File name: Pandora270s1_Warsaw-UW_20240301_L2Fit_fout2c6d20231207p1-8.txt File generation date: 20251023T081745.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Iwona Stachlewska Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 270 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora270_OF_v3d20230517.txt Instrument calibration file used: Pandora270s1_CF_v6d20231207.txt Level 1 file used: Pandora270s1_Warsaw-UW_20240301_L1_smca1c6d20231207p1-8.txt Full location name: Warsaw Observatory Station, Faculty of Physics, University of Warsaw Short location name: Warsaw-UW Country of location: Poland Location latitude [deg]: 52.2113 Location longitude [deg]: 20.9828 Location altitude [m]: 137 Local noon date: 20240301 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0251 305.1656 305.3062 305.4467 305.5872 305.7277 305.8682 306.0087 306.1492 306.2897 306.4301 306.5705 306.7110 306.8514 306.9918 307.1322 307.2726 307.4129 307.5533 307.6936 307.8339 307.9743 308.1146 308.2549 308.3951 308.5354 308.6757 308.8159 308.9561 309.0964 309.2366 309.3768 309.5169 309.6571 309.7973 309.9374 310.0776 310.2177 310.3578 310.4979 310.6380 310.7781 310.9181 311.0582 311.1982 311.3382 311.4782 311.6182 311.7582 311.8982 312.0382 312.1781 312.3181 312.4580 312.5979 312.7378 312.8777 313.0176 313.1575 313.2973 313.4372 313.5770 313.7168 313.8567 313.9965 314.1362 314.2760 314.4158 314.5555 314.6953 314.8350 314.9747 315.1144 315.2541 315.3938 315.5334 315.6731 315.8127 315.9524 316.0920 316.2316 316.3712 316.5108 316.6503 316.7899 316.9294 317.0690 317.2085 317.3480 317.4875 317.6270 317.7665 317.9059 318.0454 318.1848 318.3242 318.4636 318.6030 318.7424 318.8818 319.0212 319.1605 319.2999 319.4392 319.5785 319.7178 319.8571 319.9964 320.1357 320.2749 320.4142 320.5534 320.6926 320.8318 320.9710 321.1102 321.2494 321.3885 321.5277 321.6668 321.8059 321.9451 322.0842 322.2232 322.3623 322.5014 322.6404 322.7795 322.9185 323.0575 323.1965 323.3355 323.4745 323.6135 323.7524 323.8914 324.0303 324.1692 324.3081 324.4470 324.5859 324.7248 324.8636 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240301T073203.2Z 8826.313926 284 1 54.36 2 72.73 128.31 95.28 245.16 0.00 1 0.00 1 0 25 1.310e-01 5.723e-03 9.103e-03 5.687e-04 5.975111e-01 2.955726e-04 7.645797e-03 -6.000000e+00 7.699975e-02 224.37 -2.00 3.84 -2.00 319.15 0.00e+00 1.873412e-03 7.189823e-05 3.371588e-04 -6.000000e+00 3.227038e-03 267.30 -2.00 20.00 -2.00 318.75 0.00e+00 3.321 0.001 302.00 328.00 3 1.9196e+00 8.0555e-04 4.6732e-02 -6.0000e+00 1.9067e-01 7.6795e-02 9.3363e-04 3.3286e-02 -6.0000e+00 2.0715e-01 -6.7833e-02 7.7722e-04 1.7170e-02 -6.0000e+00 1.2264e-01 2.0270e-02 4.1816e-04 5.6887e-03 -6.0000e+00 5.1924e-02 1.4087e-03 -3.7144e-04 1.5915e-05 6.3563e-05 -6.0000e+00 3.8897e-03 5.5601e-03 0.0000e+00 10 0 0 10 0 0 84.43 25.82 0.34 0.00556 0.00277 478 50 2 8 0 113.700 20.02 25.82 15.34 34.75 33.50 2.0 921.57 -48791 -62714 -44033 -56138 -43462 -54199 -26201 -23048 -30681 -45416 -22579 -29936 -15927 -24823 -13542 -10344 -5538 -2639 -3033 -2353 -133 -724 -1929 -2971 -1429 -1351 -6892 -7341 -4696 -6720 1717 -1936 3689 -1792 -1881 -2706 -1503 -3028 -636 502 -756 -64 -1024 -179 91 124 547 611 702 -387 1110 2003 2729 1606 1349 1267 891 583 693 391 272 1447 1885 1289 1261 390 -79 105 274 901 903 595 98 -22 7 -168 -545 -682 -676 -659 -576 -1229 -1494 -1713 -1085 -1066 -714 -137 134 285 356 367 344 367 204 2 365 574 258 -69 -437 -513 -498 46 -393 -731 -746 -675 -320 16 147 79 139 7 7 242 391 509 542 428 -36 91 240 322 317 169 53 614 674 301 102 -33 -315 -233 -169 -252 -286 76 76 98 40 -275 -320 -779 -1364 -865 -1242 -795 -1073 -414 -396 -643 -1209 -511 -810 -455 -978 -593 -527 -306 -157 -196 -160 -9 -51 -142 -237 -122 -122 -675 -711 -435 -663 177 -222 460 -257 -270 -386 -226 -536 -133 114 -199 -18 -310 -56 28 40 177 187 222 -130 402 797 1100 710 638 626 425 281 350 194 137 722 1046 753 787 245 -49 65 181 629 663 465 77 -17 5 -114 -361 -441 -438 -489 -471 -1095 -1405 -1647 -1102 -1100 -774 -147 143 312 366 369 327 345 205 2 416 715 342 -94 -578 -650 -599 52 -472 -899 -965 -891 -437 23 225 126 224 11 11 367 579 769 828 687 -57 146 369 495 467 248 74 863 980 472 166 -56 -561 -422 -315 -482 -567 149 150 195 77 -520 -577 SS 20240301T073756.0Z 8826.318009 287 1 54.36 2 72.03 129.65 96.08 246.25 0.00 1 0.00 1 0 25 1.083e-01 5.732e-03 7.490e-03 5.494e-04 5.769232e-01 2.848401e-04 7.401037e-03 -6.000000e+00 6.360517e-02 224.37 -2.00 3.84 -2.00 318.98 0.00e+00 1.691452e-03 6.540080e-05 2.911588e-04 -6.000000e+00 2.665698e-03 267.30 -2.00 20.00 -2.00 318.57 0.00e+00 3.199 0.001 302.00 328.00 3 2.0029e+00 7.7231e-04 4.5030e-02 -6.0000e+00 1.5750e-01 7.1450e-02 8.8633e-04 3.2037e-02 -6.0000e+00 1.7112e-01 -6.2259e-02 7.0800e-04 1.6382e-02 -6.0000e+00 1.0130e-01 1.8291e-02 3.8166e-04 5.2971e-03 -6.0000e+00 4.2891e-02 1.4891e-03 -3.6606e-04 1.5434e-05 5.9567e-05 -6.0000e+00 3.2132e-03 5.7066e-03 0.0000e+00 10 0 0 10 0 0 96.70 25.83 0.34 0.00571 0.00296 426 44 2 8 0 127.580 20.01 25.83 15.63 34.75 33.50 2.0 922.52 -39216 -49085 -38436 -44793 -39674 -46952 -23073 -17258 -26173 -33468 -17301 -29273 -10388 -19304 -10896 -8540 -7038 -1166 -3639 -2596 -1193 1103 -940 -1664 -1381 342 -4489 -5915 -3304 -5143 1897 -1566 3376 -1973 -1354 -2829 -1414 -2828 -616 25 -864 -46 -771 60 91 -103 502 778 972 -282 941 1915 2324 1519 1440 1080 871 385 710 391 271 1541 1960 1308 1200 476 249 10 148 710 826 375 41 -119 -56 -38 -452 -675 -469 -662 -654 -1170 -1607 -1792 -1199 -1121 -801 -121 124 441 436 377 353 403 201 154 240 477 207 -45 -360 -537 -428 -10 -350 -623 -843 -689 -406 35 129 158 163 -23 -75 309 468 549 547 358 4 -17 222 338 358 192 35 544 690 407 211 -25 -342 -191 -150 -267 -242 99 87 25 -53 -302 -329 -725 -1181 -902 -1116 -880 -1087 -444 -351 -658 -990 -464 -977 -346 -881 -566 -518 -477 -82 -284 -212 -99 91 -82 -156 -140 36 -464 -610 -357 -534 208 -208 489 -327 -223 -465 -245 -575 -136 7 -241 -14 -246 20 30 -35 170 269 346 -107 356 793 1051 700 708 555 462 207 372 202 142 801 1130 795 778 310 158 7 101 511 626 303 34 -94 -41 -26 -307 -447 -328 -502 -546 -1014 -1549 -1766 -1194 -1189 -855 -133 137 474 461 388 343 386 205 170 278 605 269 -60 -484 -691 -521 -11 -428 -780 -1073 -928 -565 51 195 247 258 -37 -114 455 696 806 843 561 7 -26 346 509 534 275 51 770 1010 620 344 -42 -593 -336 -271 -499 -467 193 171 48 -101 -558 -598 SS 20240301T074242.4Z 8826.321324 289 1 54.37 2 71.47 130.75 96.75 247.12 0.00 1 0.00 1 0 25 9.403e-02 5.691e-03 5.260e-03 4.482e-04 5.616895e-01 2.319128e-04 7.231461e-03 -6.000000e+00 5.525370e-02 224.37 -2.00 3.84 -2.00 318.83 0.00e+00 1.551072e-03 5.077033e-05 2.829199e-04 -6.000000e+00 2.315652e-03 267.30 -2.00 20.00 -2.00 318.42 0.00e+00 3.108 0.001 302.00 328.00 3 1.7101e+00 6.2652e-04 4.3794e-02 -6.0000e+00 1.3682e-01 6.6839e-02 7.1520e-04 3.1157e-02 -6.0000e+00 1.4865e-01 -5.8871e-02 5.5234e-04 1.5892e-02 -6.0000e+00 8.8001e-02 1.7505e-02 2.9781e-04 5.0625e-03 -6.0000e+00 3.7260e-02 2.2148e-03 -3.4213e-04 1.2648e-05 5.7978e-05 -6.0000e+00 2.7911e-03 5.4306e-03 0.0000e+00 10 0 0 10 0 0 44.76 25.83 0.32 0.00543 0.00286 597 62 2 8 0 91.060 20.02 25.83 15.83 34.75 33.50 1.9 923.32 -34177 -39634 -33797 -37029 -34202 -42038 -21241 -17153 -25097 -31521 -17447 -21559 -9732 -17769 -10117 -5708 -4020 -1893 -1691 -898 314 645 -588 -813 -811 -697 -3322 -5162 -2943 -3677 913 -417 2365 -1171 -1548 -1963 -1396 -1989 -472 335 -816 -254 -696 116 -49 470 259 805 593 -113 1090 1828 2060 1323 1163 1015 822 430 679 499 440 1386 1869 1531 1163 492 -76 -12 186 703 620 293 167 -73 -79 -98 -391 -754 -513 -564 -598 -1190 -1599 -1809 -1267 -1180 -750 -70 124 316 315 346 394 328 294 94 317 500 164 -117 -392 -540 -519 -26 -379 -669 -795 -696 -412 96 135 171 159 -3 98 283 523 561 530 351 -30 30 168 337 341 258 142 572 677 360 212 -50 -268 -147 -175 -259 -313 49 98 -28 -29 -240 -365 -736 -1060 -923 -1039 -873 -1124 -486 -423 -756 -1106 -565 -801 -385 -951 -618 -397 -311 -157 -152 -77 27 62 -54 -80 -86 -79 -395 -614 -334 -435 116 -63 395 -220 -290 -364 -275 -418 -118 92 -258 -86 -233 40 -17 164 92 290 220 -44 458 787 968 635 595 542 452 239 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