File name: Pandora270s1_Warsaw-UW_20251211_L2Fit_fwvt1c6d20231207p1-8.txt File generation date: 20251211T223344.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c6p1-8 Local principal investigator: Iwona Stachlewska Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 270 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora270_OF_v3d20230517.txt Instrument calibration file used: Pandora270s1_CF_v6d20231207.txt Level 1 file used: Pandora270s1_Warsaw-UW_20251211_L1_smca1c6d20231207p1-8.txt Full location name: Warsaw Observatory Station, Faculty of Physics, University of Warsaw Short location name: Warsaw-UW Country of location: Poland Location latitude [deg]: 52.2113 Location longitude [deg]: 20.9828 Location altitude [m]: 137 Local noon date: 20251211 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1624 1775 Nominal wavelengths inside fitting window [nm]: 492.0035 492.1240 492.2444 492.3648 492.4851 492.6055 492.7259 492.8462 492.9665 493.0868 493.2071 493.3273 493.4476 493.5678 493.6880 493.8082 493.9284 494.0485 494.1687 494.2888 494.4089 494.5290 494.6491 494.7691 494.8892 495.0092 495.1292 495.2492 495.3692 495.4891 495.6091 495.7290 495.8489 495.9688 496.0886 496.2085 496.3283 496.4482 496.5680 496.6878 496.8075 496.9273 497.0470 497.1667 497.2864 497.4061 497.5258 497.6454 497.7651 497.8847 498.0043 498.1239 498.2434 498.3630 498.4825 498.6020 498.7215 498.8410 498.9605 499.0799 499.1994 499.3188 499.4382 499.5576 499.6769 499.7963 499.9156 500.0349 500.1542 500.2735 500.3928 500.5120 500.6312 500.7504 500.8696 500.9888 501.1080 501.2271 501.3462 501.4654 501.5844 501.7035 501.8226 501.9416 502.0606 502.1797 502.2986 502.4176 502.5366 502.6555 502.7744 502.8933 503.0122 503.1311 503.2499 503.3688 503.4876 503.6064 503.7252 503.8440 503.9627 504.0814 504.2002 504.3189 504.4375 504.5562 504.6749 504.7935 504.9121 505.0307 505.1493 505.2678 505.3864 505.5049 505.6234 505.7419 505.8604 505.9789 506.0973 506.2157 506.3341 506.4525 506.5709 506.6893 506.8076 506.9259 507.0442 507.1625 507.2808 507.3991 507.5173 507.6355 507.7537 507.8719 507.9901 508.1082 508.2264 508.3445 508.4626 508.5807 508.6987 508.8168 508.9348 509.0528 509.1708 509.2888 509.4068 509.5247 509.6426 509.7605 509.8784 509.9963 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-253: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 254-405: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20251211T084738.9Z 9476.366422 337 1 54.97 2 78.46 156.21 72.65 256.35 0.00 1 0.00 1 0 15 9.700e-03 9.687e-03 2.348e-03 2.341e-03 1.868310e+03 1.279863e+02 1.566696e+02 -6.000000e+00 4.937510e+02 268.16 -2.00 20.00 -2.00 505.25 0.00e+00 5.012139e-04 6.144178e-05 3.483471e-05 -6.000000e+00 2.592390e-04 268.16 -2.00 20.00 -2.00 500.34 0.00e+00 5.145036e-01 4.583017e-02 1.432423e-02 -6.000000e+00 1.896634e-01 220.25 -2.00 3.84 -2.00 501.95 0.00e+00 4.837 0.002 489.00 513.00 1 9.4520e+00 3.4995e-03 6.9380e-03 -6.0000e+00 1.4452e-02 2.3173e-02 9.1383e-04 5.1575e-04 -6.0000e+00 3.8025e-03 7.4821e-05 -2.2368e-03 2.0946e-04 2.6104e-05 -6.0000e+00 8.9372e-04 -1.4180e-02 1.7252e-04 12 9 8 11 32 0 99.98 25.82 1.60 -0.01418 -0.02970 29 3 1 2 0 1895.210 20.00 25.82 16.49 34.75 33.75 3.8 920.03 -806 -1183 274 -1191 1096 -107 862 673 2473 1276 417 -723 -147 371 -1135 273 196 1197 870 -1996 -92 -295 626 -331 -1194 -632 -78 -6 571 -146 -1314 360 483 1025 68 -846 -90 17 -176 -659 974 1042 693 -1579 915 358 143 1357 744 1459 -1045 -1610 -626 -614 -1308 -93 -332 -55 -418 -669 -535 -167 -452 -252 -821 8 317 2562 415 -1983 -723 1236 1437 -468 -482 575 24 167 -597 -284 1082 138 -280 -1921 -878 -730 -1968 1794 345 -674 -325 -1240 -11 1193 -218 839 -352 2529 -1183 -185 -610 -1230 -669 485 936 -490 -979 349 772 -24 -687 286 637 286 305 -1520 -213 -330 979 1407 395 33 28 349 93 845 -696 439 354 -724 849 1162 -686 1595 -1448 1359 -846 421 -272 -863 -1509 179 1849 32 -465 2950 -1225 -1184 -1613 715 1018 900000 -754 -1115 261 -1199 1113 -113 915 726 2630 1360 441 -765 -152 375 -1153 274 199 1225 918 -2090 -101 -324 681 -344 -1255 -663 -81 -6 609 -152 -1341 360 486 1053 74 -890 -94 17 -179 -704 1017 1091 735 -1637 935 370 148 1378 749 1512 -1077 -1616 -609 -594 -1294 -94 -346 -55 -422 -676 -538 -168 -457 -255 -834 8 310 2554 417 -2013 -715 1193 1394 -468 -488 580 24 164 -583 -273 1025 133 -273 -1921 -876 -696 -1917 1782 328 -648 -313 -1214 -11 1175 -217 820 -342 2477 -1103 -176 -572 -1163 -640 448 895 -486 -975 339 734 -23 -660 276 623 285 307 -1566 -218 -340 994 1409 394 32 27 335 90 817 -684 427 343 -709 818 1107 -654 1462 -1353 1230 -792 399 -265 -858 -1526 180 1827 33 -475 2920 -1255 -1190 -1584 672 948 900000 SQ 20251211T090333.4Z 9476.377470 344 1 5.21 2 77.54 159.83 75.03 259.51 0.00 1 0.00 1 0 15 7.081e-03 7.003e-03 5.349e-03 5.329e-03 3.311462e+03 3.031665e+02 2.250962e+02 -6.000000e+00 3.603164e+02 268.16 -2.00 20.00 -2.00 505.25 0.00e+00 4.086028e-04 1.392383e-04 2.651793e-05 -6.000000e+00 1.889214e-04 268.16 -2.00 20.00 -2.00 500.47 0.00e+00 3.358907e-01 1.035228e-01 3.073385e-02 -6.000000e+00 1.373895e-01 220.25 -2.00 3.84 -2.00 502.04 0.00e+00 4.509 0.002 489.00 513.00 1 6.0100e+00 7.9070e-03 6.8402e-03 -6.0000e+00 1.0481e-02 2.9108e-04 2.0447e-03 7.8104e-04 -6.0000e+00 2.7339e-03 2.4779e-03 -2.3477e-04 4.7799e-04 3.1348e-05 -6.0000e+00 6.5065e-04 -5.5026e-03 -3.9175e-05 12 8 8 10 0 0 37.54 25.82 4.09 -0.00550 -0.00713 2167 515 3 2 0 2.400 19.99 25.82 16.71 34.75 33.75 3.9 921.59 900000 -1630 81 -221 -307 -265 746 189 1319 -319 -289 273 -243 418 -333 -213 33 357 1253 -288 866 -833 390 -768 -205 201 868 19 41 214 -896 -358 -1520 77 188 -630 -1106 83 119 -406 486 -81 -133 -627 162 790 1153 814 645 -169 -55 -80 403 -893 -130 114 -642 757 -126 1076 614 -430 661 43 763 898 -110 779 -918 415 -948 384 -573 48 -139 1143 -37 -256 -823 -1869 -630 -1902 181 -956 -452 1007 -632 665 -308 -195 708 -89 -717 -314 -90 -606 1040 277 626 -500 -512 -387 -1143 43 1767 214 -891 874 869 503 509 -287 155 -761 1006 706 -33 16 764 718 -557 -695 738 -992 722 279 1703 -696 -894 -77 134 682 -1759 32 -1053 -636 -1515 -139 79 984 427 764 255 460 304 -254 -63 288 -363 -786 197 -160 900000 -1489 74 -212 -305 -269 766 198 1374 -335 -299 277 -245 410 -325 -208 32 357 1278 -305 913 -894 414 -825 -220 215 925 20 43 217 -889 -352 -1523 77 198 -685 -1207 88 125 -424 500 -84 -139 -668 173 847 1231 865 677 -175 -55 -78 383 -853 -125 113 -660 784 -133 1118 638 -452 693 45 800 931 -113 784 -928 408 -932 371 -563 47 -140 1141 -37 -252 -802 -1821 -605 -1861 175 -943 -448 997 -642 667 -312 -197 713 -91 -748 -308 -88 -588 1050 276 603 -474 -477 -360 -1012 39 1640 208 -877 836 817 470 478 -276 150 -756 993 702 -33 16 771 719 -557 -685 706 -957 688 269 1621 -679 -873 -74 129 649 -1688 30 -978 -585 -1422 -131 77 958 423 760 256 464 309 -260 -64 287 -354 -754 185 -153 SQ 20251211T090338.8Z 9476.377532 344 2 5.21 2 77.54 159.85 75.04 259.53 0.00 1 0.00 1 0 15 3.051e-02 3.019e-02 2.332e-02 2.313e-02 2.697619e+03 1.322148e+03 7.163659e+01 -6.000000e+00 1.552330e+03 268.16 -2.00 20.00 -2.00 505.34 0.00e+00 -8.144613e-04 6.096629e-04 4.986543e-05 -6.000000e+00 8.139771e-04 268.16 -2.00 20.00 -2.00 500.39 0.00e+00 1.388415e+00 4.489806e-01 5.616327e-02 -6.000000e+00 5.921650e-01 220.25 -2.00 3.84 -2.00 502.05 0.00e+00 4.507 0.002 489.00 513.00 1 7.4679e+00 3.4371e-02 7.7252e-03 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