File name: Pandora40s1_WallopsIslandVA_20220921_L2Fit_fout2c9d20220711p1-8.txt File generation date: 20260321T165808.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: John Moisan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 40 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora40_OF_v3d20210309.txt Instrument calibration file used: Pandora40s1_CF_v9d20220711.txt Level 1 file used: Pandora40s1_WallopsIslandVA_20220921_L1_smca1c9d20220711p1-8.txt.bz2 Full location name: Wallops Island X-75 Station, Wallops Flight Facility Geophysical Observatory Short location name: WallopsIslandVA Country of location: USA Location latitude [deg]: 37.8439 Location longitude [deg]: -75.4775 Location altitude [m]: 11 Local noon date: 20220921 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 8 "New VP from L6 L7" update Field Cal First and last pixel inside fitting window: 231 372 Nominal wavelengths inside fitting window [nm]: 305.1289 305.2698 305.4107 305.5516 305.6924 305.8333 305.9741 306.1150 306.2558 306.3966 306.5374 306.6782 306.8189 306.9597 307.1004 307.2412 307.3819 307.5226 307.6633 307.8040 307.9447 308.0853 308.2260 308.3666 308.5073 308.6479 308.7885 308.9291 309.0697 309.2103 309.3508 309.4914 309.6319 309.7724 309.9129 310.0535 310.1939 310.3344 310.4749 310.6154 310.7558 310.8962 311.0367 311.1771 311.3175 311.4579 311.5982 311.7386 311.8789 312.0193 312.1596 312.2999 312.4402 312.5805 312.7208 312.8611 313.0014 313.1416 313.2818 313.4221 313.5623 313.7025 313.8427 313.9828 314.1230 314.2632 314.4033 314.5434 314.6836 314.8237 314.9638 315.1039 315.2439 315.3840 315.5240 315.6641 315.8041 315.9441 316.0841 316.2241 316.3641 316.5041 316.6440 316.7840 316.9239 317.0638 317.2037 317.3436 317.4835 317.6234 317.7633 317.9031 318.0430 318.1828 318.3226 318.4624 318.6022 318.7420 318.8818 319.0215 319.1613 319.3010 319.4407 319.5804 319.7201 319.8598 319.9995 320.1392 320.2788 320.4185 320.5581 320.6977 320.8373 320.9769 321.1165 321.2561 321.3956 321.5352 321.6747 321.8142 321.9538 322.0933 322.2328 322.3722 322.5117 322.6512 322.7906 322.9300 323.0695 323.2089 323.3483 323.4876 323.6270 323.7664 323.9057 324.0451 324.1844 324.3237 324.4630 324.6023 324.7416 324.8809 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220921T112829.8Z 8299.478123 199 1 49.28 2 83.03 94.68 33.11 106.48 0.00 1 0.00 1 0 25 5.313e-01 2.977e-02 4.717e-01 2.829e-02 7.778747e-01 1.749492e-02 9.266873e-03 -6.000000e+00 3.253713e-01 228.78 -2.00 3.45 -2.00 322.13 0.00e+00 5.322672e-03 1.054735e-02 7.567041e-03 -6.000000e+00 1.774474e-02 289.18 -2.00 20.00 -2.00 321.63 0.00e+00 7.542 0.007 302.00 328.00 3 1.6752e+00 7.2628e-02 9.3442e-02 -6.0000e+00 8.1209e-01 7.4283e-01 9.8995e-02 6.2769e-02 -6.0000e+00 8.8359e-01 -1.0864e+00 8.3219e-02 3.2647e-02 -6.0000e+00 5.1871e-01 4.4784e-01 3.8053e-02 9.3537e-03 -6.0000e+00 2.2524e-01 2.5995e-05 -1.4619e-03 9.0642e-04 2.2281e-04 -6.0000e+00 1.6318e-02 -3.7213e-03 -6.6419e-05 12 9 9 12 4 4 89.18 44.92 0.80 -0.00372 -0.01471 17 4 1 5 0 2898.720 24.75 20.00 44.92 27.36 10.7 1016.17 900000 -61080 900000 900000 900000 900000 -173892 900000 -101960 900000 -83603 900000 900000 900000 -36696 107798 900000 -52539 -31113 900000 900000 -8482 900000 900000 -84566 -26020 15204 -29545 -38091 29491 14762 -71886 900000 -8848 68310 -30605 -47562 -19595 5864 302962 82208 175884 -35589 188247 86018 -7845 61109 131126 -3562 45276 69770 7511 28395 68171 16661 2462 -9405 1771 31612 5409 131845 99144 35467 2492 2570 6249 11573 26003 38179 12802 12175 14015 6337 29578 15319 18667 19742 -9318 -11092 -11551 8789 -3973 1303 -9855 2834 12865 3041 3809 4182 912 2650 -1723 -8132 -3540 722 -2526 534 -7870 -800 2349 -4895 -3454 1895 -737 -7597 -735 -822 -1134 -1023 408 16 -961 939 -1928 -1998 -3555 -1505 3282 308 7582 2211 1825 -187 -789 3834 -2634 2434 76 -939 122 -247 139 -10 121 -405 831 1735 897 -906 -1140 -1487 -487 900000 -1680 900000 900000 900000 900000 -6750 900000 -2804 900000 -2299 900000 900000 900000 -1009 2964 900000 -1965 -958 900000 900000 -233 900000 900000 -4372 -759 418 -812 -1154 811 406 -4800 900000 -343 1878 -1391 -2829 -1034 283 8331 2308 4836 -3375 5176 2464 -568 2310 3606 -276 2386 3197 691 2342 4022 1674 291 -1251 204 2644 583 4320 5046 3799 400 423 978 1747 3709 5446 2594 2651 3028 1415 4914 2633 2823 2895 -1975 -2751 -3442 2496 -1449 489 -4408 1191 5169 1403 1767 1901 407 1114 -726 -3690 -1681 382 -1595 382 -6938 -696 1937 -4005 -2569 1267 -523 -6185 -594 -714 -1063 -1082 484 21 -1341 1288 -2643 -2642 -4722 -2023 4444 452 10497 3149 2559 -258 -1066 4788 -3416 3038 107 -1533 219 -488 292 -22 293 -1049 2206 4657 2442 -2458 -2934 -3588 -1101 SS 20220921T113855.2Z 8299.485362 202 1 48.69 2 80.98 96.31 31.20 109.05 0.00 1 0.00 1 0 25 4.590e-01 1.439e-02 3.194e-01 6.912e-03 6.657089e-01 3.997330e-03 9.537327e-03 -6.000000e+00 2.735454e-01 228.78 -2.00 3.45 -2.00 321.67 0.00e+00 4.606443e-03 2.245986e-03 1.287116e-02 -6.000000e+00 1.253654e-02 289.18 -2.00 20.00 -2.00 321.09 0.00e+00 6.040 0.004 302.00 328.00 3 1.3018e+00 1.5374e-02 9.7707e-02 -6.0000e+00 6.7999e-01 8.9615e-02 2.1854e-02 9.7383e-02 -6.0000e+00 7.3501e-01 -2.1769e-01 2.1233e-02 3.5044e-02 -6.0000e+00 4.3926e-01 8.2925e-02 9.7833e-03 6.2837e-03 -6.0000e+00 1.8864e-01 1.9520e-04 -5.3176e-04 2.1542e-04 1.7570e-04 -6.0000e+00 1.3350e-02 -4.8523e-03 -6.4857e-05 12 9 9 12 4 4 91.19 44.47 0.52 -0.00485 -0.00885 58 13 1 5 0 839.470 24.75 20.01 44.47 27.78 10.7 1019.50 -96360 -65874 -96208 -211708 17542 -71925 -195758 -188865 -58853 -167793 -121196 900000 -175075 67329 -43111 900000 -99918 -56361 8601 -66515 -16366 -33634 78252 -31696 -46058 -13514 -51382 38691 -95981 6728 -13053 52161 -493 9406 24508 -32085 9675 660 11657 14670 6380 9479 5218 5641 -2664 17371 -1799 20070 12731 63 8830 4454 19276 2347 11093 9799 5029 4592 -126 2455 56 17312 10820 8296 5350 2916 2490 -1053 4778 4735 9418 5700 77 -1385 -3552 -2710 -6636 -4146 -5728 -597 -3209 -2491 -1309 -2335 387 302 2970 2071 473 -70 -451 -563 -3165 -2917 -2887 -443 157 791 -21 -2579 -2909 -2325 -1584 -1667 -1942 -927 -1037 1268 1674 3333 1660 1392 961 -850 -1623 -803 638 106 1192 871 1153 1683 967 327 -610 -595 -510 -1252 -1206 -898 -641 -879 -576 -48 473 351 794 406 -27 103 -478 -414 -649 -444 -648 -2995 118 -485 -2506 -2545 -396 -2148 -1061 900000 -4128 454 -436 900000 -2356 -949 81 -1389 -209 -521 527 -555 -993 -218 -1212 365 -3621 104 -299 738 -13 234 512 -1232 280 25 487 692 361 556 334 369 -194 1065 -138 1298 943 6 839 492 2013 313 1427 1327 725 656 -19 356 9 2612 1983 1710 1160 639 555 -260 1265 1419 2899 1859 26 -438 -1041 -721 -1793 -1170 -1910 -224 -1438 -1247 -701 -1227 212 176 1759 1258 316 -45 -271 -322 -1857 -1845 -2092 -365 136 760 -21 -2615 -2733 -2172 -1408 -1547 -1933 -968 -1053 1369 2006 4394 2422 2106 1444 -1248 -2295 -1109 895 158 1852 1383 1791 2510 1406 463 -839 -794 -752 -1843 -2008 -1665 -1288 -1878 -1302 -115 1203 931 2143 1110 -73 264 -1167 -965 SS 20220921T114841.8Z 8299.492150 207 1 48.97 2 79.07 97.85 29.44 111.66 0.00 1 0.00 1 0 25 2.899e-01 1.113e-02 2.250e-01 4.123e-03 5.853409e-01 2.322480e-03 7.735759e-03 -6.000000e+00 1.720022e-01 228.77 -2.00 3.45 -2.00 321.34 0.00e+00 2.786500e-03 1.170189e-03 7.891034e-03 -6.000000e+00 7.729321e-03 289.18 -2.00 20.00 -2.00 320.72 0.00e+00 5.077 0.002 302.00 328.00 3 1.4258e+00 8.3217e-03 7.1891e-02 -6.0000e+00 4.2725e-01 -2.6305e-02 1.1389e-02 6.2951e-02 -6.0000e+00 4.6129e-01 -4.3748e-02 1.0822e-02 2.4121e-02 -6.0000e+00 2.7566e-01 1.2572e-02 5.1318e-03 5.0257e-03 -6.0000e+00 1.1865e-01 4.6417e-04 -6.8793e-04 1.3007e-04 1.1757e-04 -6.0000e+00 8.4221e-03 -5.8229e-03 -4.7658e-06 12 9 9 12 4 4 89.95 43.05 0.45 -0.00582 -0.01099 122 27 1 5 0 401.340 24.75 20.00 43.05 28.36 10.7 1024.71 -75982 -63546 -144372 -115617 -92157 -122837 -55918 11553 -71910 -93740 -24644 -109395 -82773 25786 -19532 18998 -36939 793 -26375 2076 -922 -14570 -3377 -28288 10445 -41681 -4658 -27700 -4570 -6628 -6553 5501 1793 -14585 -17003 -21252 -14726 -2017 1205 -4172 7906 -5163 566 -3132 640 6351 4005 8406 2284 764 -3225 2501 4470 5196 2992 3379 6255 -805 3843 -1120 4344 5386 6516 6172 3020 580 -1325 -765 1656 1927 2206 2620 2903 -572 -1849 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