File name: Pandora270s1_Warsaw-UW_20260416_L2Fit_fwvt1c6d20231207p1-8.txt
File generation date: 20260416T224350.8Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c6p1-8
Local principal investigator: Iwona Stachlewska
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 270
Spectrometer number: 1
Processing software version used: BlickP v1.8.88
Instrument operation file used: Pandora270_OF_v3d20230517.txt
Instrument calibration file used: Pandora270s1_CF_v6d20231207.txt
Level 1 file used: Pandora270s1_Warsaw-UW_20260416_L1_smca1c6d20231207p1-8.txt
Full location name: Warsaw Observatory Station, Faculty of Physics, University of Warsaw
Short location name: Warsaw-UW
Country of location: Poland
Location latitude [deg]: 52.2113
Location longitude [deg]: 20.9828
Location altitude [m]: 137
Local noon date: 20260416
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1624 1775
Nominal wavelengths inside fitting window [nm]: 492.0035 492.1240 492.2444 492.3648 492.4851 492.6055 492.7259 492.8462 492.9665 493.0868 493.2071 493.3273 493.4476 493.5678 493.6880 493.8082 493.9284 494.0485 494.1687 494.2888 494.4089 494.5290 494.6491 494.7691 494.8892 495.0092 495.1292 495.2492 495.3692 495.4891 495.6091 495.7290 495.8489 495.9688 496.0886 496.2085 496.3283 496.4482 496.5680 496.6878 496.8075 496.9273 497.0470 497.1667 497.2864 497.4061 497.5258 497.6454 497.7651 497.8847 498.0043 498.1239 498.2434 498.3630 498.4825 498.6020 498.7215 498.8410 498.9605 499.0799 499.1994 499.3188 499.4382 499.5576 499.6769 499.7963 499.9156 500.0349 500.1542 500.2735 500.3928 500.5120 500.6312 500.7504 500.8696 500.9888 501.1080 501.2271 501.3462 501.4654 501.5844 501.7035 501.8226 501.9416 502.0606 502.1797 502.2986 502.4176 502.5366 502.6555 502.7744 502.8933 503.0122 503.1311 503.2499 503.3688 503.4876 503.6064 503.7252 503.8440 503.9627 504.0814 504.2002 504.3189 504.4375 504.5562 504.6749 504.7935 504.9121 505.0307 505.1493 505.2678 505.3864 505.5049 505.6234 505.7419 505.8604 505.9789 506.0973 506.2157 506.3341 506.4525 506.5709 506.6893 506.8076 506.9259 507.0442 507.1625 507.2808 507.3991 507.5173 507.6355 507.7537 507.8719 507.9901 508.1082 508.2264 508.3445 508.4626 508.5807 508.6987 508.8168 508.9348 509.0528 509.1708 509.2888 509.4068 509.5247 509.6426 509.7605 509.8784 509.9963
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal
Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal
Column 100: Humidity in head sensor [%], -9=no humidity signal
Column 101: Pressure in head sensor [hPa], -9=no pressure signal
Columns 102-253: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 254-405: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20260416T054054.3Z 9602.236739 87 1 10.96 2 72.08 96.62 66.19 113.63 0.00 1 0.00 1 0 15 3.042e-03 3.020e-03 1.990e-04 1.988e-04 1.895849e+03 1.089894e+01 1.513396e+02 -6.000000e+00 1.576421e+02 272.34 -2.00 20.00 -2.00 505.29 0.00e+00 8.223308e-04 5.246906e-06 4.639725e-05 -6.000000e+00 8.192475e-05 272.34 -2.00 20.00 -2.00 500.61 0.00e+00 2.984517e-01 3.844112e-03 1.540009e-02 -6.000000e+00 5.945211e-02 227.72 -2.00 3.84 -2.00 502.18 0.00e+00 3.206 0.001 489.00 513.00 1 3.6418e+00 2.9316e-04 4.8256e-03 -6.0000e+00 4.5374e-03 -3.0293e-03 7.6209e-05 4.4035e-04 -6.0000e+00 1.1847e-03 3.1646e-02 7.1413e-04 1.7860e-05 2.6822e-05 -6.0000e+00 2.7969e-04 -2.0581e-03 -8.8287e-05 12 1 1 12 1 1 98.90 25.76 1.57 -0.00206 0.00290 166 86 1 2 0 65.610 20.00 25.76 16.83 34.75 33.50 4.0 922.91 900000 -658 -342 -9 68 306 497 535 489 329 278 293 -10 -224 -227 -272 -268 -86 145 103 69 244 62 110 289 266 356 512 60 -434 -411 -458 -569 -111 249 33 95 130 -38 -188 -180 -80 -47 66 204 311 295 348 327 117 -269 -456 -741 -774 -493 -277 -98 -12 56 37 114 152 305 249 342 164 42 78 -19 -270 -463 -305 -262 -172 116 61 -174 -109 -207 -344 -399 -291 -301 -391 -124 -10 -58 -187 -128 -197 -167 -84 279 380 260 367 434 181 -140 -465 -663 -698 -568 -269 83 -56 -40 -78 -371 -310 -175 -59 -4 177 253 306 442 630 518 341 336 177 17 55 265 53 144 255 117 227 490 62 -61 -4 -295 -427 -82 -25 -141 107 242 113 139 276 351 387 309 11 -318 -400 -489 -462 900000 -630 -331 -9 68 309 507 554 503 340 283 298 -10 -223 -227 -271 -267 -86 148 106 72 253 65 115 298 276 368 531 62 -441 -409 -453 -569 -112 255 35 99 134 -39 -191 -183 -81 -48 68 211 320 304 359 333 118 -268 -450 -725 -753 -480 -275 -99 -12 57 38 115 154 310 254 348 165 42 78 -19 -266 -451 -298 -256 -170 115 60 -172 -107 -201 -332 -385 -282 -292 -382 -122 -10 -57 -185 -126 -194 -165 -84 278 381 262 369 433 177 -135 -448 -629 -662 -547 -261 82 -56 -40 -78 -365 -305 -173 -59 -4 178 257 309 448 641 528 345 338 178 17 54 261 53 143 254 117 225 484 61 -60 -4 -285 -410 -80 -24 -140 107 243 114 140 280 353 390 314 11 -314 -389 -479 -451
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SQ 20260416T054232.5Z 9602.237876 89 2 5.94 2 71.83 96.95 65.96 113.99 0.00 1 0.00 1 0 15 3.183e-03 3.158e-03 9.005e-05 8.998e-05 1.850742e+03 4.907753e+00 1.467174e+02 -6.000000e+00 1.649758e+02 272.34 -2.00 20.00 -2.00 505.29 0.00e+00 7.879095e-04 2.375739e-06 4.471826e-05 -6.000000e+00 8.573326e-05 272.34 -2.00 20.00 -2.00 500.66 0.00e+00 2.875467e-01 1.736053e-03 1.532924e-02 -6.000000e+00 6.220895e-02 227.72 -2.00 3.84 -2.00 502.22 0.00e+00 3.165 0.001 489.00 513.00 1 1.4575e+00 1.3236e-04 4.7600e-03 -6.0000e+00 4.7479e-03 -1.3100e-02 3.4401e-05 4.3575e-04 -6.0000e+00 1.2395e-03 2.8323e-01 5.0944e-04 8.0965e-06 2.6257e-05 -6.0000e+00 2.9267e-04 -1.5711e-03 -8.1516e-05 10 0 0 10 0 0 98.61 25.76 1.58 -0.00157 0.00196 921 96 2 2 0 6.440 20.00 25.76 16.96 34.75 33.50 4.0 923.33 900000 -701 -378 -25 51 324 567 568 525 363 310 288 -14 -256 -207 -321 -271 -58 153 89 102 231 99 124 290 250 360 492 44 -505 -421 -471 -611 -146 253 81 147 160 -20 -190 -150 -111 -65 99 219 340 296 347 308 151 -283 -487 -744 -826 -547 -293 -150 18 92 30 90 189 298 283 353 200 76 92 -16 -278 -474 -340 -268 -170 71 65 -166 -110 -200 -392 -439 -277 -328 -447 -146 -57 -97 -133 -155 -187 -173 -54 300 405 278 379 415 163 -172 -474 -646 -749 -590 -278 93 -67 -35 -62 -386 -334 -180 -113 -29 195 293 330 517 626 543 345 363 167 -3 97 305 66 166 263 127 262 444 59 -50 -9 -323 -461 -100 -7 -76 118 248 109 173 274 319 379 295 0 -355 -420 -491 -438 900000 -667 -363 -24 51 326 574 584 537 372 313 291 -14 -254 -205 -319 -269 -58 155 92 105 239 101 127 299 258 371 503 45 -506 -418 -465 -603 -146 259 83 151 164 -20 -193 -152 -113 -66 101 224 351 305 355 313 152 -282 -476 -721 -804 -534 -291 -150 18 93 31 91 192 304 287 360 202 76 91 -15 -273 -465 -332 -262 -167 71 65 -163 -108 -194 -377 -426 -268 -321 -436 -143 -56 -96 -132 -153 -186 -171 -53 299 411 280 380 415 161 -168 -457 -620 -711 -568 -270 93 -67 -36 -62 -382 -330 -179 -113 -29 196 298 338 525 639 555 351 367 168 -3 96 302 66 166 262 127 261 442 58 -49 -9 -314 -446 -97 -7 -76 118 249 110 175 277 324 386 299 0 -353 -412 -480 -431
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