File name: Pandora140s1_WashingtonDC_20201022_L2Fit_fout2c10d20200806p1-8.txt File generation date: 20260509T075407.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Jim Szykman Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 140 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora140_OF_v2d20200721.txt Instrument calibration file used: Pandora140s1_CF_v10d20200806.txt Level 1 file used: Pandora140s1_WashingtonDC_20201022_L1_smca1c10d20200806p1-8.txt Full location name: McMillan Reservoir Short location name: WashingtonDC Country of location: United States Location latitude [deg]: 38.9218 Location longitude [deg]: -77.0124 Location altitude [m]: 58 Local noon date: 20201022 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0548 305.1956 305.3364 305.4772 305.6179 305.7587 305.8994 306.0401 306.1808 306.3215 306.4622 306.6029 306.7436 306.8842 307.0249 307.1655 307.3061 307.4468 307.5874 307.7279 307.8685 308.0091 308.1496 308.2902 308.4307 308.5712 308.7118 308.8523 308.9927 309.1332 309.2737 309.4141 309.5546 309.6950 309.8354 309.9758 310.1162 310.2566 310.3970 310.5373 310.6777 310.8180 310.9584 311.0987 311.2390 311.3793 311.5196 311.6598 311.8001 311.9403 312.0806 312.2208 312.3610 312.5012 312.6414 312.7816 312.9218 313.0619 313.2021 313.3422 313.4823 313.6224 313.7625 313.9026 314.0427 314.1828 314.3228 314.4629 314.6029 314.7429 314.8829 315.0229 315.1629 315.3029 315.4428 315.5828 315.7227 315.8627 316.0026 316.1425 316.2824 316.4223 316.5621 316.7020 316.8418 316.9817 317.1215 317.2613 317.4011 317.5409 317.6807 317.8205 317.9602 318.1000 318.2397 318.3794 318.5191 318.6588 318.7985 318.9382 319.0779 319.2175 319.3572 319.4968 319.6364 319.7760 319.9156 320.0552 320.1948 320.3343 320.4739 320.6134 320.7529 320.8924 321.0319 321.1714 321.3109 321.4504 321.5898 321.7293 321.8687 322.0081 322.1476 322.2870 322.4263 322.5657 322.7051 322.8444 322.9838 323.1231 323.2624 323.4017 323.5410 323.6803 323.8196 323.9588 324.0981 324.2373 324.3765 324.5158 324.6550 324.7941 324.9333 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20201022T140331.4Z 7600.585780 1035 1 4.85 2 63.82 132.75 132.01 90.05 0.00 1 0.00 1 0 17 1.845e-02 8.808e-03 1.760e-02 5.573e-03 2.905348e-01 2.782857e-03 3.485098e-03 -6.000000e+00 1.040242e-02 225.55 -2.00 3.47 -2.00 317.19 0.00e+00 -1.417821e-03 3.971594e-04 2.144942e-04 -6.000000e+00 4.661944e-04 284.51 -2.00 20.00 -2.00 316.44 0.00e+00 2.253 0.000 302.00 328.00 3 4.4771e+00 7.3072e-03 2.6755e-02 -6.0000e+00 2.5704e-02 2.7229e-02 8.2339e-03 1.4890e-02 -6.0000e+00 2.7931e-02 3.2178e-05 4.9636e-03 7.2674e-03 -6.0000e+00 1.6686e-02 -2.0865e-03 2.4731e-03 2.3895e-03 -6.0000e+00 7.1651e-03 4.5149e-04 -2.6787e-04 1.5659e-04 2.5106e-05 -6.0000e+00 4.8945e-04 -4.2225e-03 -9.4650e-07 12 9 1 12 1 1 999.00 18.16 0.16 -0.00422 -0.00624 2 6 1 5 0 1557.990 26.62 19.99 18.16 28.22 11.8 1031.12 1611 2292 -5958 3395 -2822 -3572 -2480 775 8157 -3043 -3991 -3076 -924 -5215 329 -1823 2033 -3411 2048 -2788 -1151 30 -1957 1929 714 6170 1565 2044 -728 1992 -873 -109 4159 -1947 -156 -3123 -2367 -149 842 -1012 28 -391 -68 783 -458 1482 -716 -1006 -2489 -27 463 -1318 2031 527 1802 564 1830 423 -6854 240 544 877 2383 2482 885 1129 -1908 -786 72 537 756 1184 996 101 708 -744 -103 -2202 -775 -906 -610 14 -1861 -1584 -1169 324 -405 26 131 894 895 350 104 -728 782 -290 -358 572 309 310 313 -242 -1583 -659 -659 -566 -117 -257 -154 277 327 288 827 -130 342 -920 -369 368 -411 594 333 241 -200 -167 216 269 97 414 102 192 442 -276 -162 456 744 -361 -61 -49 -585 594 -627 -24 -346 164 254 -735 367 -289 -354 -259 88 974 -429 -567 -442 -144 -958 65 -403 456 -829 495 -726 -302 8 -526 534 211 1812 482 597 -204 535 -253 -33 1333 -682 -51 -1021 -827 -58 377 -525 15 -227 -40 465 -273 873 -423 -587 -1452 -16 276 -845 1329 363 1269 408 1333 312 -5236 173 398 672 1917 2100 763 926 -1520 -610 57 468 704 1136 960 96 639 -632 -81 -1695 -605 -769 -562 14 -1946 -1703 -1308 377 -489 32 162 1078 1030 383 108 -740 813 -324 -427 728 411 410 400 -295 -1863 -780 -823 -734 -155 -351 -217 405 497 444 1251 -191 476 -1236 -491 499 -583 873 498 359 -294 -240 301 363 127 540 139 273 650 -417 -247 708 1195 -603 -104 -83 -1014 1009 -1050 -39 -557 SU 20201022T140535.3Z 7600.587214 1037 1 26.52 2 63.53 133.21 131.62 90.36 0.00 1 0.00 1 0 17 1.971e-02 6.238e-03 1.224e-02 2.954e-03 2.844469e-01 1.468514e-03 3.404754e-03 -6.000000e+00 1.111188e-02 225.55 -2.00 3.47 -2.00 317.86 0.00e+00 1.325475e-04 2.491230e-04 1.660591e-04 -6.000000e+00 4.979749e-04 284.51 -2.00 20.00 -2.00 317.09 0.00e+00 2.230 0.000 302.00 328.00 3 4.8510e+00 3.9086e-03 2.6397e-02 -6.0000e+00 2.7457e-02 3.2524e-02 4.4332e-03 1.4462e-02 -6.0000e+00 2.9836e-02 2.6915e-03 2.7817e-03 7.1385e-03 -6.0000e+00 1.7824e-02 -4.9048e-03 1.4236e-03 2.0210e-03 -6.0000e+00 7.6538e-03 3.1802e-04 -2.9353e-04 8.4352e-05 2.2362e-05 -6.0000e+00 5.2281e-04 -3.9648e-03 1.5483e-05 12 1 1 12 1 1 97.97 18.16 0.33 -0.00396 -0.00617 11 4 1 5 0 2195.580 26.62 19.99 18.16 28.25 11.8 1031.85 -6808 7524 -567 857 -5186 -7225 2285 -10291 1081 773 4771 -7477 3693 -714 -3676 -273 1938 3120 -1143 2045 -1135 -720 -2213 258 339 -1657 331 1503 -853 -590 3386 550 1021 -1721 -1037 -2828 -3952 -1083 -1433 1053 -482 -136 -1112 -797 1228 -688 17 -686 -186 -233 353 1093 421 353 316 1120 782 970 -52 405 272 889 2222 1637 1059 -73 -445 -942 -626 925 1024 389 314 247 156 -23 -643 -606 -1816 -442 -762 -964 -1599 -1904 -850 -885 134 450 905 239 584 275 -535 -64 -327 308 225 835 566 209 -350 -724 -1427 -973 -1187 -724 -316 -356 106 649 492 704 467 266 -541 -243 -319 -266 -62 224 -111 78 363 228 304 229 94 397 368 308 146 411 -309 95 -55 217 24 207 37 34 -424 -541 -375 -553 589 -50 71 -403 -548 167 -951 100 77 454 -816 407 -94 -572 -46 334 553 -221 398 -233 -146 -465 56 78 -404 80 342 -185 -126 739 133 267 -483 -273 -732 -1120 -343 -539 451 -229 -67 -571 -413 624 -357 9 -345 -92 -115 183 602 246 216 200 719 513 636 -34 260 179 616 1640 1291 847 -56 -320 -664 -459 744 895 355 288 221 132 -18 -462 -416 -1295 -345 -659 -909 -1606 -1987 -927 -1022 160 551 1111 287 663 292 -535 -61 -329 333 264 1064 760 280 -451 -881 -1653 -1139 -1486 -944 -425 -497 153 978 777 1128 736 400 -770 -328 -429 -368 -90 340 -172 119 548 335 430 314 124 520 507 448 222 639 -489 154 -93 380 43 377 68 61 -750 -934 -634 SU 20201022T140712.6Z 7600.588341 1039 1 5.30 2 63.30 133.57 131.32 90.60 0.00 1 0.00 1 0 17 9.482e-03 5.716e-03 6.003e-03 2.148e-03 2.799284e-01 1.072088e-03 3.364726e-03 -6.000000e+00 5.346736e-03 225.55 -2.00 3.47 -2.00 316.98 0.00e+00 4.263535e-04 1.453865e-04 7.591033e-05 -6.000000e+00 2.396202e-04 284.51 -2.00 20.00 -2.00 316.24 0.00e+00 2.213 0.000 302.00 328.00 3 3.1180e+00 2.8058e-03 2.6095e-02 -6.0000e+00 1.3211e-02 1.2505e-02 3.1551e-03 1.4165e-02 -6.0000e+00 1.4356e-02 -2.0371e-03 1.8748e-03 6.9860e-03 -6.0000e+00 8.5764e-03 -1.7910e-03 9.2195e-04 1.9901e-03 -6.0000e+00 3.6827e-03 1.8636e-03 -3.5646e-04 6.0194e-05 2.2405e-05 -6.0000e+00 2.5157e-04 -3.7505e-03 1.3207e-05 12 1 1 12 1 1 88.22 18.15 0.18 -0.00375 -0.00643 13 26 1 5 0 365.700 26.62 19.99 18.15 28.32 11.9 1032.67 1094 333 -1387 188 -2616 -2710 -3737 -2287 303 -781 -535 -1944 239 -1186 -1685 -1511 753 -1021 771 1246 389 379 972 -493 -701 15 1318 -358 -54 -727 1607 581 735 -487 -2226 -2597 -2977 -795 -624 -117 -90 -52 190 -447 63 -298 -246 -192 -691 -416 676 355 1068 1190 976 540 1015 607 148 24 532 1156 1560 1893 1007 302 -602 -423 335 201 889 427 -37 -87 60 -473 -964 -1323 -1488 -617 -1090 -1406 -1579 -1323 -1155 -623 -254 -104 455 583 442 210 -134 54 326 595 530 748 453 146 -115 -742 -787 -960 -653 -669 -242 -404 -39 321 560 589 183 55 -120 -280 -206 107 -258 115 -56 75 30 294 770 407 233 456 312 476 424 120 251 -198 -32 38 5 128 -117 -225 -265 -417 -465 132 45 -196 25 -313 -308 -454 -306 44 -123 -83 -314 39 -228 -375 -374 192 -275 214 356 106 111 288 -146 -219 5 425 -111 -16 -222 510 188 259 -182 -792 -894 -1117 -338 -297 -62 -52 -32 119 -269 40 -190 -155 -118 -419 -252 428 228 723 852 727 389 744 447 107 18 388 900 1320 1628 884 247 -487 -332 274 177 817 414 -36 -82 56 -397 -772 -1004 -1170 -542 -1030 -1407 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