File name: Pandora270s1_Warsaw-UW_20260320_L2Fit_fout2c6d20231207p1-8.txt File generation date: 20260320T224935.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Iwona Stachlewska Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 270 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora270_OF_v3d20230517.txt Instrument calibration file used: Pandora270s1_CF_v6d20231207.txt Level 1 file used: Pandora270s1_Warsaw-UW_20260320_L1_smca1c6d20231207p1-8.txt Full location name: Warsaw Observatory Station, Faculty of Physics, University of Warsaw Short location name: Warsaw-UW Country of location: Poland Location latitude [deg]: 52.2113 Location longitude [deg]: 20.9828 Location altitude [m]: 137 Local noon date: 20260320 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0251 305.1656 305.3062 305.4467 305.5872 305.7277 305.8682 306.0087 306.1492 306.2897 306.4301 306.5705 306.7110 306.8514 306.9918 307.1322 307.2726 307.4129 307.5533 307.6936 307.8339 307.9743 308.1146 308.2549 308.3951 308.5354 308.6757 308.8159 308.9561 309.0964 309.2366 309.3768 309.5169 309.6571 309.7973 309.9374 310.0776 310.2177 310.3578 310.4979 310.6380 310.7781 310.9181 311.0582 311.1982 311.3382 311.4782 311.6182 311.7582 311.8982 312.0382 312.1781 312.3181 312.4580 312.5979 312.7378 312.8777 313.0176 313.1575 313.2973 313.4372 313.5770 313.7168 313.8567 313.9965 314.1362 314.2760 314.4158 314.5555 314.6953 314.8350 314.9747 315.1144 315.2541 315.3938 315.5334 315.6731 315.8127 315.9524 316.0920 316.2316 316.3712 316.5108 316.6503 316.7899 316.9294 317.0690 317.2085 317.3480 317.4875 317.6270 317.7665 317.9059 318.0454 318.1848 318.3242 318.4636 318.6030 318.7424 318.8818 319.0212 319.1605 319.2999 319.4392 319.5785 319.7178 319.8571 319.9964 320.1357 320.2749 320.4142 320.5534 320.6926 320.8318 320.9710 321.1102 321.2494 321.3885 321.5277 321.6668 321.8059 321.9451 322.0842 322.2232 322.3623 322.5014 322.6404 322.7795 322.9185 323.0575 323.1965 323.3355 323.4745 323.6135 323.7524 323.8914 324.0303 324.1692 324.3081 324.4470 324.5859 324.7248 324.8636 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260320T081737.9Z 9575.345577 127 1 54.13 2 60.58 136.94 60.00 117.03 0.00 1 0.00 1 0 17 4.325e-02 8.514e-03 7.395e-03 1.610e-03 3.692726e-01 8.326898e-04 4.866136e-03 -6.000000e+00 2.555947e-02 225.45 -2.00 3.84 -2.00 317.65 0.00e+00 6.080161e-04 1.296007e-04 1.508031e-04 -6.000000e+00 1.073059e-03 268.99 -2.00 20.00 -2.00 317.20 0.00e+00 2.027 0.000 302.00 328.00 3 5.3116e+00 2.1957e-03 2.8837e-02 -6.0000e+00 6.3413e-02 7.6576e-02 2.4636e-03 2.0561e-02 -6.0000e+00 6.8782e-02 -2.7359e-02 1.5763e-03 1.0306e-02 -6.0000e+00 4.0726e-02 4.9648e-03 8.1050e-04 3.0248e-03 -6.0000e+00 1.7265e-02 2.1083e-04 -2.4140e-04 4.8277e-05 3.6387e-05 -6.0000e+00 1.2833e-03 -7.1105e-03 0.0000e+00 11 8 0 10 0 0 99.94 25.77 0.31 -0.00711 -0.00892 25 3 1 8 0 2164.890 19.99 25.77 14.36 34.75 33.50 3.9 911.76 677 -14217 -9293 -26127 -10486 6483 10461 5434 -7241 -15392 10480 -3631 15068 -11763 -2965 4655 8372 -1211 870 -601 -1156 6307 2609 -56 6189 6776 -1657 -2115 -596 -5940 8734 -344 5593 -2542 -718 -3983 313 -3462 -1573 -1630 -1633 503 -1650 -1345 963 -1473 -745 314 -1004 -1213 637 1326 2720 2569 189 1209 730 -96 1687 1593 -727 1423 1612 772 1941 207 -477 189 -846 215 472 662 -393 -502 968 848 -297 -1521 -281 -1564 -126 -1334 -1102 -1185 -492 -1364 -951 -549 284 620 -51 -226 841 305 -327 -289 197 1550 474 -88 -724 -435 -223 594 -797 -1152 -673 -437 -304 -273 168 303 623 374 -503 -387 211 2 154 783 429 434 76 439 472 -65 -432 679 979 847 793 75 -506 -632 -167 -71 -245 119 169 213 -127 -630 -555 42 -1156 -760 -2474 -781 385 614 370 -625 -1554 843 -350 1351 -1616 -437 724 1365 -209 155 -113 -225 1144 500 -12 1278 1457 -394 -490 -129 -1334 1790 -85 1436 -752 -205 -1140 90 -1178 -625 -703 -794 257 -896 -687 523 -757 -410 169 -546 -669 333 743 1613 1622 128 837 519 -64 1174 1091 -516 969 1192 624 1615 170 -372 142 -662 184 418 623 -380 -473 844 723 -232 -1128 -209 -1295 -109 -1309 -1106 -1264 -552 -1552 -1140 -681 354 756 -60 -257 874 304 -335 -323 230 1891 638 -123 -976 -542 -271 696 -993 -1451 -887 -604 -420 -403 251 473 970 560 -747 -535 295 2 217 1167 665 671 116 642 658 -91 -583 885 1322 1173 1180 113 -788 -1017 -267 -119 -431 204 292 382 -221 -1051 -935 SS 20260320T081844.7Z 9575.346351 129 1 5.37 2 60.47 137.23 59.85 117.29 0.00 1 0.00 1 0 17 2.241e-02 6.684e-03 1.324e-02 3.623e-03 3.614297e-01 1.878340e-03 4.793361e-03 -6.000000e+00 1.323694e-02 225.45 -2.00 3.84 -2.00 317.32 0.00e+00 6.175349e-04 2.648010e-04 9.702775e-05 -6.000000e+00 5.559390e-04 268.99 -2.00 20.00 -2.00 316.87 0.00e+00 2.020 0.000 302.00 328.00 3 4.5516e+00 4.9223e-03 2.8449e-02 -6.0000e+00 3.2840e-02 4.8170e-02 5.5003e-03 2.0099e-02 -6.0000e+00 3.5628e-02 -1.7716e-02 3.3919e-03 1.0058e-02 -6.0000e+00 2.1096e-02 3.2877e-03 1.7083e-03 2.9433e-03 -6.0000e+00 8.9363e-03 4.6514e-04 -5.4440e-04 1.0814e-04 3.6551e-05 -6.0000e+00 6.6516e-04 -2.5380e-03 0.0000e+00 12 9 1 12 1 1 83.95 25.77 0.41 -0.00254 -0.00663 4 5 1 8 0 1073.680 19.99 25.77 14.38 34.75 33.75 3.9 912.22 -2866 -7894 -14008 -7322 -1512 -790 165 7625 -4000 -5944 4172 -5474 2127 -4367 -1607 -473 878 -742 91 1473 -1129 4260 3873 -934 2736 3032 979 -4327 -689 -3547 2813 -256 2407 47 -2448 -2873 -541 -2784 -706 588 -2058 -528 -186 -466 763 1233 -21 379 -852 -1419 -65 1237 1089 1865 518 1105 797 678 979 -513 291 1600 1266 1095 960 196 -175 -344 -64 747 862 -3 -170 375 -30 697 -409 -355 -771 -1301 -38 -1104 -1275 -1778 -1640 -985 -1260 -244 -199 163 -221 124 149 114 238 425 743 1180 462 112 -851 401 -174 78 -652 -538 -233 -809 53 -89 60 410 836 157 -296 -103 174 -1 114 176 262 -285 -109 470 185 144 450 586 764 679 459 49 -150 -410 -514 -5 -178 221 117 113 -376 -405 -409 -237 -778 -1408 -740 -133 -65 14 657 -432 -706 461 -694 280 -654 -274 -91 180 -164 21 349 -282 1014 942 -230 690 798 267 -1207 -176 -917 722 -75 750 16 -835 -956 -185 -1025 -303 274 -1108 -280 -102 -262 427 687 -12 210 -475 -806 -38 772 685 1238 366 798 590 505 717 -375 214 1155 998 885 807 161 -144 -275 -53 637 771 -2 -167 356 -27 596 -339 -276 -611 -1079 -36 -1100 -1322 -1872 -1827 -1112 -1511 -301 -237 199 -256 138 161 117 251 465 864 1460 601 151 -1108 500 -211 91 -811 -683 -309 -1089 74 -130 89 636 1290 233 -430 -145 235 -1 165 260 384 -421 -163 677 265 197 610 776 1007 966 675 73 -231 -632 -831 -9 -304 383 200 197 -635 -681 -661 SS 20260320T082031.9Z 9575.347591 131 1 54.32 2 60.28 137.70 59.61 117.70 0.00 1 0.00 1 0 25 1.525e-02 5.401e-03 1.532e-03 5.105e-04 3.593657e-01 2.652238e-04 4.757499e-03 -6.000000e+00 9.008143e-03 225.45 -2.00 3.84 -2.00 316.98 0.00e+00 4.635636e-04 3.413305e-05 8.500411e-05 -6.000000e+00 3.782273e-04 268.99 -2.00 20.00 -2.00 316.53 0.00e+00 2.008 0.000 302.00 328.00 3 3.2696e+00 6.9100e-04 2.8221e-02 -6.0000e+00 2.2349e-02 3.9941e-02 7.7162e-04 1.9882e-02 -6.0000e+00 2.4243e-02 -1.7815e-02 4.6414e-04 9.9415e-03 -6.0000e+00 1.4354e-02 3.6117e-03 2.2864e-04 2.8913e-03 -6.0000e+00 6.0840e-03 1.7083e-03 -2.2622e-04 1.5202e-05 3.6377e-05 -6.0000e+00 4.5238e-04 -5.9946e-03 0.0000e+00 10 0 0 10 0 0 99.92 25.77 0.32 -0.00599 -0.00769 232 24 1 8 0 234.130 19.99 25.77 14.50 34.75 33.75 3.9 913.51 -2851 -5582 -4872 -8304 -6889 -4534 -2708 -1514 -1966 -4861 -2092 -2584 -1077 -2321 -919 83 427 338 958 715 1003 1328 1656 801 1420 1336 203 -907 -446 -369 1920 1308 2096 -24 -778 -1579 -1165 -913 107 -139 -619 -557 -875 -720 -124 -393 -158 -186 -426 -131 710 976 1258 1004 785 851 734 503 523 532 422 1109 1326 946 777 -8 -281 -363 -66 410 322 178 -19 -134 182 121 -166 -434 -259 -543 -592 -1048 -1585 -1662 -1317 -1132 -830 -307 -59 152 200 286 361 393 550 403 472 735 236 -71 -292 -473 -511 -50 -493 -533 -724 -585 -278 57 257 303 245 140 -17 273 334 431 407 292 -53 -21 84 248 357 224 310 669 727 606 430 100 -170 -112 -159 -260 -302 -67 -44 -121 -127 -351 -412 -290 -660 -604 -1041 -783 -476 -288 -176 -256 -702 -303 -392 -180 -421 -192 20 100 84 250 194 279 370 469 241 451 413 65 -282 -141 -115 616 432 754 -9 -301 -597 -430 -383 50 -72 -343 -331 -514 -431 -74 -236 -94 -110 -250 -78 438 646 847 720 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