File name: Pandora208s1_Windsor-West_20220614_L2Fit_fout2c4d20220407p1-8.txt File generation date: 20251128T143632.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 208 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora208_OF_v4d20211014.txt Instrument calibration file used: Pandora208s1_CF_v4d20220407.txt Level 1 file used: Pandora208s1_Windsor-West_20220614_L1_smca1c4d20220407p1-8.txt Full location name: Ontario Ministry of the Environment, Windsor West Short location name: Windsor-West Country of location: Canada Location latitude [deg]: 42.2929 Location longitude [deg]: -83.0731 Location altitude [m]: 180 Local noon date: 20220614 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 206 347 Nominal wavelengths inside fitting window [nm]: 305.0986 305.2399 305.3812 305.5224 305.6637 305.8050 305.9462 306.0874 306.2286 306.3698 306.5110 306.6522 306.7934 306.9345 307.0757 307.2168 307.3579 307.4990 307.6401 307.7812 307.9223 308.0633 308.2044 308.3454 308.4864 308.6275 308.7685 308.9095 309.0504 309.1914 309.3324 309.4733 309.6142 309.7552 309.8961 310.0370 310.1779 310.3187 310.4596 310.6004 310.7413 310.8821 311.0229 311.1637 311.3045 311.4453 311.5861 311.7268 311.8676 312.0083 312.1490 312.2897 312.4304 312.5711 312.7118 312.8525 312.9931 313.1338 313.2744 313.4150 313.5556 313.6962 313.8368 313.9773 314.1179 314.2584 314.3990 314.5395 314.6800 314.8205 314.9610 315.1015 315.2419 315.3824 315.5228 315.6632 315.8037 315.9441 316.0845 316.2248 316.3652 316.5056 316.6459 316.7862 316.9265 317.0669 317.2072 317.3474 317.4877 317.6280 317.7682 317.9085 318.0487 318.1889 318.3291 318.4693 318.6095 318.7496 318.8898 319.0299 319.1701 319.3102 319.4503 319.5904 319.7305 319.8705 320.0106 320.1506 320.2907 320.4307 320.5707 320.7107 320.8507 320.9907 321.1306 321.2706 321.4105 321.5504 321.6903 321.8302 321.9701 322.1100 322.2499 322.3897 322.5296 322.6694 322.8092 322.9490 323.0888 323.2286 323.3684 323.5081 323.6479 323.7876 323.9273 324.0670 324.2067 324.3464 324.4861 324.6258 324.7654 324.9051 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220614T111137.1Z 8200.466402 212 1 47.06 2 78.25 69.13 104.87 247.39 0.00 1 0.00 1 0 17 3.971e-01 8.940e-03 2.970e-01 6.865e-03 6.098215e-01 3.799555e-03 7.001012e-03 -6.000000e+00 2.373230e-01 232.78 -2.00 3.53 -2.00 321.10 0.00e+00 1.750640e-03 1.770470e-03 2.353715e-03 -6.000000e+00 1.107060e-02 284.89 -2.00 20.00 -2.00 320.51 0.00e+00 4.753 0.002 302.00 328.00 3 3.3001e+00 1.2854e-02 5.8141e-02 -6.0000e+00 5.9576e-01 1.0067e-01 1.7318e-02 3.6036e-02 -6.0000e+00 6.4312e-01 -1.0584e-01 1.6934e-02 1.8705e-02 -6.0000e+00 3.8092e-01 2.9572e-02 8.1125e-03 5.5661e-03 -6.0000e+00 1.6167e-01 9.5185e-05 5.2593e-04 2.0628e-04 8.6164e-05 -6.0000e+00 1.1486e-02 -2.8996e-03 -7.9454e-06 11 9 0 11 8 0 84.35 19.33 0.41 -0.00290 0.00105 50 14 1 5 0 941.030 22.71 14.99 19.33 24.60 6.6 999.42 137507 -69182 -177949 900000 -127309 900000 -83531 -9310 20597 -105835 900000 -110981 234202 -60123 -35066 99438 56476 -59182 -42042 -37006 -26978 90616 -28956 97847 -41559 25052 -28909 -11603 9134 -2085 17675 -2685 40607 -9171 -8381 -10270 3286 798 -3362 2957 415 14103 -6595 156 -4981 16850 8583 -3767 -7432 -6055 2259 5183 187 -2724 10407 -791 6801 -2494 -346 4011 -3038 2406 1167 5659 1554 5092 1350 4076 2732 2608 1060 1490 1158 957 -715 -2614 -4614 -5504 -2760 -1765 544 -2565 -1818 354 -1323 721 -619 1231 -301 -20 1900 107 1374 -1445 1260 -133 860 732 -180 -1144 -324 -175 -548 -1037 -1264 -914 -754 -691 -567 708 536 642 -130 -922 317 -578 311 71 487 -365 457 425 874 414 210 -450 774 470 219 -358 -348 214 -176 -413 390 6 407 -277 -73 -169 43 -247 920 -463 -3030 900000 -1161 900000 -615 -62 138 -1345 900000 -1856 1567 -965 -540 665 453 -1663 -1069 -941 -632 667 -755 785 -1446 469 -928 -303 196 -56 461 -101 1114 -423 -370 -481 154 46 -250 241 38 1208 -724 16 -556 1544 873 -449 -965 -842 323 797 33 -534 1880 -166 1347 -534 -71 791 -685 575 318 1605 462 1417 392 1222 941 1019 452 644 486 375 -257 -873 -1519 -1937 -1091 -812 282 -1531 -1156 235 -956 541 -489 969 -236 -15 1276 69 867 -1008 975 -120 884 838 -215 -1323 -341 -168 -509 -1023 -1335 -1013 -888 -878 -797 1086 884 1075 -214 -1449 466 -846 467 113 814 -623 755 679 1342 611 299 -622 1066 710 372 -675 -702 411 -357 -898 893 15 978 -677 -173 -379 91 -556 SS 20220614T111718.4Z 8200.470352 215 1 46.57 2 77.26 70.01 105.80 248.20 0.00 1 0.00 1 0 25 2.515e-01 1.139e-02 2.496e-01 6.705e-03 5.678959e-01 3.707086e-03 6.742605e-03 -6.000000e+00 1.497165e-01 232.78 -2.00 3.53 -2.00 320.98 0.00e+00 3.855296e-03 1.621745e-03 2.706342e-03 -6.000000e+00 6.689695e-03 284.89 -2.00 20.00 -2.00 320.36 0.00e+00 4.412 0.002 302.00 328.00 3 3.6464e+00 1.2195e-02 5.4146e-02 -6.0000e+00 3.7585e-01 1.0296e-01 1.5914e-02 3.3688e-02 -6.0000e+00 4.0570e-01 -1.1736e-01 1.4864e-02 1.8738e-02 -6.0000e+00 2.4065e-01 3.9877e-02 7.2296e-03 6.5498e-03 -6.0000e+00 1.0260e-01 9.5954e-05 5.2299e-04 2.0570e-04 9.8562e-05 -6.0000e+00 7.1684e-03 -3.2365e-03 7.3574e-06 12 8 8 10 0 0 77.72 19.34 0.58 -0.00324 0.00069 38 10 1 5 0 1225.360 22.71 14.98 19.34 24.82 6.6 1001.41 900000 -105387 47108 -50039 900000 -156997 -69694 -23460 12548 -7491 -6764 -82524 -95977 38301 -75216 2527 7549 -7744 44360 -22390 34670 -38115 6243 -39075 -7320 -30588 -4517 -34943 -11772 -37994 -32421 16592 2664 14360 -28236 12959 -15650 18903 8956 11001 -3788 8072 6856 -6258 3700 -9090 548 -589 1551 4051 2411 5889 3914 8113 -1368 5717 -2424 5270 -4702 5516 3493 6632 10464 890 3318 -4205 1770 1634 3663 -833 4906 3440 1682 -111 -3655 86 -7601 -454 -4118 -979 -1996 -1294 687 -1447 1130 -1229 1590 -999 812 620 2642 -152 -525 -162 -987 1573 -688 523 -1096 -713 -385 -119 -1097 -2120 -597 -1770 412 -1824 1112 -323 345 -360 -118 422 -428 -460 100 1547 -107 697 63 189 592 438 1313 -232 1321 -912 825 -154 826 -539 -378 -193 52 691 -68 169 -757 -168 -68 -206 900000 -1377 308 -389 900000 -3171 -672 -161 82 -51 -48 -1464 -2449 322 -2411 43 136 -178 649 -669 593 -1364 152 -1605 -232 -1276 -145 -1468 -396 -1844 -1755 640 133 648 -1872 589 -1076 1106 702 982 -430 864 774 -822 448 -1276 71 -79 214 587 395 1024 754 1606 -311 1251 -583 1156 -1116 1195 823 1690 2885 292 1064 -1401 554 539 1338 -360 2147 1555 750 -47 -1451 32 -2881 -169 -1737 -468 -1107 -793 442 -1011 826 -975 1276 -835 654 471 1827 -102 -363 -114 -791 1415 -724 604 -1325 -825 -408 -115 -1035 -2136 -634 -2001 484 -2359 1537 -499 566 -602 -191 642 -621 -657 147 2372 -176 1157 104 299 900 637 1820 -314 1770 -1361 1352 -280 1585 -1098 -809 -438 120 1626 -163 412 -1808 -396 -153 -444 SS 20220614T112323.2Z 8200.474574 218 1 46.98 2 76.20 70.94 106.80 249.07 0.00 1 0.00 1 0 17 2.217e-01 7.534e-03 2.342e-01 5.287e-03 5.379622e-01 2.878268e-03 6.350227e-03 -6.000000e+00 1.316515e-01 232.78 -2.00 3.53 -2.00 320.75 0.00e+00 3.196734e-03 1.185356e-03 2.260305e-03 -6.000000e+00 5.742873e-03 284.89 -2.00 20.00 -2.00 320.11 0.00e+00 4.095 0.001 302.00 328.00 3 3.6522e+00 9.2030e-03 5.0365e-02 -6.0000e+00 3.3081e-01 4.6633e-02 1.1785e-02 3.1079e-02 -6.0000e+00 3.5692e-01 -2.6191e-02 1.0947e-02 1.6836e-02 -6.0000e+00 2.1198e-01 -3.0638e-04 5.4023e-03 5.7492e-03 -6.0000e+00 8.9799e-02 1.3282e-04 9.5701e-04 1.6109e-04 8.3912e-05 -6.0000e+00 6.2646e-03 -3.3310e-03 1.8447e-05 11 8 0 10 0 0 28.09 19.32 0.31 -0.00333 0.00386 45 12 1 5 0 1043.700 22.71 14.99 19.32 25.04 6.6 1003.04 -1047 -107068 -41374 -87119 -20520 -58050 84546 -61355 -27583 63315 -63041 83525 -78618 -34887 -32658 -7623 -32595 -4906 -37818 -21930 -12187 -11489 1349 -1675 18217 -18876 19795 14685 -5548 -10975 -21241 2675 -1366 28732 35 1283 -15089 -4790 -7861 567 -4069 4653 -3698 769 -1267 4528 6139 -882 4707 193 5064 2527 -897 4533 96 3302 -92 4198 2533 970 1993 -340 3144 115 3617 -1879 1434 -113 1949 -1119 2320 200 1471 519 -2228 -1735 -2169 -576 -1878 179 -2466 -1291 -1483 -1492 137 -212 -339 447 1577 843 -239 -407 -655 -127 -447 -220 709 1139 -724 629 -1355 -29 -1576 -193 -1370 -1307 -271 -199 1080 392 958 36 -81 -211 46 393 -133 144 253 373 -580 404 198 261 37 189 579 -313 258 -58 78 -753 -97 -650 529 173 68 402 -543 16 -20 -16 -5 -1551 -325 -1026 -116 -484 436 -663 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