File name: Pandora40s1_WallopsIslandVA_20220830_L2Fit_fout2c9d20220711p1-8.txt File generation date: 20260321T164943.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: John Moisan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 40 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora40_OF_v3d20210309.txt Instrument calibration file used: Pandora40s1_CF_v9d20220711.txt Level 1 file used: Pandora40s1_WallopsIslandVA_20220830_L1_smca1c9d20220711p1-8.txt.bz2 Full location name: Wallops Island X-75 Station, Wallops Flight Facility Geophysical Observatory Short location name: WallopsIslandVA Country of location: USA Location latitude [deg]: 37.8439 Location longitude [deg]: -75.4775 Location altitude [m]: 11 Local noon date: 20220830 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 8 "New VP from L6 L7" update Field Cal First and last pixel inside fitting window: 231 372 Nominal wavelengths inside fitting window [nm]: 305.1289 305.2698 305.4107 305.5516 305.6924 305.8333 305.9741 306.1150 306.2558 306.3966 306.5374 306.6782 306.8189 306.9597 307.1004 307.2412 307.3819 307.5226 307.6633 307.8040 307.9447 308.0853 308.2260 308.3666 308.5073 308.6479 308.7885 308.9291 309.0697 309.2103 309.3508 309.4914 309.6319 309.7724 309.9129 310.0535 310.1939 310.3344 310.4749 310.6154 310.7558 310.8962 311.0367 311.1771 311.3175 311.4579 311.5982 311.7386 311.8789 312.0193 312.1596 312.2999 312.4402 312.5805 312.7208 312.8611 313.0014 313.1416 313.2818 313.4221 313.5623 313.7025 313.8427 313.9828 314.1230 314.2632 314.4033 314.5434 314.6836 314.8237 314.9638 315.1039 315.2439 315.3840 315.5240 315.6641 315.8041 315.9441 316.0841 316.2241 316.3641 316.5041 316.6440 316.7840 316.9239 317.0638 317.2037 317.3436 317.4835 317.6234 317.7633 317.9031 318.0430 318.1828 318.3226 318.4624 318.6022 318.7420 318.8818 319.0215 319.1613 319.3010 319.4407 319.5804 319.7201 319.8598 319.9995 320.1392 320.2788 320.4185 320.5581 320.6977 320.8373 320.9769 321.1165 321.2561 321.3956 321.5352 321.6747 321.8142 321.9538 322.0933 322.2328 322.3722 322.5117 322.6512 322.7906 322.9300 323.0695 323.2089 323.3483 323.4876 323.6270 323.7664 323.9057 324.0451 324.1844 324.3237 324.4630 324.6023 324.7416 324.8809 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220830T141854.2Z 8277.596461 155 1 50.78 2 46.83 117.47 83.10 100.91 0.00 1 0.00 1 0 17 1.581e-02 1.199e-02 5.577e-03 2.501e-03 1.904186e-01 1.317526e-03 2.352014e-03 -6.000000e+00 9.458792e-03 230.53 -2.00 3.45 -2.00 316.58 0.00e+00 6.544554e-04 1.602121e-04 4.336263e-04 -6.000000e+00 4.249757e-04 290.91 -2.00 20.00 -2.00 315.73 0.00e+00 1.459 0.000 302.00 328.00 3 5.2446e+00 3.4480e-03 1.7548e-02 -6.0000e+00 2.3581e-02 2.0030e-02 3.8416e-03 9.7248e-03 -6.0000e+00 2.5405e-02 4.3302e-03 2.2313e-03 4.6852e-03 -6.0000e+00 1.5176e-02 -9.7645e-03 1.0560e-03 1.3110e-03 -6.0000e+00 6.5308e-03 5.2983e-04 -2.9937e-04 7.6549e-05 1.8153e-05 -6.0000e+00 4.5929e-04 -1.3847e-02 1.5103e-04 12 9 9 12 4 4 6.27 50.83 0.39 -0.01385 -0.01610 13 3 1 5 0 3905.800 24.86 20.00 50.83 36.16 10.7 1088.94 -452 2662 1973 -547 -1203 -3002 -2010 -3415 -1184 -4699 -1059 86 1442 276 -20 -807 -213 238 464 2391 1546 1363 562 -549 1262 415 598 -1458 -1465 -1184 -1511 -150 -216 -2927 -6034 -4749 -3615 -1098 549 617 181 73 150 241 825 598 -718 -444 -825 -364 830 1010 1791 1357 1642 928 523 -487 -131 2 1523 2478 3426 1641 291 -492 -1257 -1179 309 504 1883 1203 941 -188 -466 -2144 -3730 -3727 -3750 -2063 -2653 -1598 -2289 -525 23 836 1090 1337 1511 815 290 -1361 -1570 -1827 -1485 -307 652 1106 332 -102 -959 -2034 -1721 -1208 -1700 -1065 -216 148 1294 2063 1820 1980 967 -124 -1090 -508 -824 -76 610 511 632 964 536 418 426 -824 -764 -523 -892 -572 -946 -238 -418 -187 56 293 878 348 268 102 -276 -987 -81 488 368 -95 -190 -474 -336 -645 -237 -994 -213 18 325 71 -6 -242 -65 75 150 794 521 458 195 -202 463 157 224 -519 -490 -391 -525 -55 -83 -1140 -2290 -1801 -1505 -512 298 369 117 49 102 164 556 399 -471 -281 -511 -226 536 690 1272 1005 1238 716 399 -372 -101 2 1212 2051 3002 1508 261 -406 -996 -928 254 461 1785 1182 917 -181 -414 -1779 -2869 -2841 -2972 -1792 -2514 -1626 -2425 -577 27 1014 1355 1693 1889 995 334 -1444 -1575 -1817 -1563 -344 781 1428 436 -133 -1173 -2397 -1985 -1463 -2179 -1427 -294 209 1898 3097 2821 3024 1440 -172 -1435 -649 -1069 -101 866 751 943 1415 767 582 563 -1068 -956 -666 -1205 -796 -1370 -348 -614 -287 89 481 1477 588 451 171 -451 -1578 SS 20220830T142448.5Z 8277.600561 158 1 48.96 2 45.80 118.91 82.00 101.85 0.00 1 0.00 1 0 17 1.628e-02 1.214e-02 5.449e-03 2.475e-03 1.906599e-01 1.305109e-03 2.334402e-03 -6.000000e+00 9.739731e-03 230.53 -2.00 3.45 -2.00 316.55 0.00e+00 9.434208e-04 1.571732e-04 3.894200e-04 -6.000000e+00 4.377189e-04 290.91 -2.00 20.00 -2.00 315.70 0.00e+00 1.432 0.000 302.00 328.00 3 5.2236e+00 3.4110e-03 1.7323e-02 -6.0000e+00 2.4282e-02 2.6390e-02 3.8000e-03 9.6797e-03 -6.0000e+00 2.6162e-02 1.0031e-03 2.2088e-03 4.6898e-03 -6.0000e+00 1.5628e-02 -1.0085e-02 1.0434e-03 1.2953e-03 -6.0000e+00 6.7242e-03 5.5374e-04 -7.2946e-04 7.5529e-05 1.7226e-05 -6.0000e+00 4.7314e-04 -1.5321e-02 1.7219e-05 12 9 9 12 4 4 27.83 50.03 0.42 -0.01532 -0.02080 13 3 1 5 0 3766.030 24.86 20.00 50.03 36.05 10.7 1088.60 460 1431 1075 -2582 -1531 -1563 1281 -1787 -892 -5141 -2740 -3012 535 737 2146 822 -137 2254 1173 442 225 395 1527 150 2210 -525 -245 -1102 -2335 -1024 116 1109 -1159 -2690 -4163 -6548 -3668 -2024 18 -584 788 308 1054 18 1068 149 -155 -254 -1283 -174 421 89 1565 1784 1265 1431 167 -427 206 474 1512 3005 3245 2083 592 -1034 -1367 -1715 243 851 1371 909 937 759 -478 -2287 -4155 -4132 -3298 -2542 -2348 -1789 -2026 -679 -269 320 1053 1656 1541 1155 200 -1182 -1983 -2198 -1259 66 679 988 500 -16 -1154 -2221 -1311 -1325 -1067 -976 -487 267 1179 1987 1849 1834 685 -25 -688 -138 -492 -324 497 337 823 790 600 203 116 -759 -1007 -509 -776 -385 -1114 -399 -483 -193 83 300 663 560 468 289 -270 -1209 83 271 201 -471 -249 -249 212 -340 -182 -1113 -570 -653 124 193 597 246 -43 704 382 149 76 133 520 54 812 -202 -91 -397 -802 -344 41 408 -458 -1065 -1580 -2575 -1512 -963 10 -355 506 206 711 12 720 100 -102 -161 -801 -109 274 61 1117 1319 959 1100 131 -333 158 365 1204 2532 2835 1897 526 -878 -1086 -1358 205 771 1327 909 926 718 -434 -1899 -3207 -3180 -2600 -2217 -2204 -1810 -2170 -737 -312 382 1311 2093 1929 1414 227 -1269 -1982 -2176 -1311 74 818 1286 655 -21 -1425 -2656 -1525 -1584 -1367 -1281 -665 377 1731 2969 2851 2791 1024 -35 -907 -173 -627 -434 692 495 1226 1162 857 285 155 -969 -1277 -655 -1032 -538 -1583 -573 -710 -295 131 491 1111 956 798 482 -439 -1927 SS 20220830T143040.0Z 8277.604629 161 1 50.52 2 44.80 120.37 80.92 102.78 0.00 1 0.00 1 0 17 1.763e-02 1.222e-02 5.318e-03 2.446e-03 1.884938e-01 1.287791e-03 2.305733e-03 -6.000000e+00 1.054486e-02 230.53 -2.00 3.45 -2.00 316.54 0.00e+00 9.817818e-04 1.542729e-04 4.067056e-04 -6.000000e+00 4.739691e-04 290.91 -2.00 20.00 -2.00 315.69 0.00e+00 1.407 0.000 302.00 328.00 3 5.2265e+00 3.3679e-03 1.7032e-02 -6.0000e+00 2.6289e-02 2.6615e-02 3.7519e-03 9.5251e-03 -6.0000e+00 2.8326e-02 -1.8987e-03 2.1748e-03 4.6097e-03 -6.0000e+00 1.6920e-02 -1.0864e-02 1.0247e-03 1.2714e-03 -6.0000e+00 7.2790e-03 5.6912e-04 -9.1170e-04 7.4748e-05 1.7138e-05 -6.0000e+00 5.1234e-04 -1.3854e-02 2.3443e-05 12 9 9 12 4 4 9.47 50.61 0.54 -0.01385 -0.02070 14 3 1 5 0 3608.300 24.96 20.00 50.61 36.11 10.7 1089.47 1624 -618 1416 -4998 -3113 -2371 -3530 -776 337 -4537 -5379 -3036 -859 -1950 1714 584 1860 1220 2228 2147 1081 1645 1451 2972 1313 1301 -1292 -1336 -1331 -1549 -863 -236 288 -4281 -4394 -4708 -4613 -374 -44 667 48 -76 271 -168 788 579 576 -815 -1116 524 733 368 667 1507 1027 1109 492 61 -358 68 1793 2027 3176 1769 280 -653 -1323 -937 449 1225 1565 1633 1014 431 -115 -2393 -4018 -4383 -3034 -2797 -2269 -2353 -2245 -980 -295 476 1178 1628 1272 1325 -54 -1350 -1839 -2063 -1004 -301 681 955 309 -310 -1469 -1837 -1748 -718 -1098 -714 -311 50 1331 1838 2109 1533 848 276 -355 -299 -888 35 260 832 727 973 756 197 186 -1061 -523 -1208 -732 -878 -807 -711 -563 54 -220 505 838 706 303 162 -406 -922 301 -123 273 -936 -516 -382 -615 -146 68 -976 -1148 -658 -202 -522 491 180 581 395 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