File name: Pandora140s1_WashingtonDC_20221021_L2Fit_fout2c14d20220101p1-8.txt File generation date: 20241218T184938.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 140 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora140_OF_v3d20200721.txt Instrument calibration file used: Pandora140s1_CF_v14d20220101.txt Level 1 file used: Pandora140s1_WashingtonDC_20221021_L1_smca1c14d20220101p1-8.txt Full location name: McMillan Reservoir Short location name: WashingtonDC Country of location: United States Location latitude [deg]: 38.9218 Location longitude [deg]: -77.0124 Location altitude [m]: 58 Local noon date: 20221021 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 10 "Based on session 8 "Modif only on SO2 (WashingtonDC)""" First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0439 305.1847 305.3255 305.4663 305.6071 305.7478 305.8885 306.0293 306.1700 306.3107 306.4514 306.5921 306.7328 306.8734 307.0141 307.1547 307.2954 307.4360 307.5766 307.7172 307.8578 307.9983 308.1389 308.2794 308.4200 308.5605 308.7010 308.8415 308.9820 309.1225 309.2630 309.4034 309.5439 309.6843 309.8247 309.9652 310.1056 310.2459 310.3863 310.5267 310.6670 310.8074 310.9477 311.0881 311.2284 311.3687 311.5089 311.6492 311.7895 311.9297 312.0700 312.2102 312.3504 312.4906 312.6308 312.7710 312.9112 313.0514 313.1915 313.3316 313.4718 313.6119 313.7520 313.8921 314.0322 314.1722 314.3123 314.4523 314.5924 314.7324 314.8724 315.0124 315.1524 315.2924 315.4324 315.5723 315.7123 315.8522 315.9921 316.1320 316.2719 316.4118 316.5517 316.6915 316.8314 316.9712 317.1111 317.2509 317.3907 317.5305 317.6703 317.8100 317.9498 318.0895 318.2293 318.3690 318.5087 318.6484 318.7881 318.9278 319.0675 319.2071 319.3468 319.4864 319.6260 319.7656 319.9052 320.0448 320.1844 320.3239 320.4635 320.6030 320.7426 320.8821 321.0216 321.1611 321.3006 321.4400 321.5795 321.7189 321.8584 321.9978 322.1372 322.2766 322.4160 322.5554 322.6947 322.8341 322.9734 323.1128 323.2521 323.3914 323.5307 323.6700 323.8093 323.9485 324.0878 324.2270 324.3662 324.5054 324.6446 324.7838 324.9230 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221021T115503.1Z 8329.496563 179 1 49.72 2 84.97 108.22 39.43 124.84 0.00 1 0.00 1 0 25 6.568e-01 7.500e-02 5.822e-01 6.956e-02 9.807557e-01 4.221531e-02 1.202592e-02 -6.000000e+00 3.914655e-01 225.73 -2.00 3.47 -2.00 322.16 0.00e+00 -3.103810e-02 1.527955e-02 7.458091e-04 -6.000000e+00 1.874859e-02 284.76 -2.00 20.00 -2.00 321.57 0.00e+00 9.765 0.016 302.00 328.00 3 8.2636e-01 1.4309e-01 1.1389e-01 -6.0000e+00 9.7431e-01 1.6835e+00 1.7393e-01 7.7556e-02 -6.0000e+00 1.0704e+00 -2.0997e+00 1.0507e-01 2.5346e-02 -6.0000e+00 6.3121e-01 8.3118e-01 5.7781e-02 2.8539e-02 -6.0000e+00 2.6658e-01 5.5975e-06 -4.2365e-03 1.9212e-03 3.9619e-04 -6.0000e+00 1.8625e-02 5.7012e-03 0.0000e+00 12 8 8 10 0 0 34.55 18.37 1.37 0.00570 -0.02613 20 4 1 5 0 2485.060 26.51 20.00 18.37 13.61 25.4 998.36 27815 58323 209198 29875 -48085 -66846 21422 900000 900000 -50727 203304 -99700 900000 5485 210214 900000 -26253 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900000 -2444 14429 900000 -5358 2630 3422 6009 -2439 900000 10007 900000 16100 2558 7908 7673 4782 -5146 5761 900000 900000 5752 8194 4205 900000 900000 -6015 871 -11205 6390 13014 48 5536 3694 6405 -277 2037 2759 5625 -1071 -4302 5039 6472 6566 2690 12342 4684 5702 8078 -3275 2829 -8478 -2224 -3772 471 -7054 -6924 -11845 7202 3044 -3555 17702 -18939 -15411 -8473 2644 1841 9872 1056 3412 6859 -3282 2602 -11249 11883 -5929 1350 7347 -7168 -4924 -2870 5294 419 9308 -507 15728 -4876 6187 -428 -110 -9951 2911 2628 159 -15154 2077 9994 8702 1451 1889 3048 -2882 -6851 -6281 SS 20221021T120628.2Z 8329.504493 182 1 50.35 2 82.87 110.09 37.71 128.26 0.00 1 0.00 1 0 25 5.025e-01 2.574e-02 3.891e-01 1.127e-02 8.596112e-01 6.361981e-03 9.720793e-03 -6.000000e+00 2.855446e-01 225.73 -2.00 3.47 -2.00 322.17 0.00e+00 -2.197979e-02 3.734186e-03 1.774309e-03 -6.000000e+00 1.282677e-02 284.76 -2.00 20.00 -2.00 321.67 0.00e+00 7.410 0.007 302.00 328.00 3 9.4306e-01 2.6142e-02 9.1356e-02 -6.0000e+00 7.0724e-01 5.8490e-01 3.7543e-02 6.7964e-02 -6.0000e+00 7.7024e-01 -9.0964e-01 3.4972e-02 2.6084e-02 -6.0000e+00 4.5979e-01 3.7012e-01 1.5794e-02 2.1115e-02 -6.0000e+00 1.9737e-01 6.5890e-05 -1.1695e-03 3.1228e-04 2.5941e-04 -6.0000e+00 1.3424e-02 5.5431e-03 0.0000e+00 12 9 8 11 8 0 -28.18 18.37 0.28 0.00554 -0.00324 96 18 1 5 0 524.420 26.51 20.00 18.37 14.22 25.5 1004.27 900000 -107324 -97868 -149128 -219940 -54009 155467 -152742 -71014 -169403 -88703 -88675 52505 -56443 39957 900000 -115461 -12059 900000 3227 33714 31746 80053 -32467 46327 125769 -49448 -7976 40815 27555 -42378 147382 129676 8612 1106 43237 11757 19558 995 54955 48479 64948 71425 74979 34730 22522 14498 19778 14359 54116 12609 47135 38990 16036 48000 31653 19613 42898 -69258 37514 26667 28999 19044 29539 20420 23707 16527 11593 17543 17646 13754 16899 20902 7923 5732 5493 -2426 9633 -768 -2324 -2462 5746 -2728 -405 1945 292 3417 6246 2405 3549 2713 682 705 -3206 -1549 -2896 -1057 -1786 -3015 -2970 -3448 -4463 -3564 -4236 -2448 -1295 -2682 -1090 -1027 -59 696 1098 537 -107 -1011 218 215 -473 -829 404 719 465 1974 1297 2628 905 1679 1403 -233 -854 -318 410 -471 -211 -639 271 1101 949 619 311 -565 -874 -2209 900000 -1273 -1075 -2444 -6119 -593 1707 -3164 -823 -5637 -1488 -1596 577 -959 439 900000 -4634 -195 900000 48 373 354 879 -862 690 1381 -1980 -199 569 426 -1403 1618 1424 248 33 839 334 615 46 1935 2079 2560 2686 2648 1684 1185 806 1062 846 2381 904 2793 2740 1526 3733 3067 2242 3998 -17120 3262 2483 2778 2224 3538 2844 3184 2388 1850 2931 3404 3069 3852 4569 1845 1242 1065 -471 1698 -165 -599 -749 1878 -1082 -169 846 138 1635 2988 1191 1680 1214 296 302 -1497 -806 -1779 -740 -1455 -2754 -2761 -3066 -3654 -2606 -3065 -1872 -1040 -2302 -993 -1035 -67 898 1545 788 -157 -1447 297 294 -679 -1258 630 1103 684 2757 1778 3451 1180 2114 1838 -356 -1506 -624 873 -1078 -515 -1686 751 3096 2712 1773 857 -1468 -2130 -5211 SS 20221021T121709.5Z 8329.511915 185 1 50.31 2 80.93 111.88 36.18 131.69 0.00 1 0.00 1 0 25 5.117e-01 1.114e-02 1.744e-01 3.701e-03 7.246621e-01 1.997538e-03 8.124122e-03 -6.000000e+00 2.888173e-01 225.73 -2.00 3.47 -2.00 321.68 0.00e+00 5.742552e-03 1.102748e-03 2.006366e-03 -6.000000e+00 1.294538e-02 284.76 -2.00 20.00 -2.00 321.16 0.00e+00 6.015 0.004 302.00 328.00 3 7.0641e-01 7.4903e-03 7.0846e-02 -6.0000e+00 7.1388e-01 2.5291e-01 1.0642e-02 3.9532e-02 -6.0000e+00 7.7555e-01 -3.6502e-01 1.0533e-02 2.2714e-02 -6.0000e+00 4.6331e-01 1.4783e-01 4.8796e-03 9.2030e-03 -6.0000e+00 1.9899e-01 3.2830e-04 -9.6587e-04 1.0168e-04 1.2068e-04 -6.0000e+00 1.3577e-02 4.2678e-03 0.0000e+00 12 8 8 10 0 0 0.08 18.37 0.24 0.00427 -0.00299 244 46 1 5 0 206.150 26.51 20.00 18.37 15.36 25.5 1012.94 -183303 -192473 -18521 -179232 78789 -220184 -160577 -194567 -162373 -109351 -155961 -72481 -116324 -32558 -84394 -59794 -83956 -59895 6063 -43304 66876 -66028 -41996 -76619 -16581 -38331 -30391 -41303 -36172 41630 -24796 16503 -16685 4200 -6563 173 -15022 9183 6933 7114 28072 1837 15825 7525 13134 4671 15962 10475 15252 17910 10698 12210 7705 12199 6637 8928 7306 8069 3437 -3750 9007 1561 7597 5427 9491 5242 3014 3619 3922 6712 2811 6099 475 2276 428 556 -2607 -4670 -555 -2561 -264 -1574 7 -2348 -1735 -460 -180 988 590 1639 -49 -399 -2086 -2045 -1363 -1143 -146 -195 -4 -656 -284 -1300 -1936 -2728 -1451 -1060 -829 -249 -882 197 74 846 460 219 -261 -80 -144 -245 116 2 863 263 652 198 845 995 348 497 -45 630 215 397 -390 -81 -114 -131 235 93 46 -22 -222 -326 -573 -2165 -2968 -67 -2587 284 -4118 -1739 -3256 -2184 -933 -2200 -549 -1603 -282 -1440 -981 -2011 -1258 72 -881 507 -1690 -868 -2413 -305 -918 -688 -1016 -831 526 -675 363 -602 135 -226 5 -591 331 312 353 1283 118 933 498 834 332 1042 753 1105 1357 975 1238 899 1490 914 1249 1070 1170 504 -577 1252 237 1246 1046 1894 1080 630 779 920 1774 862 1902 156 691 121 140 -628 -1162 -149 -842 -101 -703 3 -1249 -979 -274 -112 630 380 1012 -29 -220 -1127 -1135 -844 -828 -123 -191 -4 -726 -296 -1238 -1663 -2318 -1309 -1012 -832 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