File name: Pandora140s1_WashingtonDC_20220331_L2Fit_fwvt1c14d20220101p1-8.txt File generation date: 20241218T161745.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 140 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora140_OF_v3d20200721.txt Instrument calibration file used: Pandora140s1_CF_v14d20220101.txt Level 1 file used: Pandora140s1_WashingtonDC_20220331_L1_smca1c14d20220101p1-8.txt Full location name: McMillan Reservoir Short location name: WashingtonDC Country of location: United States Location latitude [deg]: 38.9218 Location longitude [deg]: -77.0124 Location altitude [m]: 58 Local noon date: 20220331 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 10 "Based on session 8 "Modif only on SO2 (WashingtonDC)""" First and last pixel inside fitting window: 1637 1786 Nominal wavelengths inside fitting window [nm]: 492.0699 492.1908 492.3117 492.4326 492.5535 492.6743 492.7952 492.9160 493.0368 493.1576 493.2784 493.3991 493.5199 493.6406 493.7613 493.8820 494.0027 494.1233 494.2440 494.3646 494.4852 494.6058 494.7264 494.8469 494.9675 495.0880 495.2085 495.3290 495.4495 495.5699 495.6904 495.8108 495.9312 496.0516 496.1720 496.2923 496.4127 496.5330 496.6533 496.7736 496.8939 497.0141 497.1344 497.2546 497.3748 497.4950 497.6152 497.7353 497.8555 497.9756 498.0957 498.2158 498.3359 498.4559 498.5759 498.6960 498.8160 498.9360 499.0559 499.1759 499.2958 499.4157 499.5356 499.6555 499.7754 499.8953 500.0151 500.1349 500.2547 500.3745 500.4943 500.6140 500.7338 500.8535 500.9732 501.0929 501.2125 501.3322 501.4518 501.5714 501.6910 501.8106 501.9302 502.0497 502.1693 502.2888 502.4083 502.5278 502.6472 502.7667 502.8861 503.0055 503.1249 503.2443 503.3637 503.4830 503.6023 503.7216 503.8409 503.9602 504.0795 504.1987 504.3180 504.4372 504.5564 504.6755 504.7947 504.9138 505.0330 505.1521 505.2712 505.3902 505.5093 505.6283 505.7474 505.8664 505.9854 506.1043 506.2233 506.3422 506.4611 506.5801 506.6989 506.8178 506.9367 507.0555 507.1743 507.2931 507.4119 507.5307 507.6494 507.7682 507.8869 508.0056 508.1243 508.2429 508.3616 508.4802 508.5988 508.7174 508.8360 508.9546 509.0731 509.1916 509.3102 509.4287 509.5471 509.6656 509.7840 509.9025 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20220331T141340.0Z 8125.592824 153 1 18.72 2 53.20 118.95 55.45 130.13 0.00 1 0.00 1 0 15 3.065e-03 3.029e-03 7.492e-04 7.481e-04 2.647410e+03 4.413582e+01 1.934427e+02 -6.000000e+00 1.668962e+02 279.90 -2.00 20.00 -2.00 505.27 0.00e+00 5.869720e-04 2.041285e-05 3.428455e-05 -6.000000e+00 8.507436e-05 279.90 -2.00 20.00 -2.00 500.49 0.00e+00 7.284258e-02 1.472787e-02 2.005915e-02 -6.000000e+00 6.080774e-02 227.62 -2.00 3.47 -2.00 502.08 0.00e+00 1.665 0.000 489.00 513.00 1 6.4709e+00 1.1267e-03 3.0311e-03 -6.0000e+00 4.6495e-03 -2.4091e-03 2.9325e-04 4.9151e-04 -6.0000e+00 1.2183e-03 2.3549e-03 1.0770e-03 7.1303e-05 2.7763e-05 -6.0000e+00 3.0158e-04 3.5696e-03 -5.5039e-05 12 1 1 12 1 1 99.99 18.58 0.92 0.00357 0.01104 18 10 1 4 0 975.830 26.73 20.01 18.58 25.17 23.3 1031.67 -842 -536 -253 65 239 365 511 438 446 424 96 89 -177 -195 -505 -329 -106 14 343 138 127 -44 162 176 178 322 222 200 -158 -224 -310 -395 -207 215 355 308 260 174 -228 -243 -178 -175 -16 68 258 468 289 209 29 -221 -528 -629 -754 -606 -149 37 121 269 281 122 227 233 145 250 148 46 -80 -82 -222 -247 -259 -258 -226 -9 143 121 -82 -317 -400 -473 -456 -321 -393 -190 -232 -49 -184 -83 -183 -1 77 227 402 336 256 206 110 -191 -340 -541 -723 -588 -368 26 -31 10 -67 -212 -289 -291 -72 -6 251 313 309 368 575 386 239 315 76 -17 60 324 183 390 408 570 210 331 393 -64 -126 -352 -340 -135 14 68 6 190 115 135 222 195 44 50 -161 -375 -381 -815 -805 -519 -253 64 242 378 537 464 471 443 99 91 -177 -193 -499 -327 -106 14 361 142 131 -45 166 182 185 333 228 212 -163 -224 -306 -391 -209 224 365 319 267 177 -239 -252 -185 -184 -16 70 266 483 297 212 30 -224 -521 -606 -720 -584 -147 38 125 270 282 123 228 235 147 253 148 48 -81 -82 -220 -241 -251 -251 -223 -9 143 120 -81 -306 -383 -452 -438 -311 -384 -187 -230 -49 -185 -84 -184 -1 75 224 402 337 254 201 110 -185 -322 -505 -675 -558 -359 25 -31 10 -66 -207 -280 -283 -70 -6 253 318 317 379 594 400 246 319 76 -17 58 317 180 384 402 559 206 324 382 -62 -119 -343 -331 -128 13 67 6 192 117 138 219 194 43 49 -162 -368 -367 -786 SQ 20220331T142057.4Z 8125.597887 159 1 49.82 2 51.96 120.63 54.37 131.87 0.00 1 0.00 1 0 15 3.104e-03 3.084e-03 8.567e-04 8.548e-04 3.231416e+03 5.157014e+01 2.444261e+02 -6.000000e+00 1.690598e+02 279.90 -2.00 20.00 -2.00 505.27 0.00e+00 6.102165e-04 2.333305e-05 3.507572e-05 -6.000000e+00 8.617705e-05 279.90 -2.00 20.00 -2.00 500.40 0.00e+00 7.333131e-02 1.694850e-02 2.210630e-02 -6.000000e+00 6.159205e-02 227.62 -2.00 3.47 -2.00 502.01 0.00e+00 1.619 0.000 489.00 513.00 1 7.4614e+00 1.2986e-03 3.1047e-03 -6.0000e+00 4.7096e-03 1.3894e-03 3.3605e-04 5.6577e-04 -6.0000e+00 1.2339e-03 8.7888e-04 7.7228e-04 8.1277e-05 3.3042e-05 -6.0000e+00 3.0548e-04 1.9078e-03 -3.8554e-05 10 0 0 10 0 0 99.98 18.58 0.84 0.00191 0.00726 30 6 1 4 0 1660.190 26.73 20.00 18.58 25.46 23.3 1033.22 -661 -535 -244 64 118 519 416 614 554 262 43 -206 -183 -323 -137 -477 -109 112 310 342 112 273 13 198 75 426 403 50 -193 -258 -343 -501 -36 84 376 63 304 37 -332 -168 -238 -169 -84 81 154 261 271 456 -28 -400 -472 -707 -763 -706 -96 36 341 360 -36 153 266 194 99 363 36 157 143 -120 -138 -140 -161 -253 -197 114 78 178 -224 -202 -434 -297 -559 -410 -313 -248 -145 -133 -54 -2 20 24 -1 213 330 389 478 263 400 -161 -383 -577 -684 -578 -378 -9 88 -100 34 -382 -395 -147 -93 -166 80 267 247 458 356 505 252 236 181 146 -38 184 243 111 619 155 100 144 289 -67 -120 -232 -522 -90 -102 -82 91 189 204 267 234 188 279 174 -174 -314 -470 -619 -648 -532 -237 64 122 543 443 659 593 277 45 -213 -185 -324 -137 -481 -111 116 330 368 121 296 14 204 78 440 414 53 -202 -261 -342 -503 -36 88 386 66 312 38 -352 -177 -250 -178 -85 83 159 270 278 461 -29 -410 -470 -688 -737 -688 -95 37 338 360 -37 153 266 195 100 365 36 155 146 -121 -138 -138 -157 -249 -195 114 79 179 -221 -197 -419 -285 -541 -400 -307 -245 -145 -127 -52 -1 19 23 -1 209 328 387 469 254 377 -156 -364 -540 -639 -549 -370 -9 87 -99 33 -370 -380 -141 -90 -165 80 270 251 467 365 518 257 237 179 143 -37 179 237 108 603 151 98 140 278 -64 -113 -216 -485 -84 -98 -81 90 188 205 270 237 191 285 176 -173 -306 -449 -590 SQ 20220331T160739.4Z 8125.671984 236 1 23.45 2 37.57 152.97 42.95 163.54 0.00 1 0.00 1 0 15 3.366e-03 3.338e-03 1.224e-03 1.221e-03 3.169672e+03 7.337232e+01 2.280714e+02 -6.000000e+00 1.832932e+02 279.90 -2.00 20.00 -2.00 505.25 0.00e+00 4.960908e-04 3.310441e-05 3.117700e-05 -6.000000e+00 9.343138e-05 279.90 -2.00 20.00 -2.00 500.39 0.00e+00 2.225564e-02 2.412738e-02 2.341801e-02 -6.000000e+00 6.677178e-02 227.63 -2.00 3.47 -2.00 501.99 0.00e+00 1.261 0.000 489.00 513.00 1 7.5678e+00 1.8433e-03 2.7766e-03 -6.0000e+00 5.1057e-03 4.8932e-03 4.8096e-04 5.6615e-04 -6.0000e+00 1.3375e-03 8.3607e-04 8.1923e-04 1.1598e-04 3.1138e-05 -6.0000e+00 3.3118e-04 5.7756e-04 -2.4319e-05 12 1 1 12 1 1 99.80 18.57 0.94 0.00058 0.00626 6 3 1 4 0 3324.430 26.73 20.01 18.57 26.94 23.6 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