File name: Pandora40s1_WallopsIslandVA_20250914_L2Fit_fout2c11d20230901p1-8.txt File generation date: 20250915T050852.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 40 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora40_OF_v2d20230731.txt Instrument calibration file used: Pandora40s1_CF_v11d20230901.txt Level 1 file used: Pandora40s1_WallopsIslandVA_20250914_L1_smca1c11d20230901p1-8.txt Full location name: Wallops Island X-75 Station, Wallops Flight Facility Geophysical Observatory Short location name: WallopsIslandVA Country of location: USA Location latitude [deg]: 37.8439 Location longitude [deg]: -75.4775 Location altitude [m]: 11 Local noon date: 20250914 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 10 First and last pixel inside fitting window: 228 370 Nominal wavelengths inside fitting window [nm]: 305.0793 305.2203 305.3612 305.5021 305.6430 305.7838 305.9247 306.0656 306.2064 306.3472 306.4881 306.6289 306.7697 306.9105 307.0512 307.1920 307.3328 307.4735 307.6142 307.7550 307.8957 308.0364 308.1771 308.3177 308.4584 308.5990 308.7397 308.8803 309.0209 309.1615 309.3021 309.4427 309.5833 309.7239 309.8644 310.0050 310.1455 310.2860 310.4265 310.5670 310.7075 310.8479 310.9884 311.1289 311.2693 311.4097 311.5501 311.6905 311.8309 311.9713 312.1117 312.2520 312.3924 312.5327 312.6730 312.8133 312.9536 313.0939 313.2342 313.3745 313.5147 313.6550 313.7952 313.9354 314.0756 314.2158 314.3560 314.4962 314.6363 314.7765 314.9166 315.0568 315.1969 315.3370 315.4771 315.6171 315.7572 315.8973 316.0373 316.1773 316.3174 316.4574 316.5974 316.7374 316.8773 317.0173 317.1573 317.2972 317.4371 317.5770 317.7170 317.8568 317.9967 318.1366 318.2765 318.4163 318.5561 318.6960 318.8358 318.9756 319.1154 319.2551 319.3949 319.5347 319.6744 319.8141 319.9539 320.0936 320.2333 320.3729 320.5126 320.6523 320.7919 320.9316 321.0712 321.2108 321.3504 321.4900 321.6296 321.7691 321.9087 322.0482 322.1878 322.3273 322.4668 322.6063 322.7458 322.8852 323.0247 323.1641 323.3036 323.4430 323.5824 323.7218 323.8612 324.0006 324.1399 324.2793 324.4186 324.5580 324.6973 324.8366 324.9759 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250914T115334.7Z 9388.495540 252 1 48.78 2 76.97 96.16 15.86 237.51 0.00 1 0.00 1 0 25 3.329e-01 1.432e-02 2.034e-01 6.871e-03 5.073687e-01 3.679258e-03 6.279174e-03 -6.000000e+00 1.963914e-01 229.43 -2.00 3.45 -2.00 321.04 0.00e+00 2.202365e-03 1.740664e-03 5.918754e-03 -6.000000e+00 9.008094e-03 289.92 -2.00 20.00 -2.00 320.32 0.00e+00 4.318 0.001 302.00 328.00 3 3.1257e+00 1.2758e-02 5.7828e-02 -6.0000e+00 4.8854e-01 -6.8409e-02 1.6691e-02 4.6413e-02 -6.0000e+00 5.3038e-01 -4.2829e-02 1.4601e-02 1.8899e-02 -6.0000e+00 3.1550e-01 2.3364e-02 7.0045e-03 3.5749e-03 -6.0000e+00 1.3278e-01 1.9697e-04 5.5489e-03 2.1669e-04 9.3638e-05 -6.0000e+00 9.8098e-03 1.5150e-01 -5.0467e-05 12 8 8 10 0 0 99.67 21.32 0.23 0.15150 0.19320 44 10 1 5 0 1108.480 26.11 20.01 21.32 23.78 7.9 974.09 -99338 -89710 -110443 -15977 -109432 900000 -122516 152792 -155276 5919 -112976 900000 -18070 -41671 42047 18700 60633 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540 642 45 -673 55 -638 -1450 959 -1956 166 -1547 488 -2435 1612 299 1584 908 984 948 -747 1467 -2352 1225 -2998 311 -1213 1247 -725 -776 -2566 -2341 -1260 -2006 674 -2136 584 -748 2566 179 2056 1333 -629 1227 -2511 -418 -2024 1474 -1251 1251 176 1802 1827 -470 784 -395 -285 -1332 2381 -1444 1191 -1632 1136 -1073 661 84 1433 1876 -702 2269 -2849 -133 -2360 900000 SS 20250914T120843.2Z 9388.506056 258 1 48.87 2 74.00 98.59 18.41 244.35 0.00 1 0.00 1 0 25 7.381e-02 6.855e-03 6.116e-02 2.656e-03 4.344872e-01 1.393439e-03 4.972904e-03 -6.000000e+00 4.323606e-02 229.43 -2.00 3.45 -2.00 320.39 0.00e+00 1.339604e-03 5.231728e-04 2.804594e-03 -6.000000e+00 1.975885e-03 289.92 -2.00 20.00 -2.00 319.60 0.00e+00 3.566 0.001 302.00 328.00 3 2.4008e+00 4.3820e-03 4.3201e-02 -6.0000e+00 1.0750e-01 -7.6355e-02 5.4157e-03 2.6479e-02 -6.0000e+00 1.1658e-01 3.2967e-02 4.4451e-03 1.3024e-02 -6.0000e+00 6.9663e-02 -1.7396e-02 2.2324e-03 3.5047e-03 -6.0000e+00 2.9453e-02 8.8190e-04 6.3204e-03 8.4355e-05 6.2471e-05 -6.0000e+00 2.1306e-03 1.4801e-01 1.3900e-04 11 8 0 10 0 0 99.91 21.38 0.23 0.14801 0.19551 149 34 1 5 0 327.930 26.11 20.00 21.38 24.33 8.0 978.39 -59111 3439 -26313 15283 -8390 -4198 -4935 -27427 19100 -12730 4829 -23125 19296 -9170 -7380 -2869 -676 -1871 -6222 8926 -584 395 -5904 -364 -3991 240 -2301 5803 -421 3791 4961 442 -1452 -6473 -2372 -3124 -2901 -1942 3057 -10 1663 840 -1670 889 -1396 1203 -1562 -173 -1437 1422 688 572 461 178 1116 -847 863 -1775 1378 1144 3431 1835 2223 741 -129 29 -195 393 423 1009 2 872 -676 -621 -2546 -2702 -3169 -2065 -1636 -2233 -1285 -1364 -368 40 886 1083 1990 1384 1868 427 -100 -1137 -962 -453 340 683 372 620 -545 -895 -1696 -1341 -635 -444 -885 -181 302 603 1059 832 824 78 -302 -794 -738 -383 -368 142 79 500 -166 554 36 204 -589 -594 -190 244 68 -368 -407 -375 1 -65 487 325 591 212 229 -243 -621 -322 900000 -1130 39 -375 135 -96 -52 -70 -497 247 -239 86 -613 441 -303 -269 -109 -27 -80 -291 366 -27 19 -329 -21 -241 14 -130 302 -25 245 362 37 -123 -562 -206 -314 -354 -282 483 -2 285 150 -311 176 -286 241 -325 -37 -327 344 170 165 130 57 338 -286 283 -591 451 400 1295 720 920 308 -55 12 -86 193 216 549 1 473 -378 -317 -1205 -1215 -1480 -1072 -976 -1519 -885 -1006 -286 33 776 991 1826 1254 1599 344 -81 -899 -796 -415 325 733 438 754 -647 -978 -1726 -1445 -666 -499 -1053 -225 398 861 1634 1353 1348 123 -450 -1121 -1017 -540 -551 225 128 807 -262 837 52 286 -855 -856 -270 379 115 -658 -756 -728 1 -142 1093 748 1368 488 507 -515 -1274 -668 900000 SS 20250914T121809.2Z 9388.512607 261 1 35.04 2 72.17 100.13 20.07 247.86 0.00 1 0.00 1 0 25 1.280e-01 8.563e-03 1.191e-01 5.396e-03 3.962103e-01 2.795696e-03 4.499561e-03 -6.000000e+00 7.500003e-02 229.43 -2.00 3.45 -2.00 319.95 0.00e+00 2.641271e-03 9.172934e-04 1.861702e-03 -6.000000e+00 3.427373e-03 289.92 -2.00 20.00 -2.00 319.12 0.00e+00 3.220 0.001 302.00 328.00 3 3.9815e+00 8.3771e-03 3.8127e-02 -6.0000e+00 1.8647e-01 -2.8786e-02 1.0110e-02 2.0935e-02 -6.0000e+00 2.0222e-01 6.8406e-03 7.8503e-03 1.1663e-02 -6.0000e+00 1.2084e-01 -7.5895e-03 4.0092e-03 4.4513e-03 -6.0000e+00 5.1092e-02 2.5767e-04 6.3321e-03 1.6949e-04 5.8446e-05 -6.0000e+00 3.6958e-03 1.4772e-01 1.3903e-04 12 9 1 12 9 1 99.27 21.43 0.28 0.14772 0.19531 15 5 1 5 0 2189.680 26.21 20.00 21.43 24.96 8.0 984.02 3103 78052 -3822 51377 96873 -33318 28061 2462 -9319 -16484 -8997 9090 -19019 15778 10798 3444 -7083 2702 -10423 3895 2467 2681 -202 -922 5595 -7364 8114 -8375 2088 3090 -3130 -977 1676 -8884 -2958 -9033 -3326 4948 3452 1491 1471 -630 -1250 118 -1283 -696 -1410 2240 -188 653 2769 1602 2838 1226 -152 -3711 -1181 610 1548 1181 752 1423 992 1583 -1076 -521 166 -1011 -219 623 281 13 848 -528 -2775 -2117 -4396 -2743 -1954 -1622 -1452 -380 -476 845 915 515 1820 2544 2407 110 221 -1452 -1369 -302 598 887 36 793 118 -1823 -2459 -858 -1367 -1403 -48 -577 446 1140 1089 816 890 -39 -227 -146 -953 -458 -561 471 -198 72 -108 -171 550 302 -42 -1080 -111 210 85 -148 -440 -353 19 -54 305 763 324 373 112 -445 -618 -126 900000 55 699 -69 524 649 -832 444 54 -235 -464 -265 269 -882 609 486 178 -434 159 -725 240 156 177 -15 -72 417 -613 564 -679 162 268 -324 -107 179 -1020 -332 -1222 -513 833 670 319 332 -149 -304 29 -320 -172 -354 555 -50 188 846 530 974 444 -57 -1466 -450 227 579 471 331 679 501 782 -519 -242 80 -548 -131 394 182 8 506 -294 -1440 -1037 -2258 -1545 -1244 -1154 -1121 -309 -410 766 881 518 1834 2500 2268 99 184 -1188 -1166 -279 613 1006 45 1005 146 -2124 -2684 -918 -1544 -1690 -60 -758 612 1666 1701 1328 1454 -62 -341 -208 -1339 -656 -848 743 -325 116 -171 -265 818 435 -58 -1498 -161 328 142 -259 -792 -660 36 -111 644 1634 704 802 235 -900 -1218 -251 900000 SS 20250914T122435.1Z 9388.517073 265 1 18.02 2 70.92 101.19 21.22 250.00 0.00 1 0.00 1 0 25 6.405e-02 7.985e-03 5.007e-02 4.566e-03 3.740423e-01 2.347965e-03 4.082216e-03 -6.000000e+00 3.746417e-02 229.43 -2.00 3.45 -2.00 319.45 0.00e+00 5.954778e-04 6.571060e-04 7.602839e-04 -6.000000e+00 1.716164e-03 289.92 -2.00 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