File name: Pandora140s1_WashingtonDC_20230306_L2Fit_fout2c14d20220101p1-8.txt File generation date: 20241218T202834.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 140 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora140_OF_v3d20200721.txt Instrument calibration file used: Pandora140s1_CF_v14d20220101.txt Level 1 file used: Pandora140s1_WashingtonDC_20230306_L1_smca1c14d20220101p1-8.txt Full location name: McMillan Reservoir Short location name: WashingtonDC Country of location: United States Location latitude [deg]: 38.9218 Location longitude [deg]: -77.0124 Location altitude [m]: 58 Local noon date: 20230306 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 10 "Based on session 8 "Modif only on SO2 (WashingtonDC)""" First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0439 305.1847 305.3255 305.4663 305.6071 305.7478 305.8885 306.0293 306.1700 306.3107 306.4514 306.5921 306.7328 306.8734 307.0141 307.1547 307.2954 307.4360 307.5766 307.7172 307.8578 307.9983 308.1389 308.2794 308.4200 308.5605 308.7010 308.8415 308.9820 309.1225 309.2630 309.4034 309.5439 309.6843 309.8247 309.9652 310.1056 310.2459 310.3863 310.5267 310.6670 310.8074 310.9477 311.0881 311.2284 311.3687 311.5089 311.6492 311.7895 311.9297 312.0700 312.2102 312.3504 312.4906 312.6308 312.7710 312.9112 313.0514 313.1915 313.3316 313.4718 313.6119 313.7520 313.8921 314.0322 314.1722 314.3123 314.4523 314.5924 314.7324 314.8724 315.0124 315.1524 315.2924 315.4324 315.5723 315.7123 315.8522 315.9921 316.1320 316.2719 316.4118 316.5517 316.6915 316.8314 316.9712 317.1111 317.2509 317.3907 317.5305 317.6703 317.8100 317.9498 318.0895 318.2293 318.3690 318.5087 318.6484 318.7881 318.9278 319.0675 319.2071 319.3468 319.4864 319.6260 319.7656 319.9052 320.0448 320.1844 320.3239 320.4635 320.6030 320.7426 320.8821 321.0216 321.1611 321.3006 321.4400 321.5795 321.7189 321.8584 321.9978 322.1372 322.2766 322.4160 322.5554 322.6947 322.8341 322.9734 323.1128 323.2521 323.3914 323.5307 323.6700 323.8093 323.9485 324.0878 324.2270 324.3662 324.5054 324.6446 324.7838 324.9230 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230306T120502.5Z 8465.503501 248 1 16.98 2 84.76 101.61 97.23 293.86 0.00 1 0.00 1 0 25 7.560e-01 8.038e-02 5.772e-01 7.674e-02 9.557852e-01 4.492465e-02 1.200292e-02 -6.000000e+00 4.435098e-01 225.94 -2.00 3.47 -2.00 321.92 0.00e+00 1.329912e-02 1.576659e-02 1.095371e-02 -6.000000e+00 2.169472e-02 277.76 -2.00 20.00 -2.00 321.41 0.00e+00 9.494 0.015 302.00 328.00 3 6.4744e-01 1.4694e-01 1.1613e-01 -6.0000e+00 1.1085e+00 2.0842e+00 1.6772e-01 6.6365e-02 -6.0000e+00 1.2142e+00 -2.1796e+00 1.0065e-01 2.8032e-02 -6.0000e+00 7.0923e-01 7.9512e-01 5.9531e-02 8.3452e-03 -6.0000e+00 3.0031e-01 6.4844e-06 7.3242e-04 2.0501e-03 2.7460e-04 -6.0000e+00 2.1746e-02 3.9175e-03 0.0000e+00 12 9 9 12 1 1 -7.08 18.35 1.36 0.00392 0.00942 5 3 1 5 0 2801.200 26.41 20.00 18.35 11.06 26.6 994.66 83268 900000 174235 900000 -51608 900000 128978 900000 900000 -33897 -33498 900000 15401 64539 -30058 131367 -6428 -46021 900000 900000 -22789 -41386 -4894 144132 137238 240226 -93343 900000 900000 155791 -49193 -77954 -3961 164678 900000 -25869 182700 -49402 -17758 11145 900000 -592 -5850 107308 900000 73828 -12886 145140 4093 -33364 900000 309521 75394 36827 27353 80762 9064 133098 142867 158778 89251 110680 88162 262454 16123 72262 22405 35063 30202 -706 68300 16419 -7156 -37265 132466 -3187 -6388 14457 228818 21992 35815 76813 -2487 17695 -6215 -11921 -35762 25727 17019 34675 -23832 -12154 -12027 3206 -7105 9824 -8337 -2857 13356 8131 1540 -14756 -11674 5751 928 -5772 -11576 -5233 1301 4251 4131 5657 -794 -4864 -2338 6517 -5817 1790 3331 -36 6646 7399 10244 2555 -5123 218 -1516 992 -4790 2839 -5075 4434 -1207 -1397 -2970 23 5801 -1164 -136 703 -1580 -2606 2700 6214 900000 13003 900000 -8024 900000 9626 900000 900000 -2530 -2500 900000 1149 4817 -4113 9804 -840 -9159 900000 900000 -2976 -5663 -465 10757 10242 17928 -15094 900000 900000 11627 -6341 -14544 -430 12290 900000 -2808 13635 -7374 -2169 1134 900000 -72 -754 8008 900000 5510 -1661 10832 472 -5885 900000 23100 5627 4248 3526 6027 1353 9933 10662 11850 6661 8260 6580 19587 2735 6864 3496 4996 4918 -177 9268 3787 -1991 -12641 9886 -584 -1127 2158 17077 4327 7290 11986 -945 5763 -2699 -5743 -22565 8902 6351 10351 -11803 -5030 -4896 1196 -3422 4799 -5826 -2229 9877 6399 1212 -12114 -8158 3278 592 -4151 -9346 -4332 1139 4211 4736 7024 -1087 -6898 -3124 7737 -7933 2381 4610 -53 8883 9237 11885 3103 -6500 256 -1769 1204 -7279 4700 -10329 9025 -2792 -3479 -8102 63 15506 -3372 -386 1878 -3977 -6100 5679 SS 20230306T121538.1Z 8465.510858 251 1 49.61 2 82.75 103.32 99.07 295.55 0.00 1 0.00 1 0 17 4.201e-01 1.862e-02 3.295e-01 1.027e-02 8.780834e-01 5.811529e-03 9.454639e-03 -6.000000e+00 2.399665e-01 225.94 -2.00 3.47 -2.00 322.20 0.00e+00 3.352261e-03 3.281512e-03 1.248714e-03 -6.000000e+00 1.062405e-02 277.76 -2.00 20.00 -2.00 321.76 0.00e+00 7.311 0.007 302.00 328.00 3 7.5744e-01 2.2298e-02 8.6789e-02 -6.0000e+00 5.9527e-01 7.7021e-01 3.0426e-02 4.9325e-02 -6.0000e+00 6.4799e-01 -1.0787e+00 2.9623e-02 2.6008e-02 -6.0000e+00 3.8278e-01 4.4364e-01 1.3872e-02 9.0392e-03 -6.0000e+00 1.6231e-01 7.5343e-05 -1.5590e-03 2.8254e-04 1.2589e-04 -6.0000e+00 1.1330e-02 6.3971e-03 0.0000e+00 12 8 8 10 0 0 61.09 18.34 0.37 0.00640 -0.00532 106 20 1 5 0 467.950 26.41 20.01 18.34 11.73 26.6 1001.03 -140237 -25554 -197543 -79232 -135306 900000 -128007 900000 -126380 40345 -117559 -72062 900000 -145422 11683 -41999 47779 -58346 -61526 19765 -13567 140033 -15357 22756 -67053 21107 -43570 58605 -67196 16206 -34811 -41953 36399 -15042 25572 31259 41394 -27742 19961 40815 30877 28101 25497 42310 -2036 35508 1565 -6661 19045 -5098 33011 28081 52809 28722 42656 25242 38383 6615 9503 6114 -3807 23834 16509 15345 25343 18995 8362 5005 14150 7066 10468 10077 9384 5643 6897 3543 1868 -3930 5976 3630 1506 1269 1768 3519 2558 2787 -565 -3298 1456 604 911 845 -1866 -4895 576 -5620 -509 -1757 -2536 -2000 -1969 154 -4623 -1721 -2474 -586 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5.367e-01 1.131e-02 1.634e-01 3.409e-03 7.380972e-01 1.847526e-03 8.126622e-03 -6.000000e+00 3.029770e-01 225.94 -2.00 3.47 -2.00 321.69 0.00e+00 2.982139e-03 9.553240e-04 2.376075e-03 -6.000000e+00 1.318612e-02 277.76 -2.00 20.00 -2.00 321.22 0.00e+00 5.911 0.004 302.00 328.00 3 6.6512e-01 6.5740e-03 7.0907e-02 -6.0000e+00 7.5104e-01 2.2588e-01 9.4902e-03 4.1696e-02 -6.0000e+00 8.1685e-01 -3.3044e-01 1.0031e-02 2.3575e-02 -6.0000e+00 4.8586e-01 1.3337e-01 4.6791e-03 8.1952e-03 -6.0000e+00 2.0717e-01 3.7678e-04 -6.7472e-04 9.4750e-05 1.1262e-04 -6.0000e+00 1.4237e-02 5.5610e-03 0.0000e+00 12 8 8 10 0 0 60.51 18.35 0.22 0.00556 0.00049 256 48 1 5 0 189.020 26.41 20.00 18.35 12.77 26.5 1008.32 -56093 -204257 -169081 -159440 -214188 -130643 -210536 -47632 -194742 -133683 -211476 -136367 -120999 -111065 -22549 -86942 -22838 -81200 -13422 -53441 -19410 -30430 -58476 -5292 -44410 -5859 -45115 16470 -61875 -31871 -27200 -16425 -5130 -4590 6583 -22391 18342 -2816 20933 -3913 14515 8899 -2290 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