File name: Pandora140s1_WashingtonDC_20230128_L2Fit_fout2c14d20220101p1-8.txt File generation date: 20241218T195450.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 140 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora140_OF_v3d20200721.txt Instrument calibration file used: Pandora140s1_CF_v14d20220101.txt Level 1 file used: Pandora140s1_WashingtonDC_20230128_L1_smca1c14d20220101p1-8.txt Full location name: McMillan Reservoir Short location name: WashingtonDC Country of location: United States Location latitude [deg]: 38.9218 Location longitude [deg]: -77.0124 Location altitude [m]: 58 Local noon date: 20230128 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 10 "Based on session 8 "Modif only on SO2 (WashingtonDC)""" First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0439 305.1847 305.3255 305.4663 305.6071 305.7478 305.8885 306.0293 306.1700 306.3107 306.4514 306.5921 306.7328 306.8734 307.0141 307.1547 307.2954 307.4360 307.5766 307.7172 307.8578 307.9983 308.1389 308.2794 308.4200 308.5605 308.7010 308.8415 308.9820 309.1225 309.2630 309.4034 309.5439 309.6843 309.8247 309.9652 310.1056 310.2459 310.3863 310.5267 310.6670 310.8074 310.9477 311.0881 311.2284 311.3687 311.5089 311.6492 311.7895 311.9297 312.0700 312.2102 312.3504 312.4906 312.6308 312.7710 312.9112 313.0514 313.1915 313.3316 313.4718 313.6119 313.7520 313.8921 314.0322 314.1722 314.3123 314.4523 314.5924 314.7324 314.8724 315.0124 315.1524 315.2924 315.4324 315.5723 315.7123 315.8522 315.9921 316.1320 316.2719 316.4118 316.5517 316.6915 316.8314 316.9712 317.1111 317.2509 317.3907 317.5305 317.6703 317.8100 317.9498 318.0895 318.2293 318.3690 318.5087 318.6484 318.7881 318.9278 319.0675 319.2071 319.3468 319.4864 319.6260 319.7656 319.9052 320.0448 320.1844 320.3239 320.4635 320.6030 320.7426 320.8821 321.0216 321.1611 321.3006 321.4400 321.5795 321.7189 321.8584 321.9978 322.1372 322.2766 322.4160 322.5554 322.6947 322.8341 322.9734 323.1128 323.2521 323.3914 323.5307 323.6700 323.8093 323.9485 324.0878 324.2270 324.3662 324.5054 324.6446 324.7838 324.9230 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230128T125003.1Z 8428.534758 56 1 50.79 2 85.17 118.08 121.91 32.40 0.00 1 0.00 1 0 25 5.709e-01 7.379e-02 4.585e-01 6.957e-02 1.010796e+00 4.006177e-02 1.168452e-02 -6.000000e+00 3.258241e-01 224.37 -2.00 3.47 -2.00 321.40 0.00e+00 5.920012e-03 1.023256e-02 1.270216e-03 -6.000000e+00 1.487513e-02 276.67 -2.00 20.00 -2.00 320.82 0.00e+00 10.092 0.018 302.00 328.00 3 -1.2661e-01 1.1878e-01 1.1196e-01 -6.0000e+00 8.0058e-01 2.4868e+00 1.3581e-01 4.8609e-02 -6.0000e+00 8.7030e-01 -2.4474e+00 7.6266e-02 2.4446e-02 -6.0000e+00 5.2195e-01 8.5084e-01 4.4818e-02 8.1012e-03 -6.0000e+00 2.2481e-01 7.0703e-06 -1.5344e-03 1.7180e-03 1.2221e-04 -6.0000e+00 1.5420e-02 7.4202e-03 0.0000e+00 12 9 8 11 8 0 47.83 18.36 1.03 0.00742 -0.00411 28 5 1 5 0 1813.780 26.41 20.00 18.36 10.07 26.1 1022.24 140323 227244 150573 71262 -20646 76070 -21635 -21569 15198 46079 -23901 -12536 877 63402 -31965 44305 76921 16790 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900000 749 -9476 5174 1716 10226 3462 7769 1086 -4628 -2464 2682 3975 26 -2294 9837 8489 6811 8943 4594 9177 8313 10976 11996 6261 2947 -1078 -212 -10708 -3700 2429 -13344 3612 3616 946 2296 5159 5190 7295 2430 3420 3307 -5880 2274 -10871 -12368 5195 -7589 5501 9875 -6633 -661 14671 6344 -938 -22576 6981 -7196 353 -2145 4234 3205 -10673 -3024 -6348 4032 8830 4415 13619 6170 232 -9820 -2257 -11474 9539 2024 4107 -2335 9210 2421 -8297 6243 4555 1308 -4470 3255 733 -7098 -2852 -234 5002 -1747 -10617 -4140 9877 8712 SS 20230128T130054.4Z 8428.542296 59 1 50.23 2 83.33 119.88 120.75 35.04 0.00 1 0.00 1 0 25 3.456e-01 2.180e-02 2.618e-01 1.250e-02 9.375076e-01 7.047933e-03 1.008100e-02 -6.000000e+00 1.939185e-01 224.37 -2.00 3.47 -2.00 322.33 0.00e+00 3.965479e-03 3.885007e-03 2.926098e-03 -6.000000e+00 8.452062e-03 276.67 -2.00 20.00 -2.00 321.90 0.00e+00 7.840 0.008 302.00 328.00 3 3.8826e-01 2.6940e-02 9.4340e-02 -6.0000e+00 4.7918e-01 1.1441e+00 3.4078e-02 5.7056e-02 -6.0000e+00 5.2186e-01 -1.5899e+00 2.8501e-02 2.7205e-02 -6.0000e+00 3.1057e-01 6.5123e-01 1.3925e-02 9.2023e-03 -6.0000e+00 1.3272e-01 6.0232e-05 -1.4682e-03 3.3322e-04 1.2649e-04 -6.0000e+00 9.1635e-03 6.1949e-03 0.0000e+00 12 8 8 10 0 0 44.59 18.36 0.32 0.00619 -0.00484 114 22 1 5 0 440.510 26.41 20.00 18.36 10.93 26.1 1028.53 -99907 30064 -13535 -10764 -80822 -55520 -121338 -93189 -4228 -97786 -83938 -54506 -42745 -30589 -67632 -12841 8385 37419 -19613 -15327 26096 -66290 -14847 -30077 -51157 28936 -30941 -26490 4404 -65250 20944 24325 13411 18210 -50906 12640 17005 13673 104908 56907 25270 74645 48801 59779 42692 35557 72573 48548 30812 42418 79405 37611 65875 51577 32271 27066 34183 35180 14435 35353 23528 25353 21862 41426 23303 21637 19374 19606 23157 16576 23522 10838 21853 15342 16530 13827 -5332 3900 -14278 2052 -2279 2593 5468 -5295 3112 -3995 1621 -500 3903 2284 -2863 -2659 -5751 -4081 -3538 -5887 -4543 -2988 -1731 -222 -1286 -2321 -2265 -4761 -3924 -4079 -1762 -1667 -1029 -80 -1552 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2.112e-01 4.239e-03 8.165055e-01 2.329329e-03 8.810365e-03 -6.000000e+00 3.150727e-01 224.37 -2.00 3.47 -2.00 321.95 0.00e+00 6.017878e-03 1.269525e-03 1.460393e-03 -6.000000e+00 1.365865e-02 276.67 -2.00 20.00 -2.00 321.50 0.00e+00 6.414 0.005 302.00 328.00 3 3.7023e-01 8.5841e-03 7.7872e-02 -6.0000e+00 7.7973e-01 4.3429e-01 1.2530e-02 4.8661e-02 -6.0000e+00 8.4966e-01 -6.1201e-01 1.3280e-02 2.4959e-02 -6.0000e+00 5.0357e-01 2.5053e-01 6.1388e-03 1.0174e-02 -6.0000e+00 2.1439e-01 2.8334e-04 -1.1642e-03 1.1575e-04 1.2313e-04 -6.0000e+00 1.5003e-02 6.0398e-03 0.0000e+00 12 8 8 10 0 0 50.32 18.36 0.28 0.00604 -0.00271 271 51 1 5 0 182.620 26.41 20.00 18.36 11.58 26.0 1033.11 -161372 -86644 -137038 -118142 -199485 -162351 -256524 900000 -227640 -40541 -211391 -124200 122189 -139876 -26564 -107920 8194 -103207 22346 -63816 -19388 -11350 -71219 86057 -87816 22344 -62951 10646 -37771 9383 -14224 -33142 20008 -15444 55226 -22785 22832 -14378 41486 16497 27125 26466 1482 44083 -2161 41960 6216 30704 11681 21825 20671 21677 28322 10786 27105 6633 19991 12866 11711 12261 13485 15170 4103 15694 5551 14682 2353 10681 6705 6867 7181 3757 9177 866 6255 -3520 1002 -3037 -2958 -1956 -767 839 -2988 853 -2625 680 -572 1057 2016 4 1220 -2010 -448 -5366 -1078 -1615 -296 -462 -752 -421 -1631 -631 -2895 -1225 -2720 -940 -1536 -1177 -408 -1039 543 -423 604 -249 -66 -489 -244 -321 -263 584 14 1305 532 1239 1415 1188 739 48 753 403 706 184 248 -154 -104 65 144 37 -119 318 -470 -191 -1174 -1516 -456 -1287 -888 -2998 -1586 -6097 900000 -5218 -168 -4528 -1260 505 -2891 -230 -2595 78 -3025 222 -1415 -277 -145 -1686 498 -2772 268 -1632 141 -724 136 -294 -1021 429 -516 959 -753 515 -546 1091 670 1121 1183 82 1789 -129 1798 360 1592 716 1308 1410 1658 2234 1111 2530 788 2135 1463 1291 1301 1440 1750 611 2411 1027 2473 450 1965 1411 1544 1792 1015 2320 223 1491 -822 209 -675 -748 -549 -254 318 -1317 384 -1306 349 -311 583 1104 2 608 -971 -208 -2726 -598 -1066 -228 -417 -761 -432 -1600 -552 -2299 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