693 -435 -374 -710 -626 -312 -503 -264 -464 -239 6 436 849 968 990 602 190 -248 -127 30 73 605 552 248 111 651 -160 -250 -72 -731 -751 -409 -483 -484 -26 -27 12 562 87 502 687 562 541 250 193 -543 -517 -754 -1078 -629 -145 147 159 468 808 813 571 702 36 -147 -443 -521 -547 -780 -368 -183 210 464 224 251 495 446 549 905 580 42 -118 -498 -537 -810 -74 41 217 284 127 -172 -416 -314 -322 213 159 347 512 508 377 239 -237 -205 -851 -1003 -1205 -952 -546 -71 83 -141 83 299 515 349 777 264 659 512 -37 -84 -416 -197 -521 -121 -242 -12 274 -158 -170 -851 -585 -495 -111 -279 -32 -25 -98 109 -472 29 344 478 702 912 893 847 898 267 529 -28 -245 -724 -602 -812 -895 -632 -402 -359 -698 -616 -305 -494 -261 -463 -240 6 433 844 974 1014 605 192 -247 -129 30 72 593 544 246 111 647 -154 -250 -71 -719 -734 -401 -463 -473 -26 -27 13 585 92 536 709 580 555 255 195 -567 -536 -761 SQ 20220821T104233.9Z 8268.446225 216 1 49.52 2 87.02 77.06 26.29 108.53 0.00 1 0.00 1 0 29 4.735e-03 4.672e-03 8.471e-04 8.435e-04 2.517283e+04 7.065485e+01 1.579185e+03 -6.000000e+00 2.805249e+02 291.51 -2.00 20.00 -2.00 505.38 0.00e+00 1.620575e-03 2.419922e-05 1.179459e-04 -6.000000e+00 1.374181e-04 291.51 -2.00 20.00 -2.00 500.47 0.00e+00 1.562396e+00 1.695240e-02 1.337796e-01 -6.000000e+00 9.497070e-02 231.20 -2.00 3.45 -2.00 502.06 0.00e+00 13.492 0.042 489.00 513.00 1 5.0234e+00 1.3027e-03 2.3408e-02 -6.0000e+00 7.3222e-03 -3.2191e-03 3.2154e-04 3.5612e-03 -6.0000e+00 1.8695e-03 1.5695e-03 6.7146e-04 7.7894e-05 1.1266e-04 -6.0000e+00 5.3339e-04 -7.8811e-03 4.3975e-05 12 9 9 12 4 4 91.47 43.91 2.75 -0.00788 -0.00322 20 4 1 4 0 2475.960 24.56 20.00 43.91 30.10 10.4 1044.84 -1037 -728 -320 -29 186 402 854 761 284 598 81 -256 -367 -459 -507 -716 -303 -17 81 286 161 184 460 566 592 765 505 -44 -213 -365 -504 -701 37 75 308 320 -29 -139 -318 -204 -281 135 221 307 436 369 494 214 -248 -366 -889 -945 -839 -791 -583 -117 89 -50 218 192 597 368 555 233 514 355 242 -81 -405 -80 -423 -185 -126 -23 272 -160 -262 -730 -627 -411 -148 -274 -243 95 -92 9 -290 9 143 463 846 1018 475 864 659 518 593 7 -209 -584 -840 -980 -860 -584 -512 -218 -614 -440 -374 -618 -356 -446 -149 190 381 814 891 986 602 376 -133 -24 168 78 375 482 226 52 527 12 -215 -204 -816 -733 -581 -559 -351 -8 -44 112 327 127 335 385 536 458 244 211 -495 -388 -669 -997 -702 -302 -28 185 411 888 771 291 607 82 -256 -377 -467 -513 -726 -310 -17 83 297 169 194 485 599 629 814 537 -47 -223 -373 -505 -700 37 78 326 332 -31 -144 -328 -209 -298 138 228 320 458 390 522 225 -258 -374 -924 -959 -837 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-6.0000e+00 1.6255e-03 3.2244e-03 7.1092e-04 5.3520e-05 9.1027e-05 -6.0000e+00 4.6370e-04 -2.5612e-03 4.2245e-06 12 9 1 12 4 4 91.55 46.87 2.42 -0.00256 0.00237 35 8 1 4 0 1397.200 24.56 20.00 46.87 30.84 10.4 1049.18 -1121 -721 -302 -126 187 287 511 524 261 407 -24 -221 -343 -382 -503 -544 -250 -69 116 325 207 291 509 497 497 620 351 -13 -192 -286 -511 -509 45 107 205 274 48 -99 -92 -126 -165 129 268 297 389 519 435 219 -158 -316 -595 -897 -876 -663 -375 -168 101 49 176 330 433 481 498 353 329 389 212 -115 -264 -160 -319 -128 -195 -16 7 -65 -283 -497 -572 -429 -276 -421 -293 -293 -117 -8 -259 -10 96 199 639 629 536 756 708 369 390 14 -194 -504 -717 -807 -647 -552 -416 -218 -636 -494 -305 -366 -320 -224 -97 206 533 854 948 787 609 191 127 232 206 182 329 404 203 93 349 -182 -20 18 -522 -622 -319 -643 -351 -131 -139 26 114 134 270 482 338 214 117 -31 -330 -535 -622 -1093 -704 -290 -124 190 288 523 544 272 422 -25 -224 -345 -380 -498 -538 -250 -70 120 342 221 301 526 515 518 647 366 -13 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