File name: Pandora140s1_WashingtonDC_20220123_L2Fit_fout2c14d20220101p1-8.txt File generation date: 20241218T134344.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 140 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora140_OF_v3d20200721.txt Instrument calibration file used: Pandora140s1_CF_v14d20220101.txt Level 1 file used: Pandora140s1_WashingtonDC_20220123_L1_smca1c14d20220101p1-8.txt Full location name: McMillan Reservoir Short location name: WashingtonDC Country of location: United States Location latitude [deg]: 38.9218 Location longitude [deg]: -77.0124 Location altitude [m]: 58 Local noon date: 20220123 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 10 "Based on session 8 "Modif only on SO2 (WashingtonDC)""" First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0439 305.1847 305.3255 305.4663 305.6071 305.7478 305.8885 306.0293 306.1700 306.3107 306.4514 306.5921 306.7328 306.8734 307.0141 307.1547 307.2954 307.4360 307.5766 307.7172 307.8578 307.9983 308.1389 308.2794 308.4200 308.5605 308.7010 308.8415 308.9820 309.1225 309.2630 309.4034 309.5439 309.6843 309.8247 309.9652 310.1056 310.2459 310.3863 310.5267 310.6670 310.8074 310.9477 311.0881 311.2284 311.3687 311.5089 311.6492 311.7895 311.9297 312.0700 312.2102 312.3504 312.4906 312.6308 312.7710 312.9112 313.0514 313.1915 313.3316 313.4718 313.6119 313.7520 313.8921 314.0322 314.1722 314.3123 314.4523 314.5924 314.7324 314.8724 315.0124 315.1524 315.2924 315.4324 315.5723 315.7123 315.8522 315.9921 316.1320 316.2719 316.4118 316.5517 316.6915 316.8314 316.9712 317.1111 317.2509 317.3907 317.5305 317.6703 317.8100 317.9498 318.0895 318.2293 318.3690 318.5087 318.6484 318.7881 318.9278 319.0675 319.2071 319.3468 319.4864 319.6260 319.7656 319.9052 320.0448 320.1844 320.3239 320.4635 320.6030 320.7426 320.8821 321.0216 321.1611 321.3006 321.4400 321.5795 321.7189 321.8584 321.9978 322.1372 322.2766 322.4160 322.5554 322.6947 322.8341 322.9734 323.1128 323.2521 323.3914 323.5307 323.6700 323.8093 323.9485 324.0878 324.2270 324.3662 324.5054 324.6446 324.7838 324.9230 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220123T125322.0Z 8058.537060 274 1 50.85 2 85.26 119.66 60.62 242.64 0.00 1 0.00 1 0 25 6.694e-01 9.143e-02 5.539e-01 9.139e-02 1.167861e+00 5.462891e-02 1.404271e-02 -6.000000e+00 3.900903e-01 224.20 -2.00 3.47 -2.00 321.65 0.00e+00 -4.895602e-02 1.320825e-02 6.806052e-03 -6.000000e+00 1.868018e-02 276.69 -2.00 20.00 -2.00 320.87 0.00e+00 10.221 0.019 302.00 328.00 3 2.9700e-01 1.6492e-01 1.4261e-01 -6.0000e+00 9.7031e-01 2.4884e+00 1.9717e-01 1.4439e-01 -6.0000e+00 1.0660e+00 -2.7650e+00 1.1192e-01 3.0052e-02 -6.0000e+00 6.2616e-01 9.7374e-01 6.5929e-02 3.8688e-02 -6.0000e+00 2.6466e-01 4.5709e-06 3.4313e-03 2.2451e-03 5.1333e-04 -6.0000e+00 1.9847e-02 9.2836e-03 0.0000e+00 12 8 8 10 0 0 44.09 18.41 1.67 0.00928 0.03507 23 4 1 5 0 2210.680 26.51 19.99 18.41 5.82 20.9 1027.84 59123 72246 900000 900000 900000 -44359 -25299 11481 -15343 -32236 103794 45085 61666 2629 251721 -28820 900000 83853 -39425 26150 14196 900000 -11806 900000 32032 900000 21951 143391 900000 -67433 107305 -12258 900000 -10461 900000 900000 33092 81303 -9070 97336 15249 900000 -22814 900000 -36094 -9213 -25394 -28166 -11266 -56677 125285 95031 87982 -16988 900000 32180 -326 59111 73200 900000 -48564 266762 166774 177617 221641 900000 900000 11968 36486 43965 265600 -22180 66426 35335 -22831 -26042 -55383 -2816 -29649 207925 -41204 4573 6706 12922 366 -2598 46493 -3949 -16001 -20920 7762 27851 43451 39479 31183 3843 -12321 6541 -9691 20147 -14637 7378 25729 11732 -27089 1040 -8685 -3604 -499 -7921 10039 -660 8057 6457 -7198 1970 -3165 1014 -5508 3954 -5636 13699 8756 -5376 1556 -7887 23861 -8196 8319 -2818 3420 3084 -2070 81 -1281 617 -4823 5023 -475 5810 -7898 4393 -358 9189 8556 900000 900000 900000 -7880 -4494 1784 -3747 -10259 9219 6340 6846 486 22357 -6826 900000 7448 -8171 2745 1490 900000 -1716 900000 4655 900000 3190 12736 900000 -11978 9531 -1386 900000 -1182 900000 900000 2939 7221 -1391 8645 2462 900000 -4789 900000 -6120 -1041 -3076 -3411 -1183 -10068 11127 8440 7814 -3018 900000 4157 -60 5727 6501 900000 -9019 23693 14812 15775 19686 900000 900000 1739 4714 6035 23590 -6447 8260 4850 -4793 -4836 -12968 -450 -6464 18467 -14306 1181 1895 3652 124 -944 11562 -1467 -6460 -8277 2344 6679 9262 9818 9970 1738 -7660 3908 -7434 11387 -10873 3872 10969 5210 -19029 579 -5680 -2473 -382 -7803 9727 -794 9368 7716 -9648 2354 -4037 1294 -7827 5140 -7645 14269 9191 -6337 1671 -9107 21829 -10390 10815 -4869 6380 6425 -4965 207 -3630 1804 -15069 14316 -1399 14917 -21108 9470 -775 SS 20220123T130441.3Z 8058.544922 277 1 6.20 2 83.36 121.54 62.59 244.85 0.00 1 0.00 1 0 17 6.333e-01 4.203e-02 5.027e-01 3.510e-02 1.024683e+00 2.039347e-02 1.135115e-02 -6.000000e+00 3.684613e-01 224.20 -2.00 3.47 -2.00 322.22 0.00e+00 8.781205e-03 9.818420e-03 6.044717e-03 -6.000000e+00 1.614458e-02 276.69 -2.00 20.00 -2.00 321.78 0.00e+00 7.875 0.008 302.00 328.00 3 9.5314e-01 7.4186e-02 1.0351e-01 -6.0000e+00 9.1770e-01 1.5807e+00 9.0592e-02 7.8649e-02 -6.0000e+00 1.0096e+00 -1.9318e+00 6.5507e-02 2.9453e-02 -6.0000e+00 5.9270e-01 7.4951e-01 3.3579e-02 1.2195e-02 -6.0000e+00 2.5090e-01 2.5081e-05 -2.7238e-03 8.9794e-04 1.3053e-04 -6.0000e+00 1.7287e-02 1.0034e-02 0.0000e+00 12 9 9 12 1 1 66.64 18.41 0.50 0.01003 -0.01043 4 8 1 5 0 1203.680 26.51 20.00 18.41 7.30 20.6 1037.40 159525 -65728 900000 -30711 -54853 -132476 153447 3482 -99095 -73031 -1783 -21850 -54861 72236 900000 -31519 2927 214908 900000 -4533 94457 13638 -40061 112199 -3537 -24138 353605 19217 -84333 900000 29961 900000 51406 900000 900000 900000 -6807 -30966 56776 20304 -5370 -6167 900000 139428 173555 900000 63212 84400 -11116 900000 900000 248363 900000 65603 78128 105924 58007 -30275 -2478 -12072 27025 66574 73521 40261 89077 7215 -5507 78097 5382 11402 25429 35704 6716 5272 5056 25996 -3629 -16675 40711 -15698 8107 1844 21512 23210 16459 5863 7186 15146 -833 -16236 -4409 -13168 -7147 6943 -553 -4455 3794 -972 87 -5156 3726 -2852 -6994 694 -10903 -5671 -1733 -8340 -2673 621 -1812 2079 -306 -958 -136 -4866 -1713 -2304 -2368 300 2771 1889 1372 6875 6637 3701 2508 6226 -3454 985 218 2323 -163 20 -964 1698 2123 -32 -2088 -814 1490 -26 -4163 5446 -4388 900000 -1294 -2356 -10065 5239 119 -4853 -2707 -61 -746 -2188 2466 900000 -1869 137 7337 900000 -233 3225 494 -2273 3830 -139 -1118 12072 656 -5719 900000 1023 900000 1761 900000 900000 900000 -360 -2243 2057 1185 -432 -518 900000 4760 5925 900000 2699 3054 -1040 900000 900000 8479 900000 4477 4945 5222 4470 -5097 -300 -1500 2306 4212 4972 4279 6557 1141 -991 6788 996 2264 4852 6359 1516 1108 946 3521 -603 -3250 5350 -4229 2090 585 6329 7109 5634 2324 2906 5804 -368 -7984 -1818 -5570 -2839 2572 -253 -2530 2367 -744 74 -4729 3000 -2201 -4930 435 -8017 -4192 -1302 -7221 -2462 642 -2217 2716 -428 -1355 -187 -6791 -2343 -3304 -3566 454 4000 2599 1809 8403 7910 4439 2980 7491 -5268 1684 423 4859 -374 50 -2527 4565 5772 -88 -5902 -2182 3641 -59 -9379 SS 20220123T131452.2Z 8058.551993 280 1 50.36 2 81.69 123.28 64.38 246.78 0.00 1 0.00 1 0 25 5.337e-01 1.719e-02 2.386e-01 5.979e-03 8.804173e-01 3.307418e-03 9.470548e-03 -6.000000e+00 2.992155e-01 224.20 -2.00 3.47 -2.00 322.07 0.00e+00 6.242530e-03 1.842686e-03 2.231133e-03 -6.000000e+00 1.311368e-02 276.69 -2.00 20.00 -2.00 321.63 0.00e+00 6.502 0.005 302.00 328.00 3 8.0544e-01 1.2416e-02 8.1481e-02 -6.0000e+00 7.3904e-01 6.3497e-01 1.7830e-02 5.4524e-02 -6.0000e+00 8.0535e-01 -8.6664e-01 1.8339e-02 2.6675e-02 -6.0000e+00 4.7931e-01 3.5287e-01 8.4742e-03 1.0306e-02 -6.0000e+00 2.0630e-01 1.5105e-04 -1.6774e-03 1.5839e-04 1.2662e-04 -6.0000e+00 1.4248e-02 8.8717e-03 0.0000e+00 12 8 8 10 0 0 98.56 18.41 0.29 0.00887 -0.00373 152 29 1 5 0 331.240 26.51 20.00 18.41 7.89 20.7 1041.82 900000 -228905 -84242 -101156 -120443 -180391 -219391 -187496 -193266 -9340 -188747 -40437 -126717 -63198 -69211 -75154 5042 -81977 26175 -54152 32229 -73568 5852 -57584 -17711 -25932 -61887 3179 -85033 60152 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