File name: Pandora140s1_WashingtonDC_20220819_L2Fit_fout2c14d20220101p1-8.txt File generation date: 20241218T174927.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 140 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora140_OF_v3d20200721.txt Instrument calibration file used: Pandora140s1_CF_v14d20220101.txt Level 1 file used: Pandora140s1_WashingtonDC_20220819_L1_smca1c14d20220101p1-8.txt Full location name: McMillan Reservoir Short location name: WashingtonDC Country of location: United States Location latitude [deg]: 38.9218 Location longitude [deg]: -77.0124 Location altitude [m]: 58 Local noon date: 20220819 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 10 "Based on session 8 "Modif only on SO2 (WashingtonDC)""" First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0439 305.1847 305.3255 305.4663 305.6071 305.7478 305.8885 306.0293 306.1700 306.3107 306.4514 306.5921 306.7328 306.8734 307.0141 307.1547 307.2954 307.4360 307.5766 307.7172 307.8578 307.9983 308.1389 308.2794 308.4200 308.5605 308.7010 308.8415 308.9820 309.1225 309.2630 309.4034 309.5439 309.6843 309.8247 309.9652 310.1056 310.2459 310.3863 310.5267 310.6670 310.8074 310.9477 311.0881 311.2284 311.3687 311.5089 311.6492 311.7895 311.9297 312.0700 312.2102 312.3504 312.4906 312.6308 312.7710 312.9112 313.0514 313.1915 313.3316 313.4718 313.6119 313.7520 313.8921 314.0322 314.1722 314.3123 314.4523 314.5924 314.7324 314.8724 315.0124 315.1524 315.2924 315.4324 315.5723 315.7123 315.8522 315.9921 316.1320 316.2719 316.4118 316.5517 316.6915 316.8314 316.9712 317.1111 317.2509 317.3907 317.5305 317.6703 317.8100 317.9498 318.0895 318.2293 318.3690 318.5087 318.6484 318.7881 318.9278 319.0675 319.2071 319.3468 319.4864 319.6260 319.7656 319.9052 320.0448 320.1844 320.3239 320.4635 320.6030 320.7426 320.8821 321.0216 321.1611 321.3006 321.4400 321.5795 321.7189 321.8584 321.9978 322.1372 322.2766 322.4160 322.5554 322.6947 322.8341 322.9734 323.1128 323.2521 323.3914 323.5307 323.6700 323.8093 323.9485 324.0878 324.2270 324.3662 324.5054 324.6446 324.7838 324.9230 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220819T110639.3Z 8266.462955 219 1 50.49 2 83.04 79.29 18.07 181.27 0.00 1 0.00 1 0 25 4.966e-01 2.929e-02 4.359e-01 2.270e-02 8.916164e-01 1.282733e-02 1.015349e-02 -6.000000e+00 2.863107e-01 231.37 -2.00 3.47 -2.00 322.21 0.00e+00 -1.272369e-02 7.252424e-03 4.531649e-03 -6.000000e+00 1.311510e-02 290.88 -2.00 20.00 -2.00 321.66 0.00e+00 7.549 0.007 302.00 328.00 3 1.5963e+00 5.2678e-02 9.0502e-02 -6.0000e+00 7.1573e-01 1.0390e+00 6.9659e-02 5.2407e-02 -6.0000e+00 7.7352e-01 -1.4806e+00 4.9879e-02 2.8730e-02 -6.0000e+00 4.6196e-01 5.9652e-01 2.3050e-02 9.7734e-03 -6.0000e+00 1.9774e-01 2.5487e-05 -1.6199e-03 6.1431e-04 1.7041e-04 -6.0000e+00 1.3391e-02 3.2637e-03 0.0000e+00 12 8 8 10 0 0 44.32 18.47 0.44 0.00326 -0.00891 46 9 1 5 0 1097.290 26.62 20.00 18.47 30.30 26.3 1006.99 -40397 5569 -88564 900000 -17897 -71397 -50753 -61714 25302 -106807 -116237 -77687 4675 -54991 -16885 173461 -40826 52162 44709 83529 -42078 -1875 -16302 900000 39727 -58617 10809 133067 -62353 -73358 -17380 -60348 69319 213585 7124 45530 -21836 35178 141836 112278 37321 38970 24801 45572 77028 11755 140301 31017 155031 9499 41710 31499 59048 48994 144162 49649 49071 41884 5183 25806 15102 -663 41056 31221 44938 26890 25229 28598 23127 10244 32438 18840 19998 18235 14931 12207 35101 11739 -16320 -6192 -8736 -10336 1467 -1658 5353 2427 -104 -506 -1358 -439 959 3676 2794 81 -7789 -1211 -1810 2213 -5440 -1907 -4135 -1678 -2359 -941 -1691 -6960 -2148 -3968 -3202 -2922 -1398 -1585 -131 823 -716 -2039 870 -859 -1832 854 -1036 3078 3228 4752 2586 3311 1128 800 36 553 1165 2450 -413 -30 727 356 779 -189 -191 -12 -1873 -1530 -754 -1117 123 -4083 900000 -396 -1843 -1225 -1707 560 -5514 -6644 -3151 103 -2332 -611 3838 -2033 1154 1079 1848 -2095 -64 -656 900000 1119 -4215 413 2944 -3564 -4599 -769 -4340 1673 4726 315 1282 -1274 1344 3138 2936 2327 2508 1846 2658 3099 875 3104 1872 3430 783 2769 2598 4038 4041 4930 4594 4738 4297 659 2699 1701 -84 4212 3684 5424 3520 3349 3849 3625 2115 5981 4169 4314 3732 2836 2093 4801 1883 -3882 -1598 -2754 -3869 549 -685 2201 1097 -51 -253 -684 -211 425 1491 1123 35 -4165 -717 -1268 1742 -4787 -1659 -3498 -1359 -1714 -656 -1276 -5891 -1830 -3731 -3324 -3213 -1745 -2188 -186 1151 -985 -2741 1140 -1198 -2731 1292 -1578 4642 4667 6571 3533 4377 1481 1095 57 942 2232 5087 -947 -74 1912 1000 2229 -554 -560 -33 -4943 -3728 -1868 SS 20220819T111724.8Z 8266.470426 222 1 50.45 2 80.98 80.93 18.23 189.18 0.00 1 0.00 1 0 25 5.206e-01 1.567e-02 1.926e-01 5.877e-03 7.517625e-01 3.273554e-03 8.434813e-03 -6.000000e+00 3.001879e-01 231.37 -2.00 3.47 -2.00 321.88 0.00e+00 2.351389e-03 1.913181e-03 2.363608e-03 -6.000000e+00 1.351857e-02 290.88 -2.00 20.00 -2.00 321.32 0.00e+00 6.037 0.004 302.00 328.00 3 1.3579e+00 1.3210e-02 7.2928e-02 -6.0000e+00 7.5043e-01 3.3686e-01 1.8364e-02 4.2832e-02 -6.0000e+00 8.1090e-01 -5.8865e-01 1.6283e-02 2.2110e-02 -6.0000e+00 4.8404e-01 2.4980e-01 7.4524e-03 6.5170e-03 -6.0000e+00 2.0674e-01 1.6562e-04 -1.0369e-03 1.6364e-04 9.6389e-05 -6.0000e+00 1.3833e-02 2.6556e-03 0.0000e+00 12 9 8 11 8 0 6.54 18.47 0.32 0.00266 -0.00514 147 28 1 5 0 343.140 26.73 20.00 18.47 31.18 26.2 1012.71 -197488 -162719 -179646 -68921 -173109 -129622 -229093 -129904 -182183 -84527 -148001 -180751 -27240 -96868 -64668 -73578 22518 -52028 -18945 -35889 -38250 -25180 -78019 -2467 -51669 28841 -43459 -36075 10056 -14772 37835 -467 18148 -8964 56863 5989 4695 5295 29239 9230 5244 14285 27301 34944 10750 26430 4012 32474 35871 15315 19315 13952 21610 6385 21504 19579 16113 12565 11221 5548 2451 11662 8590 13973 11827 12960 7911 6554 5243 4385 6052 5459 5876 3866 4837 706 3297 -2348 -3914 -813 -2336 2412 -640 -206 158 768 -383 -90 1076 -340 755 -2429 -281 -2760 -2768 -2413 -1053 -1190 -1794 -1364 -1526 -1195 -2499 -2216 -2343 -1805 -1745 -1688 -986 -712 663 518 595 209 152 -248 -1047 -221 -326 898 59 1225 971 1415 1126 898 842 518 991 280 1033 718 210 -266 -113 -142 -260 485 53 -68 -326 -299 -1342 -3872 -2662 -3665 -476 -2875 -1359 -6395 -1582 -4001 -793 -2607 -4734 -209 -1818 -1117 -1643 229 -1164 -334 -771 -849 -485 -2510 -43 -1499 414 -1240 -926 162 -319 595 -12 472 -325 1078 176 150 194 1035 466 309 828 1467 1787 688 1491 283 1825 2050 1124 1514 1287 2030 749 2339 2256 1977 1593 1393 706 326 1543 1324 2327 2157 2318 1476 1283 1132 1098 1664 1584 1691 1076 1224 167 709 -539 -1012 -243 -836 951 -288 -98 80 414 -219 -53 632 -197 406 -1269 -140 -1443 -1621 -1641 -823 -1077 -1810 -1396 -1490 -1063 -2033 -1768 -2010 -1636 -1667 -1731 -1102 -893 924 780 916 318 222 -350 -1491 -326 -509 1453 96 1897 1455 2055 1583 1230 1120 711 1528 493 2000 1504 465 -627 -285 -379 -710 1338 146 -183 -829 -716 -3119 SS 20220819T112816.2Z 8266.477965 227 1 50.34 2 78.89 82.59 18.67 196.92 0.00 1 0.00 1 0 25 4.315e-01 9.177e-03 7.749e-02 2.308e-03 6.497959e-01 1.252310e-03 7.333998e-03 -6.000000e+00 2.487805e-01 231.37 -2.00 3.47 -2.00 321.37 0.00e+00 9.483892e-04 6.379028e-04 1.454148e-03 -6.000000e+00 1.120298e-02 290.88 -2.00 20.00 -2.00 320.74 0.00e+00 5.002 0.002 302.00 328.00 3 1.0566e+00 4.5580e-03 6.0806e-02 -6.0000e+00 6.2192e-01 7.3835e-02 6.2324e-03 3.5801e-02 -6.0000e+00 6.7203e-01 -1.7360e-01 5.7985e-03 1.8072e-02 -6.0000e+00 4.0114e-01 6.9463e-02 2.7470e-03 5.1356e-03 -6.0000e+00 1.7134e-01 6.6575e-04 -7.7374e-04 6.4910e-05 6.8416e-05 -6.0000e+00 1.1464e-02 2.3356e-03 0.0000e+00 11 8 0 10 0 0 25.78 18.48 0.21 0.00234 -0.00348 336 64 1 5 0 149.770 26.73 20.00 18.48 32.26 26.5 1020.17 -145520 -135089 -147040 -70280 -183174 -123951 -181329 -94839 -139374 -92564 -108849 -121443 -89203 -95855 -50650 -81047 -42524 -54797 -5664 -32093 -38702 -11077 -49339 -15264 -37937 -2868 -24837 883 -29977 -16768 -14484 -16872 -897 -9845 -930 -20184 2851 -8512 1631 3573 2004 13984 1024 7777 -3093 11486 2798 8830 4357 2079 5050 3366 8874 3601 9464 3720 6207 5211 -2770 3905 1325 5473 1727 6776 1417 5724 -256 1803 1393 2589 4214 2267 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