File name: Pandora140s1_WashingtonDC_20221224_L2Fit_fout2c14d20220101p1-8.txt File generation date: 20241218T195221.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 140 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora140_OF_v3d20200721.txt Instrument calibration file used: Pandora140s1_CF_v14d20220101.txt Level 1 file used: Pandora140s1_WashingtonDC_20221224_L1_smca1c14d20220101p1-8.txt Full location name: McMillan Reservoir Short location name: WashingtonDC Country of location: United States Location latitude [deg]: 38.9218 Location longitude [deg]: -77.0124 Location altitude [m]: 58 Local noon date: 20221224 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 10 "Based on session 8 "Modif only on SO2 (WashingtonDC)""" First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0439 305.1847 305.3255 305.4663 305.6071 305.7478 305.8885 306.0293 306.1700 306.3107 306.4514 306.5921 306.7328 306.8734 307.0141 307.1547 307.2954 307.4360 307.5766 307.7172 307.8578 307.9983 308.1389 308.2794 308.4200 308.5605 308.7010 308.8415 308.9820 309.1225 309.2630 309.4034 309.5439 309.6843 309.8247 309.9652 310.1056 310.2459 310.3863 310.5267 310.6670 310.8074 310.9477 311.0881 311.2284 311.3687 311.5089 311.6492 311.7895 311.9297 312.0700 312.2102 312.3504 312.4906 312.6308 312.7710 312.9112 313.0514 313.1915 313.3316 313.4718 313.6119 313.7520 313.8921 314.0322 314.1722 314.3123 314.4523 314.5924 314.7324 314.8724 315.0124 315.1524 315.2924 315.4324 315.5723 315.7123 315.8522 315.9921 316.1320 316.2719 316.4118 316.5517 316.6915 316.8314 316.9712 317.1111 317.2509 317.3907 317.5305 317.6703 317.8100 317.9498 318.0895 318.2293 318.3690 318.5087 318.6484 318.7881 318.9278 319.0675 319.2071 319.3468 319.4864 319.6260 319.7656 319.9052 320.0448 320.1844 320.3239 320.4635 320.6030 320.7426 320.8821 321.0216 321.1611 321.3006 321.4400 321.5795 321.7189 321.8584 321.9978 322.1372 322.2766 322.4160 322.5554 322.6947 322.8341 322.9734 323.1128 323.2521 323.3914 323.5307 323.6700 323.8093 323.9485 324.0878 324.2270 324.3662 324.5054 324.6446 324.7838 324.9230 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221224T125824.9Z 8393.540566 62 1 50.83 2 85.29 125.38 100.41 116.97 0.00 1 0.00 1 0 25 6.559e-01 1.133e-01 5.589e-01 1.049e-01 1.170990e+00 6.213668e-02 1.278309e-02 -6.000000e+00 3.725085e-01 223.36 -2.00 3.47 -2.00 321.12 0.00e+00 -6.963063e-03 1.276794e-02 1.480382e-03 -6.000000e+00 1.768016e-02 278.03 -2.00 20.00 -2.00 320.45 0.00e+00 10.264 0.019 302.00 328.00 3 -2.0748e-01 1.7816e-01 1.1632e-01 -6.0000e+00 9.2130e-01 3.2886e+00 2.0545e-01 5.3505e-02 -6.0000e+00 1.0056e+00 -2.5568e+00 1.1459e-01 2.6837e-02 -6.0000e+00 5.9419e-01 6.5166e-01 6.4338e-02 8.4057e-03 -6.0000e+00 2.5505e-01 3.6921e-06 1.9894e-03 2.4593e-03 1.0979e-04 -6.0000e+00 1.8244e-02 5.4730e-03 0.0000e+00 12 8 8 10 0 0 83.78 18.35 1.28 0.00547 0.02042 16 3 1 5 0 3176.410 26.41 20.00 18.35 -6.40 23.6 994.43 81490 151073 31997 -15437 76897 53134 900000 -13426 900000 -39960 50776 900000 257561 98223 900000 99716 27431 -3136 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490 12027 900000 8304 3930 5918 -19415 6743 8392 900000 -4342 19241 9651 9734 9892 8767 5958 7965 10240 -19142 835 1618 1319 17471 5686 10512 -16395 11843 9452 12747 900000 12977 4137 3327 -3435 9680 -1207 -28359 82 13065 15047 12751 -5501 900000 8048 11098 13152 8354 12146 5219 13974 11272 4500 -18352 17815 9460 1689 21077 13241 4521 -22213 -7937 -2534 -5669 9831 9996 8318 -6299 3988 -10815 -16214 -1259 7143 7252 -4459 -2481 8184 5439 -21346 1220 6587 11593 -10729 -10049 -8008 14749 5581 10018 -6353 3746 -5387 5670 7201 -14699 -1041 -8588 9503 9937 2321 7568 -16560 6354 SS 20221224T130931.3Z 8393.548279 65 1 50.55 2 83.55 127.25 98.58 118.49 0.00 1 0.00 1 0 25 6.759e-01 5.708e-02 3.911e-01 2.229e-02 1.245225e+00 1.333593e-02 1.900372e-02 -6.000000e+00 3.864212e-01 223.36 -2.00 3.47 -2.00 322.59 0.00e+00 -8.588400e-02 6.361729e-03 1.587991e-02 -6.000000e+00 1.731808e-02 278.03 -2.00 20.00 -2.00 322.13 0.00e+00 8.060 0.009 302.00 328.00 3 7.9221e-01 5.2503e-02 2.1053e-01 -6.0000e+00 9.5000e-01 1.8528e+00 6.4679e-02 2.9557e-01 -6.0000e+00 1.0357e+00 -2.3825e+00 4.6681e-02 4.8827e-02 -6.0000e+00 6.1498e-01 8.4708e-01 2.4393e-02 7.0614e-02 -6.0000e+00 2.6487e-01 2.6012e-05 -5.8085e-06 5.4725e-04 8.2957e-04 -6.0000e+00 1.8254e-02 4.4027e-03 0.0000e+00 12 8 8 10 0 0 11.86 18.35 0.39 0.00440 0.00436 69 13 1 5 0 732.480 26.41 20.00 18.35 -5.92 23.7 1000.14 900000 17121 6150 -20169 -100063 900000 900000 167719 88675 95539 112040 177187 107036 36996 138869 166624 88346 60229 30082 900000 28724 -20991 -72501 58 287392 126942 120799 176388 107904 -2364 9955 7904 -7698 100405 82728 8435 10610 73048 75552 70026 124843 107004 81045 108703 50412 60659 900000 20699 38368 170019 74070 83607 74971 65575 78133 193080 97355 124557 -107293 24616 46122 31423 16592 40237 50653 54578 60980 29516 44209 63596 52010 46357 70031 45796 67168 38027 10347 31140 2069 10466 17873 14301 22024 18880 23124 20818 27165 26066 4578 11496 9649 -1079 9065 15676 11503 5595 3373 -6858 -4524 -11308 -8771 -7098 -3431 -2175 339 -3000 -4195 -2474 -2061 -2068 -1534 2006 768 5473 2327 3767 2563 -3132 -1291 -2134 882 333 2618 994 2080 58 -302 1259 -1769 -2417 -1485 -488 -2289 -140 -258 306 433 1118 1427 -165 228 -1409 -36 900000 682 223 -730 -6338 900000 900000 3643 3210 4323 4867 4198 3874 2143 3016 3619 2442 2022 1247 900000 1021 -1102 -8004 5 6242 6015 5724 3831 2770 -140 491 406 -486 2181 1960 400 545 2596 3729 4977 6162 6549 5760 4722 3086 2755 900000 1144 1818 3693 3071 3632 3997 4402 5399 5451 7304 7132 -46066 2673 3369 2544 1671 3575 4300 4418 4816 3555 5324 7408 6966 6880 8711 6051 6763 4355 1430 3566 322 1762 3332 3313 5461 5262 6612 6405 8014 7737 1624 3558 2812 -340 2691 4880 4393 2663 1898 -4560 -3258 -8822 -6286 -4471 -1987 -1208 197 -1906 -2847 -1666 -1580 -1893 -1669 2407 1006 7049 3059 4745 3258 -4343 -1825 -3076 1177 414 3023 1139 2303 64 -329 1447 -2518 -4164 -2946 -1079 -5678 -374 -758 952 1369 3527 4419 -483 603 -3428 -82 SS 20221224T132009.0Z 8393.555660 68 1 50.00 2 81.92 129.08 96.85 119.96 0.00 1 0.00 1 0 25 4.775e-01 1.953e-02 3.025e-01 7.554e-03 1.090422e+00 4.407270e-03 1.213709e-02 -6.000000e+00 2.669723e-01 223.36 -2.00 3.47 -2.00 322.50 0.00e+00 -3.024450e-03 2.630462e-03 9.567923e-03 -6.000000e+00 1.174260e-02 278.03 -2.00 20.00 -2.00 322.10 0.00e+00 6.665 0.005 302.00 328.00 3 6.5748e-01 1.7888e-02 1.0198e-01 -6.0000e+00 6.5792e-01 1.1658e+00 2.4861e-02 8.7667e-02 -6.0000e+00 7.1679e-01 -1.6737e+00 2.3307e-02 4.2998e-02 -6.0000e+00 4.2725e-01 6.8007e-01 1.0805e-02 1.1675e-02 -6.0000e+00 1.8326e-01 1.1667e-04 -2.1375e-03 1.9229e-04 2.4838e-04 -6.0000e+00 1.2657e-02 4.4577e-03 0.0000e+00 12 8 8 10 0 0 5.97 18.35 0.29 0.00446 -0.01160 169 32 1 5 0 295.820 26.41 20.01 18.35 -5.45 23.4 1002.78 13605 -129856 114085 -67587 152522 -126794 -115605 -83880 -175183 -13986 -147037 27636 -133975 -49118 -2907 9216 64173 12349 80122 -73493 45207 -43554 -6302 -61953 84613 -5274 -50863 33694 -64170 15024 -75645 96744 -11312 65191 81558 63446 27852 7837 46809 2879 76641 29783 102347 78565 47568 31631 18129 30492 -9445 65216 9198 67411 49186 27664 50995 42576 56396 24595 112346 15489 34978 16442 35931 26692 25186 18487 12784 23851 14856 29466 15523 21069 19404 14939 19643 -1346 6868 -7773 -843 -1437 6330 1020 4136 6110 499 5016 -1251 3651 288 5876 80 2505 -4959 -647 -4942 -4543 -1956 -3306 -2257 -2864 -1585 -2432 -3666 -3131 -3734 -2273 -2533 -1770 -3096 -1290 -1115 -64 57 -16 131 56 -403 -1539 -477 -319 1186 1733 1074 2291 1234 2709 928 1204 704 1081 978 942 379 56 71 -378 210 -366 254 356 -153 -717 -1969 100 -4000 840 -996 1124 -2462 -2013 -1123 -6218 -113 -4136 204 -4486 -888 -41 136 662 207 767 -2904 566 -1108 -110 -2033 748 -106 -1567 447 -1891 232 -3242 998 -364 1153 1142 981 636 226 1207 125 1976 1177 2186 2083 1497 1144 753 1164 -576 2258 573 2663 2569 1964 3074 2908 3437 2009 3890 1182 2132 1288 2671 2556 2715 1986 1491 2665 2015 3998 2687 3583 3264 2403 2653 -195 929 -1169 -138 -292 1445 291 1300 2014 184 1866 -514 1455 118 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