File name: Pandora270s1_Warsaw-UW_20260415_L2Fit_fout2c6d20231207p1-8.txt File generation date: 20260415T224054.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Iwona Stachlewska Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 270 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora270_OF_v3d20230517.txt Instrument calibration file used: Pandora270s1_CF_v6d20231207.txt Level 1 file used: Pandora270s1_Warsaw-UW_20260415_L1_smca1c6d20231207p1-8.txt Full location name: Warsaw Observatory Station, Faculty of Physics, University of Warsaw Short location name: Warsaw-UW Country of location: Poland Location latitude [deg]: 52.2113 Location longitude [deg]: 20.9828 Location altitude [m]: 137 Local noon date: 20260415 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0251 305.1656 305.3062 305.4467 305.5872 305.7277 305.8682 306.0087 306.1492 306.2897 306.4301 306.5705 306.7110 306.8514 306.9918 307.1322 307.2726 307.4129 307.5533 307.6936 307.8339 307.9743 308.1146 308.2549 308.3951 308.5354 308.6757 308.8159 308.9561 309.0964 309.2366 309.3768 309.5169 309.6571 309.7973 309.9374 310.0776 310.2177 310.3578 310.4979 310.6380 310.7781 310.9181 311.0582 311.1982 311.3382 311.4782 311.6182 311.7582 311.8982 312.0382 312.1781 312.3181 312.4580 312.5979 312.7378 312.8777 313.0176 313.1575 313.2973 313.4372 313.5770 313.7168 313.8567 313.9965 314.1362 314.2760 314.4158 314.5555 314.6953 314.8350 314.9747 315.1144 315.2541 315.3938 315.5334 315.6731 315.8127 315.9524 316.0920 316.2316 316.3712 316.5108 316.6503 316.7899 316.9294 317.0690 317.2085 317.3480 317.4875 317.6270 317.7665 317.9059 318.0454 318.1848 318.3242 318.4636 318.6030 318.7424 318.8818 319.0212 319.1605 319.2999 319.4392 319.5785 319.7178 319.8571 319.9964 320.1357 320.2749 320.4142 320.5534 320.6926 320.8318 320.9710 321.1102 321.2494 321.3885 321.5277 321.6668 321.8059 321.9451 322.0842 322.2232 322.3623 322.5014 322.6404 322.7795 322.9185 323.0575 323.1965 323.3355 323.4745 323.6135 323.7524 323.8914 324.0303 324.1692 324.3081 324.4470 324.5859 324.7248 324.8636 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260415T072832.6Z 9601.311488 137 1 54.37 2 56.83 120.72 55.48 156.17 0.00 1 0.00 1 0 17 8.554e-03 5.189e-03 3.787e-04 1.831e-04 2.983128e-01 9.637482e-05 3.976012e-03 -6.000000e+00 5.095889e-03 227.62 -2.00 3.84 -2.00 316.21 0.00e+00 4.156555e-04 1.027787e-05 5.142906e-05 -6.000000e+00 2.149941e-04 272.23 -2.00 20.00 -2.00 315.72 0.00e+00 1.822 0.000 302.00 328.00 3 1.5291e+00 2.4968e-04 2.4692e-02 -6.0000e+00 1.2693e-02 2.2081e-03 2.7760e-04 1.6705e-02 -6.0000e+00 1.3740e-02 -8.1981e-03 1.6103e-04 8.2685e-03 -6.0000e+00 8.1372e-03 5.7083e-04 7.4866e-05 2.3644e-03 -6.0000e+00 3.4427e-03 1.2998e-02 -1.8939e-04 5.4957e-06 3.1022e-05 -6.0000e+00 2.5400e-04 -5.3111e-03 0.0000e+00 10 0 0 10 0 0 51.22 25.76 0.34 -0.00531 -0.00673 1456 151 2 8 0 37.340 20.00 25.76 20.97 34.75 33.75 3.8 940.50 -1461 -1785 -1955 -3003 -3965 -2716 -1866 -641 -291 -1148 -1356 -1495 -687 -314 318 129 97 333 765 653 875 862 1018 855 838 790 245 -200 -39 652 1083 1690 1533 306 -1033 -1288 -1322 -760 -68 -276 -718 -709 -805 -727 -463 -341 -409 -463 -475 -107 475 839 940 953 867 741 686 475 466 428 655 965 1316 1036 458 18 -316 -359 128 503 339 35 -12 -140 -47 -27 -186 -269 -205 -377 -594 -1030 -1578 -1510 -1290 -998 -665 -247 -59 55 204 355 403 482 699 563 613 576 149 -68 -253 -479 -471 -107 -319 -536 -733 -561 -322 59 212 268 179 102 19 252 389 465 398 182 -205 -122 38 199 328 360 407 716 748 623 377 141 -89 -77 -97 -230 -328 -125 -71 -104 -144 -349 -424 -252 -346 -397 -598 -729 -503 -325 -121 -61 -260 -315 -332 -166 -87 94 40 32 116 278 232 318 315 377 332 344 319 101 -80 -15 251 431 684 675 136 -455 -581 -593 -367 -37 -161 -453 -478 -540 -497 -316 -233 -277 -308 -325 -73 321 605 694 717 682 578 546 381 369 335 518 804 1144 938 416 16 -268 -304 110 460 323 35 -12 -138 -45 -25 -163 -228 -175 -328 -564 -1029 -1675 -1649 -1449 -1164 -799 -300 -73 66 238 404 432 502 738 626 717 711 191 -89 -320 -596 -559 -127 -391 -669 -939 -735 -443 82 306 393 261 145 27 338 504 611 539 257 -297 -177 54 281 450 481 532 909 981 835 527 203 -129 -115 -148 -357 -519 -203 -117 -170 -232 -554 -650 SS 20260415T073804.5Z 9601.318107 139 1 54.37 2 55.59 123.12 54.89 158.91 0.00 1 0.00 1 0 17 8.386e-03 5.174e-03 3.435e-04 1.731e-04 2.899489e-01 9.115782e-05 3.866692e-03 -6.000000e+00 4.995577e-03 227.62 -2.00 3.84 -2.00 316.09 0.00e+00 4.376580e-04 9.458260e-06 4.890531e-05 -6.000000e+00 2.107648e-04 272.23 -2.00 20.00 -2.00 315.60 0.00e+00 1.764 0.000 302.00 328.00 3 1.4861e+00 2.3590e-04 2.3951e-02 -6.0000e+00 1.2443e-02 4.9748e-05 2.6230e-04 1.6229e-02 -6.0000e+00 1.3469e-02 -7.2847e-03 1.5177e-04 8.0320e-03 -6.0000e+00 7.9770e-03 3.6077e-04 7.0036e-05 2.2993e-03 -6.0000e+00 3.3748e-03 1.4539e-02 -1.9424e-04 5.2004e-06 3.0472e-05 -6.0000e+00 2.4901e-04 -5.1630e-03 0.0000e+00 10 0 0 10 0 0 97.32 25.77 0.33 -0.00516 -0.00662 1605 167 2 8 0 33.870 20.00 25.77 22.19 34.75 33.50 3.9 947.29 -1182 -1581 -1804 -2902 -3598 -2715 -1980 -672 -134 -1105 -1306 -1469 -681 -349 158 164 71 308 871 728 994 933 1215 937 883 872 243 -178 8 676 1070 1629 1615 397 -1001 -1282 -1270 -829 -37 -247 -752 -777 -830 -784 -457 -442 -489 -466 -495 -150 507 839 1001 938 784 718 689 508 453 429 709 963 1289 977 446 -30 -308 -359 109 512 317 93 0 -90 -53 -44 -178 -257 -220 -359 -621 -1031 -1571 -1539 -1296 -950 -685 -248 -41 83 196 348 412 486 679 556 594 577 128 -67 -253 -503 -465 -100 -308 -505 -729 -556 -335 97 234 259 171 67 26 247 334 484 404 175 -179 -111 25 199 314 342 412 699 735 589 361 92 -92 -50 -88 -220 -296 -128 -84 -135 -134 -330 -408 -221 -332 -396 -625 -713 -501 -372 -137 -30 -250 -303 -349 -176 -96 50 54 25 107 315 273 382 360 474 362 360 371 105 -75 3 273 446 690 701 183 -458 -569 -592 -416 -21 -150 -492 -520 -577 -555 -323 -312 -343 -320 -335 -101 353 597 730 723 610 574 562 417 367 344 575 793 1108 875 413 -27 -266 -308 96 461 307 93 0 -90 -52 -40 -153 -213 -183 -315 -577 -1041 -1635 -1649 -1468 -1088 -809 -304 -49 101 231 388 445 510 721 604 697 714 164 -89 -321 -628 -554 -117 -369 -632 -938 -732 -451 135 338 379 249 96 36 331 431 635 546 247 -258 -161 36 281 432 457 538 887 962 787 504 132 -133 -73 -133 -338 -465 -206 -137 -218 -215 -521 -623 SS 20260415T073956.5Z 9601.319404 142 1 12.99 2 55.35 123.60 54.78 159.46 0.00 1 0.00 1 0 17 8.533e-03 5.247e-03 9.855e-04 4.999e-04 2.887346e-01 2.630708e-04 3.851736e-03 -6.000000e+00 5.083226e-03 227.62 -2.00 3.84 -2.00 316.06 0.00e+00 4.489589e-04 2.722189e-05 4.778721e-05 -6.000000e+00 2.144570e-04 272.23 -2.00 20.00 -2.00 315.58 0.00e+00 1.754 0.000 302.00 328.00 3 2.1754e+00 6.8056e-04 2.3830e-02 -6.0000e+00 1.2661e-02 6.9194e-03 7.5625e-04 1.6161e-02 -6.0000e+00 1.3705e-02 -8.0136e-03 4.3740e-04 7.9974e-03 -6.0000e+00 8.1169e-03 4.7912e-04 2.0189e-04 2.2907e-03 -6.0000e+00 3.4342e-03 7.3618e-03 -1.7128e-04 1.5005e-05 3.0445e-05 -6.0000e+00 2.5336e-04 -5.4907e-03 0.0000e+00 12 1 1 12 1 1 99.84 25.77 0.34 -0.00549 -0.00678 181 79 2 8 0 71.340 20.00 25.77 22.32 34.75 33.50 4.0 948.74 -1169 -2184 -1636 -3279 -3468 -2981 -1581 -332 -274 -773 -1332 -1446 -663 -680 362 203 384 156 864 953 792 1087 1009 867 1095 754 253 -66 -94 468 1373 1580 1629 192 -898 -1256 -1308 -719 -90 -242 -810 -760 -933 -812 -488 -534 -403 -657 -438 -54 483 833 1056 960 767 684 641 500 517 494 637 1038 1279 998 459 17 -394 -432 104 466 340 17 29 -160 12 51 -142 -205 -251 -388 -672 -996 -1497 -1508 -1286 -957 -685 -248 -24 1 112 370 375 572 720 551 599 553 175 -68 -241 -539 -496 -91 -346 -517 -731 -510 -327 93 191 257 196 140 34 197 319 482 424 191 -173 -149 1 255 354 356 392 678 760 583 407 129 -85 -61 -98 -223 -356 -146 -54 -72 -138 -352 -456 -221 -465 -362 -715 -692 -556 -298 -68 -62 -176 -310 -345 -172 -189 114 67 136 55 314 358 305 419 395 355 446 321 110 -28 -39 189 570 668 745 89 -409 -587 -608 -359 -50 -146 -528 -506 -646 -572 -344 -375 -280 -449 -294 -37 334 612 794 735 614 542 518 407 415 392 512 877 1126 915 421 16 -349 -368 90 428 325 17 29 -158 12 47 -125 -174 -214 -348 -637 -991 -1581 -1638 -1436 -1110 -818 -299 -30 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