File name: Pandora40s1_WallopsIslandVA_20260319_L2Fit_fout2c11d20230901p1-8.txt File generation date: 20260320T051821.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 40 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora40_OF_v2d20230731.txt Instrument calibration file used: Pandora40s1_CF_v11d20230901.txt Level 1 file used: Pandora40s1_WallopsIslandVA_20260319_L1_smca1c11d20230901p1-8.txt Full location name: Wallops Island X-75 Station, Wallops Flight Facility Geophysical Observatory Short location name: WallopsIslandVA Country of location: USA Location latitude [deg]: 37.8439 Location longitude [deg]: -75.4775 Location altitude [m]: 11 Local noon date: 20260319 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 10 First and last pixel inside fitting window: 228 370 Nominal wavelengths inside fitting window [nm]: 305.0793 305.2203 305.3612 305.5021 305.6430 305.7838 305.9247 306.0656 306.2064 306.3472 306.4881 306.6289 306.7697 306.9105 307.0512 307.1920 307.3328 307.4735 307.6142 307.7550 307.8957 308.0364 308.1771 308.3177 308.4584 308.5990 308.7397 308.8803 309.0209 309.1615 309.3021 309.4427 309.5833 309.7239 309.8644 310.0050 310.1455 310.2860 310.4265 310.5670 310.7075 310.8479 310.9884 311.1289 311.2693 311.4097 311.5501 311.6905 311.8309 311.9713 312.1117 312.2520 312.3924 312.5327 312.6730 312.8133 312.9536 313.0939 313.2342 313.3745 313.5147 313.6550 313.7952 313.9354 314.0756 314.2158 314.3560 314.4962 314.6363 314.7765 314.9166 315.0568 315.1969 315.3370 315.4771 315.6171 315.7572 315.8973 316.0373 316.1773 316.3174 316.4574 316.5974 316.7374 316.8773 317.0173 317.1573 317.2972 317.4371 317.5770 317.7170 317.8568 317.9967 318.1366 318.2765 318.4163 318.5561 318.6960 318.8358 318.9756 319.1154 319.2551 319.3949 319.5347 319.6744 319.8141 319.9539 320.0936 320.2333 320.3729 320.5126 320.6523 320.7919 320.9316 321.0712 321.2108 321.3504 321.4900 321.6296 321.7691 321.9087 322.0482 322.1878 322.3273 322.4668 322.6063 322.7458 322.8852 323.0247 323.1641 323.3036 323.4430 323.5824 323.7218 323.8612 324.0006 324.1399 324.2793 324.4186 324.5580 324.6973 324.8366 324.9759 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260319T134039.4Z 9574.569901 112 1 47.61 2 61.38 115.74 62.75 107.67 0.00 1 0.00 1 0 33 3.390e-02 8.284e-03 3.247e-02 3.929e-03 3.432769e-01 1.989504e-03 3.666413e-03 -6.000000e+00 1.963584e-02 226.83 -2.00 3.45 -2.00 319.10 0.00e+00 1.827630e-03 4.866467e-04 8.638494e-04 -6.000000e+00 8.696001e-04 279.78 -2.00 20.00 -2.00 318.42 0.00e+00 2.078 0.000 302.00 328.00 3 4.9093e+00 5.5181e-03 2.6520e-02 -6.0000e+00 4.8687e-02 -9.0467e-03 6.4015e-03 1.6268e-02 -6.0000e+00 5.3024e-02 1.0091e-02 4.5760e-03 9.1035e-03 -6.0000e+00 3.1560e-02 -1.1000e-02 2.3673e-03 4.4473e-03 -6.0000e+00 1.3262e-02 3.1942e-04 8.4427e-03 1.2171e-04 4.4353e-05 -6.0000e+00 9.7748e-04 1.6504e-01 3.7312e-04 11 8 0 10 0 0 75.30 20.02 0.24 0.16504 0.22848 16 4 1 5 0 2975.070 25.07 20.00 20.02 12.94 8.5 1053.72 4222 -12351 17218 -4384 10632 -13618 -5760 -6661 4951 -9356 -2370 -9093 7967 2517 -2192 6790 -2663 -2974 8869 7151 1837 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1402 257 -1431 -1076 -718 -161 124 693 1007 306 -446 -1828 -2271 -1350 -1211 -581 -450 286 345 1635 1385 1843 1239 114 -974 -1122 -885 -591 -687 500 277 952 401 659 -334 293 -1513 -1635 44 67 433 -131 -1090 -161 -515 -53 986 783 1683 848 483 -888 -1138 -847 900000 SS 20260319T134606.7Z 9574.573689 115 1 48.26 2 60.41 116.84 61.73 108.64 0.00 1 0.00 1 0 25 3.408e-02 8.027e-03 2.624e-02 3.573e-03 3.338229e-01 1.846424e-03 3.709679e-03 -6.000000e+00 2.007552e-02 226.83 -2.00 3.45 -2.00 318.93 0.00e+00 1.628757e-03 4.252343e-04 7.492581e-04 -6.000000e+00 8.807399e-04 279.78 -2.00 20.00 -2.00 318.28 0.00e+00 2.016 0.000 302.00 328.00 3 4.7756e+00 5.0724e-03 2.6085e-02 -6.0000e+00 4.9806e-02 -1.1277e-02 5.8345e-03 1.6319e-02 -6.0000e+00 5.3923e-02 3.8207e-03 4.1490e-03 8.8619e-03 -6.0000e+00 3.2084e-02 -4.9583e-03 2.1706e-03 3.8438e-03 -6.0000e+00 1.3862e-02 3.9010e-04 6.8013e-03 1.1151e-04 3.9503e-05 -6.0000e+00 9.8483e-04 1.6622e-01 -1.0806e-05 11 8 0 10 0 0 72.63 20.06 0.25 0.16622 0.21733 19 4 1 5 0 2539.660 25.07 20.01 20.06 12.93 8.5 1054.19 8792 3470 -12274 -7196 -16780 3539 4654 15476 -15705 -9988 -2077 -4297 -4541 2040 4029 -1269 4786 -147 7922 -1534 1770 -2524 -793 -801 550 529 -2940 -2219 -125 2885 -1115 396 -3574 -4336 -4561 -4039 1042 -608 1135 -400 100 -610 628 1012 -455 573 -544 -983 -33 1086 -626 2310 614 1827 1541 1124 -2144 506 369 33 1998 748 2654 -569 -192 -1106 -634 227 399 364 545 38 -525 -499 -2910 -1897 -3557 -450 -1476 -1697 -1474 -1103 -450 306 816 1118 1727 1397 1616 82 -653 -1901 -576 -346 60 190 382 797 -766 -960 -1710 -918 -945 -264 -754 311 347 752 1166 979 919 -90 -342 -869 -379 -720 222 53 471 564 61 134 -328 -123 -1023 -220 -587 -18 -163 195 -530 -128 -180 -135 333 485 803 234 282 -624 -670 900000 900000 341 140 -528 -278 -725 140 204 655 -916 -570 -123 -304 -379 180 379 -133 499 -17 863 -184 209 -324 -107 -114 77 72 -398 -295 -17 426 -189 69 -639 -759 -840 -850 251 -173 356 -136 35 -220 227 366 -167 206 -196 -361 -13 442 -277 1054 296 898 775 570 -1105 252 188 18 1164 473 1700 -362 -115 -644 -386 152 294 283 426 29 -381 -332 -1806 -1112 -2178 -298 -1110 -1416 -1317 -1036 -444 319 895 1264 1956 1550 1699 81 -602 -1721 -538 -352 67 234 502 1056 -983 -1145 -1934 -1040 -1132 -334 -1000 426 499 1146 1869 1611 1498 -140 -505 -1220 -523 -1023 331 84 755 899 96 203 -480 -173 -1391 -296 -833 -27 -261 322 -900 -224 -331 -259 654 968 1610 466 544 -1168 -1229 900000 900000 SS 20260319T135125.6Z 9574.577379 118 1 47.96 2 59.48 117.94 60.75 109.60 0.00 1 0.00 1 0 25 2.901e-02 8.072e-03 2.105e-02 3.094e-03 3.258505e-01 1.597065e-03 3.633120e-03 -6.000000e+00 1.709145e-02 226.83 -2.00 3.45 -2.00 318.78 0.00e+00 1.208071e-03 3.523246e-04 6.784302e-04 -6.000000e+00 7.499903e-04 279.78 -2.00 20.00 -2.00 318.12 0.00e+00 1.961 0.000 302.00 328.00 3 4.6855e+00 4.3657e-03 2.5430e-02 -6.0000e+00 4.2403e-02 -1.3668e-02 5.0046e-03 1.5962e-02 -6.0000e+00 4.5908e-02 8.2741e-03 3.4951e-03 8.4812e-03 -6.0000e+00 2.7316e-02 -7.9090e-03 1.8259e-03 3.3967e-03 -6.0000e+00 1.1802e-02 4.5657e-04 6.8243e-03 9.6335e-05 3.4674e-05 -6.0000e+00 8.3850e-04 1.6370e-01 -1.1732e-04 11 8 0 10 0 0 59.27 20.10 0.16 0.16370 0.21498 21 5 1 5 0 2283.670 25.07 20.00 20.10 12.94 8.5 1054.06 9376 3801 -17935 -3332 -5481 10619 -10933 542 4454 1169 -5497 1621 -5704 -852 988 -3083 8364 -646 6329 905 -505 -727 2658 2697 -1392 -4011 -4021 -1310 -1148 4322 545 2138 -2232 -3820 -3941 -1451 -906 -146 306 -2354 1283 -1065 -82 -865 340 -439 -987 -1900 -114 450 373 2565 -437 262 1166 1819 -360 735 508 1377 2049 1892 1433 59 -8 -758 -809 416 779 558 589 -275 -27 -795 -2031 -2680 -2868 -2467 -2077 -1200 -1676 -1045 -633 369 947 1384 1692 730 974 -5 -540 -1345 -639 -319 607 567 698 470 -341 -743 -1738 -1077 -1048 -846 -527 -146 562 926 1126 1243 657 -29 -98 -1134 -1020 -849 -393 160 293 802 215 288 -22 -8 -721 -647 -322 210 -177 -158 -496 36 2 260 263 392 554 347 5 -492 -740 900000 900000 397 167 -890 -136 -233 433 -613 29 236 66 -368 118 -524 -84 104 -354 908 -80 753 114 -65 -99 374 399 -216 -619 -591 -185 -170 672 97 392 -418 -706 -766 -317 -236 -44 102 -861 472 -407 -31 -335 130 -167 -375 -738 -46 192 171 1217 -222 136 612 955 -190 381 269 769 1239 1224 960 39 -5 -453 -508 287 588 443 472 -216 -20 -546 -1287 -1627 -1794 -1706 -1605 -1016 -1528 -997 -635 390 1051 1580 1941 825 1044 -5 -505 -1229 -604 -329 683 698 915 625 -437 -889 -1979 -1232 -1265 -1082 -700 -201 808 1408 1800 2033 1067 -46 -144 -1591 -1410 -1202 -585 249 467 1270 334 434 -32 -11 -975 -872 -454 317 -281 -260 -832 62 3 489 509 772 1097 679 9 -910 -1342 900000 900000 SS 20260319T135649.3Z 9574.581126 121 1 47.98 2 58.54 119.07 59.75 110.58 0.00 1 0.00 1 0 25 2.713e-02 8.120e-03 1.832e-02 2.886e-03 3.183098e-01 1.489373e-03 3.528358e-03 -6.000000e+00 1.598230e-02 226.83 -2.00 3.45 -2.00 318.68 0.00e+00 1.246797e-03 3.184266e-04 5.544021e-04 -6.000000e+00 7.012732e-04 279.78 -2.00 20.00 -2.00 318.03 0.00e+00 1.909 0.000 302.00 328.00 3 4.6095e+00 4.0555e-03 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