File name: Pandora140s1_WashingtonDC_20211213_L2Fit_fout2c10d20200806p1-8.txt File generation date: 20260509T091227.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 140 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora140_OF_v3d20200721.txt Instrument calibration file used: Pandora140s1_CF_v10d20200806.txt Level 1 file used: Pandora140s1_WashingtonDC_20211213_L1_smca1c10d20200806p1-8.txt Full location name: McMillan Reservoir Short location name: WashingtonDC Country of location: United States Location latitude [deg]: 38.9218 Location longitude [deg]: -77.0124 Location altitude [m]: 58 Local noon date: 20211213 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0548 305.1956 305.3364 305.4772 305.6179 305.7587 305.8994 306.0401 306.1808 306.3215 306.4622 306.6029 306.7436 306.8842 307.0249 307.1655 307.3061 307.4468 307.5874 307.7279 307.8685 308.0091 308.1496 308.2902 308.4307 308.5712 308.7118 308.8523 308.9927 309.1332 309.2737 309.4141 309.5546 309.6950 309.8354 309.9758 310.1162 310.2566 310.3970 310.5373 310.6777 310.8180 310.9584 311.0987 311.2390 311.3793 311.5196 311.6598 311.8001 311.9403 312.0806 312.2208 312.3610 312.5012 312.6414 312.7816 312.9218 313.0619 313.2021 313.3422 313.4823 313.6224 313.7625 313.9026 314.0427 314.1828 314.3228 314.4629 314.6029 314.7429 314.8829 315.0229 315.1629 315.3029 315.4428 315.5828 315.7227 315.8627 316.0026 316.1425 316.2824 316.4223 316.5621 316.7020 316.8418 316.9817 317.1215 317.2613 317.4011 317.5409 317.6807 317.8205 317.9602 318.1000 318.2397 318.3794 318.5191 318.6588 318.7985 318.9382 319.0779 319.2175 319.3572 319.4968 319.6364 319.7760 319.9156 320.0552 320.1948 320.3343 320.4739 320.6134 320.7529 320.8924 321.0319 321.1714 321.3109 321.4504 321.5898 321.7293 321.8687 322.0081 322.1476 322.2870 322.4263 322.5657 322.7051 322.8444 322.9838 323.1231 323.2624 323.4017 323.5410 323.6803 323.8196 323.9588 324.0981 324.2373 324.3765 324.5158 324.6550 324.7941 324.9333 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211213T125200.0Z 8017.536111 123 1 50.62 2 85.30 125.03 136.98 357.65 0.00 1 0.00 1 0 33 6.058e-01 8.319e-02 4.642e-01 6.091e-02 9.931612e-01 3.689672e-02 1.132628e-02 -6.000000e+00 3.520871e-01 223.18 -2.00 3.47 -2.00 321.79 0.00e+00 4.625335e-03 1.154112e-02 3.558370e-03 -6.000000e+00 1.791044e-02 278.79 -2.00 20.00 -2.00 321.18 0.00e+00 10.285 0.019 302.00 328.00 3 -2.9350e-01 1.1189e-01 1.1571e-01 -6.0000e+00 8.7190e-01 2.4687e+00 1.3098e-01 5.6890e-02 -6.0000e+00 9.5813e-01 -2.3863e+00 8.2471e-02 2.6343e-02 -6.0000e+00 5.6224e-01 8.2435e-01 4.7100e-02 8.0844e-03 -6.0000e+00 2.3904e-01 6.6793e-06 -5.1240e-03 1.6093e-03 1.1766e-04 -6.0000e+00 1.7258e-02 2.8414e-03 -9.0081e-05 12 8 8 10 0 0 55.93 18.36 1.20 0.00284 -0.03566 29 5 1 5 0 1745.020 26.51 20.00 18.36 10.00 20.8 1014.55 201121 218113 900000 140995 900000 23725 17285 85309 100854 5638 900000 -26369 -38125 85840 3383 130888 -18046 900000 89873 900000 50365 31252 900000 -44536 900000 -16327 900000 16460 57847 150096 900000 125995 36772 900000 -69829 900000 -65727 900000 4956 55732 185079 17641 900000 5006 900000 9123 -18152 24061 53872 127235 9661 172407 -919 900000 -33384 900000 46066 900000 92731 -23927 -7975 6728 80487 -30702 123811 -13934 900000 4018 116061 108753 31835 108351 -10626 55665 -21848 165183 -28395 25553 59117 -2165 13388 6005 37330 -14756 67301 4973 20106 17082 27620 21637 26800 12923 -43758 31337 -22252 23767 -4880 6812 8111 -8547 22365 -22401 13989 -8590 17680 -5172 12161 11881 -2309 -646 -1797 7111 -2611 12967 1543 8069 -1524 -8736 3949 -9901 6830 -6871 12134 -3760 1856 -3367 -1860 7226 -7395 2826 -7341 4877 -3955 5759 -1520 -791 214 -930 5734 -2609 2315 -4734 4174 11902 12908 900000 8344 900000 2808 1961 5049 5969 612 900000 -3641 -6957 5503 584 7746 -4539 900000 7535 900000 5216 3391 900000 -9225 900000 -2335 900000 1505 3423 8883 900000 7456 3759 900000 -17563 900000 -13614 900000 667 5097 10953 2562 900000 781 900000 1227 -3125 2718 4637 7530 1455 10203 -178 900000 -9699 900000 5948 900000 6486 -4892 -1330 1014 6495 -8589 7993 -3523 900000 865 8742 9947 6851 11076 -3430 8385 -6230 9776 -6722 3574 6679 -547 3457 1938 9841 -6907 14483 2087 7464 6617 9510 7566 8219 4241 -24719 8767 -12211 9846 -3203 4691 6240 -8001 14559 -20367 7677 -5546 9227 -3589 7459 7926 -1988 -636 -2088 8455 -3595 15348 1992 9421 -1960 -12596 5291 -15766 9002 -9759 13513 -4754 2147 -4004 -2122 7814 -10822 4440 -14653 9577 -9170 13044 -3998 -2195 602 -2666 15393 -7270 5654 -11386 8579 SS 20211213T130303.7Z 8017.543793 126 1 50.40 2 83.56 126.89 136.95 1.53 0.00 1 0.00 1 0 25 5.427e-01 2.564e-02 3.211e-01 1.228e-02 8.374253e-01 6.808394e-03 9.148026e-03 -6.000000e+00 3.049144e-01 223.18 -2.00 3.47 -2.00 322.19 0.00e+00 1.332379e-02 3.755766e-03 5.405139e-03 -6.000000e+00 1.349258e-02 278.79 -2.00 20.00 -2.00 321.74 0.00e+00 8.074 0.009 302.00 328.00 3 3.1968e-01 2.5798e-02 1.0133e-01 -6.0000e+00 7.5175e-01 1.0350e+00 3.2750e-02 7.7624e-02 -6.0000e+00 8.2050e-01 -1.3899e+00 2.7517e-02 2.4509e-02 -6.0000e+00 4.8933e-01 5.6782e-01 1.3330e-02 1.5322e-02 -6.0000e+00 2.1041e-01 5.6023e-05 -2.0902e-03 3.3625e-04 1.3771e-04 -6.0000e+00 1.4519e-02 2.7510e-04 -2.7641e-05 12 8 8 10 0 0 7.47 18.36 0.40 0.00028 -0.01543 108 20 1 5 0 466.550 26.51 20.00 18.36 10.76 20.8 1021.09 900000 -28903 -73927 116099 -124080 -49603 -132183 142117 30923 56983 24011 -100364 21654 -92478 148233 -60538 900000 7560 393584 34029 40823 -32693 -7362 19507 -78189 17304 -23334 2349 -30190 -168 15459 -35801 53937 22781 41681 -36801 162164 44895 46242 8728 26399 56366 -21059 95690 15663 104241 39453 30363 18796 44846 79691 23957 84302 18434 41528 48211 64030 9267 900000 27164 11257 34659 -2633 39659 14593 38490 24435 28955 11736 11496 20875 -3116 13404 3582 28445 1676 4518 190 877 -311 -7410 3843 -7795 5551 598 4613 2085 3602 643 772 5639 -8570 2257 -6586 -1192 -5445 -908 -3196 -1257 -776 -3226 -318 -6124 -613 -3785 -360 -2659 -3288 -316 -3794 525 -1168 1357 -1104 -1336 -1292 -2297 -937 -372 1513 662 3268 95 3896 1221 2675 2766 -790 1450 -477 1977 591 979 -519 757 307 158 507 -828 719 -1459 -41 -2348 900000 -753 -3071 1390 -6024 -1048 -5957 1701 370 682 287 -3180 275 -4558 1774 -3282 900000 245 4711 917 977 -1404 -248 496 -4845 427 -838 61 -1062 -5 463 -2042 1533 937 1310 -2203 1941 1444 1695 535 1481 2446 -1928 2935 1066 3161 2184 1908 1392 2718 3756 2058 4541 1934 3597 4184 4742 1083 900000 2561 1189 3173 -402 4580 2343 4824 3510 4118 2157 2428 4424 -821 3096 845 4687 319 776 35 184 -80 -2326 1252 -3178 2097 252 1982 961 1682 310 360 2336 -3841 886 -2956 -581 -3306 -627 -2661 -1153 -723 -2920 -251 -4549 -418 -2859 -279 -2237 -3031 -316 -4524 653 -1619 1893 -1562 -1824 -1796 -3255 -1376 -546 2400 1046 4786 137 5289 1644 3460 3476 -1075 2235 -873 3984 1250 2202 -1265 1963 846 445 1443 -2391 1954 -3763 -101 -5672 SS 20211213T131340.5Z 8017.551163 129 1 50.35 2 81.93 128.72 136.80 5.24 0.00 1 0.00 1 0 17 5.293e-01 1.462e-02 1.796e-01 4.306e-03 7.432308e-01 2.363286e-03 8.230323e-03 -6.000000e+00 2.955594e-01 223.18 -2.00 3.47 -2.00 321.89 0.00e+00 6.217136e-03 1.284613e-03 1.040358e-03 -6.000000e+00 1.306017e-02 278.79 -2.00 20.00 -2.00 321.42 0.00e+00 6.672 0.005 302.00 328.00 3 3.5603e-01 8.7284e-03 7.6872e-02 -6.0000e+00 7.2786e-01 3.5377e-01 1.2118e-02 4.1114e-02 -6.0000e+00 7.9322e-01 -5.1755e-01 1.2212e-02 2.2051e-02 -6.0000e+00 4.7307e-01 2.1540e-01 5.7046e-03 9.0588e-03 -6.0000e+00 2.0294e-01 2.4981e-04 -1.4327e-03 1.2307e-04 1.1954e-04 -6.0000e+00 1.4034e-02 -6.9602e-04 -1.4205e-05 12 8 8 10 0 0 16.42 18.36 0.20 -0.00070 -0.01146 261 49 1 5 0 192.870 26.51 19.99 18.36 11.39 20.7 1024.81 -215332 -177676 -195221 -173837 -102388 -193471 85315 -155118 -44362 -157866 -174148 -100588 -156141 -47411 -74092 -27357 -67067 83442 -42540 -10378 -66553 -65267 22271 -40447 72953 -49123 13879 -43829 16552 -37035 -40095 15130 -16192 55798 9383 55512 -3992 10959 -9045 1488 27972 12408 28052 9544 35477 4744 29463 10718 23616 15336 9985 20001 8372 22939 6012 20243 11356 10920 55241 7142 11170 9693 16369 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