File name: Pandora40s1_WallopsIslandVA_20220911_L2Fit_fout2c9d20220711p1-8.txt File generation date: 20260321T165709.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: John Moisan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 40 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora40_OF_v3d20210309.txt Instrument calibration file used: Pandora40s1_CF_v9d20220711.txt Level 1 file used: Pandora40s1_WallopsIslandVA_20220911_L1_smca1c9d20220711p1-8.txt.bz2 Full location name: Wallops Island X-75 Station, Wallops Flight Facility Geophysical Observatory Short location name: WallopsIslandVA Country of location: USA Location latitude [deg]: 37.8439 Location longitude [deg]: -75.4775 Location altitude [m]: 11 Local noon date: 20220911 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 8 "New VP from L6 L7" update Field Cal First and last pixel inside fitting window: 231 372 Nominal wavelengths inside fitting window [nm]: 305.1289 305.2698 305.4107 305.5516 305.6924 305.8333 305.9741 306.1150 306.2558 306.3966 306.5374 306.6782 306.8189 306.9597 307.1004 307.2412 307.3819 307.5226 307.6633 307.8040 307.9447 308.0853 308.2260 308.3666 308.5073 308.6479 308.7885 308.9291 309.0697 309.2103 309.3508 309.4914 309.6319 309.7724 309.9129 310.0535 310.1939 310.3344 310.4749 310.6154 310.7558 310.8962 311.0367 311.1771 311.3175 311.4579 311.5982 311.7386 311.8789 312.0193 312.1596 312.2999 312.4402 312.5805 312.7208 312.8611 313.0014 313.1416 313.2818 313.4221 313.5623 313.7025 313.8427 313.9828 314.1230 314.2632 314.4033 314.5434 314.6836 314.8237 314.9638 315.1039 315.2439 315.3840 315.5240 315.6641 315.8041 315.9441 316.0841 316.2241 316.3641 316.5041 316.6440 316.7840 316.9239 317.0638 317.2037 317.3436 317.4835 317.6234 317.7633 317.9031 318.0430 318.1828 318.3226 318.4624 318.6022 318.7420 318.8818 319.0215 319.1613 319.3010 319.4407 319.5804 319.7201 319.8598 319.9995 320.1392 320.2788 320.4185 320.5581 320.6977 320.8373 320.9769 321.1165 321.2561 321.3956 321.5352 321.6747 321.8142 321.9538 322.0933 322.2328 322.3722 322.5117 322.6512 322.7906 322.9300 323.0695 323.2089 323.3483 323.4876 323.6270 323.7664 323.9057 324.0451 324.1844 324.3237 324.4630 324.6023 324.7416 324.8809 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220911T165450.3Z 8289.704749 427 1 49.18 2 33.48 178.35 139.98 332.07 0.00 1 0.00 1 0 17 1.741e-02 1.290e-02 4.692e-03 2.624e-03 1.566312e-01 1.381862e-03 1.911799e-03 -6.000000e+00 1.037949e-02 229.64 -2.00 3.45 -2.00 315.87 0.00e+00 7.586842e-04 1.434711e-04 2.622210e-04 -6.000000e+00 4.663505e-04 290.10 -2.00 20.00 -2.00 315.09 0.00e+00 1.198 0.000 302.00 328.00 3 5.5031e+00 3.5799e-03 1.4341e-02 -6.0000e+00 2.5828e-02 3.6761e-02 3.9757e-03 7.8369e-03 -6.0000e+00 2.7850e-02 -5.1780e-03 2.2865e-03 3.8060e-03 -6.0000e+00 1.6640e-02 -9.6269e-03 1.0466e-03 1.0562e-03 -6.0000e+00 7.1667e-03 5.6655e-04 4.9719e-05 7.9846e-05 1.5558e-05 -6.0000e+00 5.0564e-04 -1.1710e-02 1.7888e-04 12 9 9 12 4 4 99.86 80.01 0.42 -0.01171 -0.01134 18 4 1 5 0 2731.740 24.65 20.00 80.01 32.49 10.8 1059.74 4913 735 -410 -3674 -3225 -2374 -2107 1004 -1530 -1732 -3277 -1958 -2267 -990 1917 209 2268 1000 3246 1582 1228 754 609 2271 488 1358 -1456 -349 -3127 -1134 -344 -725 544 -4097 -4981 -5600 -4162 -1406 111 644 17 979 10 439 435 -119 -251 -785 -1118 -140 1485 687 1230 1669 1061 1758 417 414 -355 128 1040 1891 2848 1992 757 -592 -1436 -1256 -287 977 1377 1303 1215 769 -821 -2337 -4303 -4340 -3386 -3376 -1627 -2281 -1974 -975 -98 436 1289 1495 1642 1335 123 -876 -1983 -2375 -1052 -354 823 796 799 -154 -1204 -1615 -1847 -1269 -1103 -717 -847 288 1593 1922 2084 1083 1349 -173 -801 -1368 -762 101 618 808 621 1170 579 323 -58 -1366 -543 -662 -590 -609 -265 -595 -827 -308 -377 503 986 799 212 342 -455 -1064 1174 192 -106 -911 -715 -509 -481 247 -415 -476 -894 -543 -692 -333 688 78 871 387 1293 639 512 314 259 987 218 626 -668 -147 -1265 -443 -139 -309 239 -1846 -2132 -2440 -1983 -763 68 441 12 715 7 327 322 -89 -183 -552 -766 -95 1041 511 950 1328 864 1440 339 342 -292 106 865 1669 2648 1912 702 -520 -1180 -1020 -250 909 1367 1331 1227 746 -745 -1985 -3390 -3393 -2703 -2992 -1564 -2323 -2110 -1088 -114 535 1642 1892 2102 1626 142 -928 -2005 -2377 -1100 -392 989 1008 1036 -195 -1472 -1854 -2098 -1516 -1378 -939 -1159 406 2314 2843 3154 1625 1951 -234 -1025 -1683 -944 131 836 1154 904 1674 809 442 -76 -1709 -666 -806 -757 -822 -367 -840 -1165 -450 -582 784 1571 1299 346 545 -727 -1665 SS 20220911T171629.6Z 8289.719787 442 1 7.81 2 33.73 188.10 141.56 339.86 0.00 1 0.00 1 0 17 1.628e-02 1.334e-02 7.525e-03 5.236e-03 1.544249e-01 2.793393e-03 1.906634e-03 -6.000000e+00 9.700147e-03 229.64 -2.00 3.45 -2.00 314.87 0.00e+00 1.120381e-03 2.382117e-04 1.485084e-04 -6.000000e+00 4.360567e-04 290.10 -2.00 20.00 -2.00 314.20 0.00e+00 1.202 0.000 302.00 328.00 3 5.1992e+00 7.1616e-03 1.4354e-02 -6.0000e+00 2.4137e-02 2.6795e-02 7.9085e-03 7.8917e-03 -6.0000e+00 2.6032e-02 -1.2749e-03 4.5392e-03 3.7814e-03 -6.0000e+00 1.5554e-02 -9.1023e-03 2.0192e-03 1.0833e-03 -6.0000e+00 6.6952e-03 7.6828e-04 -4.6430e-04 1.5684e-04 1.6384e-05 -6.0000e+00 4.7297e-04 -1.0556e-02 4.7180e-05 12 9 9 12 5 5 999.00 80.76 0.47 -0.01056 -0.01404 1 3 1 5 0 3818.780 24.65 20.00 80.76 32.51 10.7 1058.55 416 269 -933 -1796 -1814 -4693 -1442 -5104 1590 -1958 -2115 932 2228 984 1222 542 1519 -514 1684 894 1421 346 1459 1879 1163 78 -223 -1401 -2813 -526 123 1207 -914 -3326 -2420 -5702 -4164 -361 293 29 -370 -600 1163 522 1366 735 1503 -610 -822 535 945 1556 2281 843 988 384 -142 -49 85 343 1210 1982 2994 2253 1075 -1789 -1471 -646 -349 887 1066 1369 1122 710 -877 -1625 -3088 -4384 -3214 -4126 -2463 -1876 -2067 -1474 745 1285 677 891 1054 254 439 -563 -2578 -1439 -1513 -1221 1046 1188 139 -508 -870 -1932 -1050 -1000 -1516 -227 -156 1033 1618 2019 1967 2227 855 257 -287 202 -908 -542 569 584 892 1034 310 881 -114 -1637 -543 -1030 -322 -471 -99 -463 -214 -118 358 283 743 329 92 120 -516 -1527 145 96 -337 -603 -559 -1452 -461 -1805 565 -728 -770 340 882 425 569 263 744 -263 863 465 736 183 765 1019 646 45 -125 -751 -1433 -263 63 639 -507 -1851 -1279 -3154 -2437 -231 209 22 -298 -500 969 438 1130 602 1199 -485 -635 416 754 1281 1918 733 871 340 -127 -44 75 306 1104 1870 2934 2246 1048 -1677 -1311 -574 -325 872 1106 1435 1165 717 -851 -1487 -2685 -3735 -2827 -3954 -2459 -1985 -2248 -1660 858 1530 840 1112 1314 306 503 -612 -2701 -1490 -1616 -1370 1230 1469 175 -631 -1037 -2235 -1204 -1184 -1868 -287 -204 1366 2202 2799 2764 3099 1162 334 -354 243 -1105 -686 748 792 1214 1404 411 1132 -144 -2013 -653 -1251 -404 -607 -130 -617 -287 -164 508 409 1088 492 138 176 -746 -2197 SS 20220911T173505.9Z 8289.732708 448 1 48.49 2 34.51 196.26 142.48 346.93 0.00 1 0.00 1 0 25 1.580e-02 1.229e-02 3.525e-03 2.058e-03 1.576448e-01 1.085676e-03 1.924407e-03 -6.000000e+00 9.417064e-03 229.64 -2.00 3.45 -2.00 315.68 0.00e+00 6.752072e-04 1.083539e-04 2.614928e-04 -6.000000e+00 4.231715e-04 290.10 -2.00 20.00 -2.00 314.92 0.00e+00 1.213 0.000 302.00 328.00 3 5.2531e+00 2.8078e-03 1.4475e-02 -6.0000e+00 2.3433e-02 3.7290e-02 3.1148e-03 7.8616e-03 -6.0000e+00 2.5269e-02 -4.3360e-03 1.7876e-03 3.8187e-03 -6.0000e+00 1.5098e-02 -8.2498e-03 8.1399e-04 1.0606e-03 -6.0000e+00 6.5018e-03 7.1499e-04 -2.8061e-04 6.2303e-05 1.6216e-05 -6.0000e+00 4.5887e-04 -1.2129e-02 1.1626e-04 12 9 9 12 4 4 98.71 76.86 0.35 -0.01213 -0.01424 13 3 1 5 0 3729.960 24.75 20.00 76.86 33.33 10.8 1065.58 1185 1634 -508 -1786 -3303 -2841 -2594 -67 -840 -3918 -1808 -3820 -562 3 1397 816 999 1300 1949 1900 822 2330 1285 2172 902 781 409 -1795 -1554 -1843 541 151 -719 -3918 -4908 -3576 -3951 -1186 18 173 404 -246 586 64 1095 -354 542 -899 -1061 -467 151 799 666 1414 1289 1543 345 -187 92 -89 1589 2069 3305 1866 657 -586 -1820 -1184 -281 1019 1060 1358 1205 740 -539 -2860 -3693 -3487 -2773 -3049 -1864 -2244 -1682 -545 -406 943 967 1340 1200 1315 153 -1249 -1904 -1959 -1364 -664 537 1179 298 30 -1239 -1507 -1449 -1052 -1356 -671 -357 116 1432 1727 2056 1677 885 -6 -696 -319 -1020 262 720 436 1126 704 608 211 496 -1067 -746 -802 -727 -681 -1114 -620 -740 233 -182 309 1223 556 354 37 -198 -1166 314 450 -140 -452 -786 -656 -638 -17 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