File name: Pandora270s1_Warsaw-UW_20250913_L2Fit_fwvt1c2d20230919p1-8.txt
File generation date: 20250913T223848.9Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c2p1-8
Local principal investigator: Iwona Stachlewska
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 270
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora270_OF_v3d20230517.txt
Instrument calibration file used: Pandora270s1_CF_v2d20230919.txt
Level 1 file used: Pandora270s1_Warsaw-UW_20250913_L1_smca1c2d20230919p1-8.txt
Full location name: Warsaw Observatory Station, Faculty of Physics, University of Warsaw
Short location name: Warsaw-UW
Country of location: Poland
Location latitude [deg]: 52.2113
Location longitude [deg]: 20.9828
Location altitude [m]: 137
Local noon date: 20250913
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: OoB session based on session 1
First and last pixel inside fitting window: 1624 1774
Nominal wavelengths inside fitting window [nm]: 492.0350 492.1554 492.2759 492.3963 492.5167 492.6371 492.7574 492.8778 492.9981 493.1184 493.2387 493.3590 493.4793 493.5995 493.7197 493.8399 493.9601 494.0803 494.2005 494.3206 494.4407 494.5609 494.6809 494.8010 494.9211 495.0411 495.1611 495.2812 495.4012 495.5211 495.6411 495.7610 495.8810 496.0009 496.1207 496.2406 496.3605 496.4803 496.6001 496.7199 496.8397 496.9595 497.0793 497.1990 497.3187 497.4384 497.5581 497.6778 497.7974 497.9171 498.0367 498.1563 498.2759 498.3955 498.5150 498.6345 498.7541 498.8736 498.9930 499.1125 499.2320 499.3514 499.4708 499.5902 499.7096 499.8290 499.9483 500.0676 500.1870 500.3062 500.4255 500.5448 500.6640 500.7833 500.9025 501.0217 501.1408 501.2600 501.3791 501.4983 501.6174 501.7365 501.8556 501.9746 502.0936 502.2127 502.3317 502.4507 502.5696 502.6886 502.8075 502.9265 503.0454 503.1642 503.2831 503.4020 503.5208 503.6396 503.7584 503.8772 503.9960 504.1147 504.2335 504.3522 504.4709 504.5895 504.7082 504.8269 504.9455 505.0641 505.1827 505.3013 505.4198 505.5384 505.6569 505.7754 505.8939 506.0124 506.1308 506.2493 506.3677 506.4861 506.6045 506.7229 506.8412 506.9595 507.0779 507.1962 507.3144 507.4327 507.5510 507.6692 507.7874 507.9056 508.0238 508.1420 508.2601 508.3782 508.4963 508.6144 508.7325 508.8506 508.9686 509.0866 509.2046 509.3226 509.4406 509.5586 509.6765 509.7944 509.9123
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal
Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal
Column 100: Humidity in head sensor [%], -9=no humidity signal
Column 101: Pressure in head sensor [hPa], -9=no pressure signal
Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250913T042803.4Z 9387.186150 182 1 54.58 2 87.69 86.94 30.53 216.57 0.00 1 0.00 1 0 22 1.093e-02 1.077e-02 5.318e-04 5.296e-04 1.690086e+04 3.627481e+01 1.124031e+03 -6.000000e+00 5.836840e+02 279.83 -2.00 20.00 -2.00 505.42 0.00e+00 3.711367e-03 1.443329e-05 2.194413e-04 -6.000000e+00 3.008023e-04 279.83 -2.00 20.00 -2.00 501.02 0.00e+00 5.583859e-01 1.013742e-02 1.177685e-01 -6.000000e+00 2.148621e-01 228.97 -2.00 3.84 -2.00 502.52 0.00e+00 15.211 0.078 489.00 513.00 1 5.0494e+00 7.7203e-04 2.6540e-02 -6.0000e+00 1.6414e-02 -5.0217e-02 1.9694e-04 3.1326e-03 -6.0000e+00 4.3193e-03 1.3277e-03 3.0976e-04 4.4004e-05 1.6202e-04 -6.0000e+00 1.0070e-03 -1.3294e-02 -5.6892e-05 12 8 8 10 0 0 73.67 25.88 7.44 -0.01329 -0.01115 47 5 1 2 0 1161.080 20.00 25.88 20.98 34.75 33.75 3.8 942.09 -2110 -1924 -962 68 997 1478 2089 2104 2370 1523 1136 607 -78 -523 -987 -926 -689 -151 503 661 488 603 643 601 693 1008 1200 931 79 -1059 -1736 -1752 -1649 -592 382 471 381 54 -344 -676 -548 -128 56 380 926 1282 1160 1154 704 73 -994 -1808 -2130 -2330 -1565 -795 -23 526 643 433 575 877 1077 1057 996 674 370 242 -332 -1112 -1418 -1127 -962 -743 -331 -306 -614 -982 -1486 -1588 -1632 -1369 -1096 -1257 -926 -646 -852 -609 -710 -799 -424 7 809 1289 1254 1165 949 510 -682 -1658 -2524 -2445 -2022 -1004 -71 54 7 -409 -870 -887 -542 -31 259 771 1444 1382 1971 2286 2036 1494 1055 460 117 322 964 986 915 1051 835 647 1013 277 -302 -469 -1107 -1229 -697 -180 -44 409 422 521 608 657 726 945 458 -163 -1122 -1505 -1775 -1844 -1692 -864 62 922 1394 1946 1991 2245 1443 1065 566 -72 -492 -926 -872 -637 -142 483 647 469 581 621 583 677 990 1179 914 77 -1007 -1665 -1679 -1556 -570 380 466 378 53 -337 -658 -533 -125 55 381 939 1310 1159 1177 713 73 -979 -1745 -2083 -2281 -1510 -788 -22 530 653 440 584 893 1105 1090 1027 691 375 242 -331 -1103 -1392 -1101 -948 -739 -333 -310 -617 -973 -1455 -1581 -1617 -1361 -1070 -1238 -919 -650 -866 -617 -714 -799 -423 8 819 1312 1264 1142 922 480 -648 -1554 -2357 -2294 -1893 -976 -70 54 8 -421 -889 -902 -556 -32 266 793 1482 1425 2038 2400 2129 1573 1102 486 121 330 986 1018 953 1100 878 681 1065 291 -313 -483 -1146 -1279 -717 -189 -47 432 454 567 667 726 787 1022 506 -178 -1215 -1614 -1909
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SQ 20250913T043953.7Z 9387.194371 192 1 54.13 2 85.88 89.28 31.62 221.13 0.00 1 0.00 1 0 22 6.384e-03 6.304e-03 3.142e-04 3.136e-04 1.434775e+04 2.112310e+01 9.701733e+02 -6.000000e+00 3.408129e+02 279.83 -2.00 20.00 -2.00 505.37 0.00e+00 2.521233e-03 8.533194e-06 1.544547e-04 -6.000000e+00 1.756354e-04 279.83 -2.00 20.00 -2.00 500.84 0.00e+00 6.417715e-01 6.052431e-03 9.682441e-02 -6.000000e+00 1.254549e-01 228.97 -2.00 3.84 -2.00 502.38 0.00e+00 11.222 0.031 489.00 513.00 1 4.6167e+00 4.6149e-04 1.8689e-02 -6.0000e+00 9.5838e-03 -4.6792e-02 1.1819e-04 2.5377e-03 -6.0000e+00 2.5219e-03 3.6232e-03 -4.3369e-04 2.6407e-05 1.3654e-04 -6.0000e+00 5.8810e-04 5.1296e-04 -1.3575e-04 12 8 8 10 0 0 93.39 25.88 3.37 0.00051 -0.00250 111 12 1 2 0 487.590 19.99 25.88 21.75 34.75 33.75 3.7 944.06 -1143 -1068 -497 84 498 878 1227 1258 1243 917 570 456 -97 -351 -563 -527 -447 -139 309 251 253 366 305 308 517 517 665 646 64 -798 -895 -957 -941 -265 272 205 202 103 -198 -454 -364 -175 -48 210 509 734 660 614 415 65 -631 -1025 -1362 -1347 -883 -473 -55 229 359 307 279 491 636 622 622 384 162 90 -173 -709 -882 -649 -508 -428 -112 -123 -400 -462 -748 -953 -925 -729 -663 -716 -495 -330 -418 -374 -433 -402 -227 53 603 870 830 840 700 394 -229 -993 -1575 -1592 -1249 -664 -29 5 -26 -204 -604 -540 -304 -80 101 393 646 700 1066 1358 1195 867 563 287 87 200 506 441 439 621 418 415 624 125 -247 -128 -656 -792 -306 -84 -70 245 334 230 377 380 453 668 378 -151 -666 -892 -971 -1038 -975 -456 78 478 844 1201 1228 1218 894 550 443 -93 -334 -532 -500 -429 -134 303 247 251 364 304 307 520 514 661 651 63 -774 -862 -921 -916 -259 270 209 206 104 -199 -452 -361 -174 -49 211 517 751 677 626 419 65 -626 -1008 -1319 -1302 -865 -468 -55 234 363 310 281 496 648 636 636 389 162 90 -172 -701 -878 -643 -499 -425 -112 -125 -402 -456 -740 -935 -902 -714 -656 -701 -489 -331 -416 -371 -435 -401 -227 52 601 876 829 831 682 379 -215 -935 -1471 -1494 -1178 -640 -29 5 -26 -206 -606 -538 -305 -82 102 401 660 718 1097 1417 1246 907 584 297 89 201 510 449 449 638 431 427 642 128 -250 -130 -657 -797 -312 -86 -74 255 353 243 401 407 486 717 403 -160 -705 -932 -1013
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