File name: Pandora208s1_Windsor-West_20220905_L2Fit_fout2c4d20220407p1-8.txt File generation date: 20251128T145954.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 208 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora208_OF_v4d20211014.txt Instrument calibration file used: Pandora208s1_CF_v4d20220407.txt Level 1 file used: Pandora208s1_Windsor-West_20220905_L1_smca1c4d20220407p1-8.txt Full location name: Ontario Ministry of the Environment, Windsor West Short location name: Windsor-West Country of location: Canada Location latitude [deg]: 42.2929 Location longitude [deg]: -83.0731 Location altitude [m]: 180 Local noon date: 20220905 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 206 347 Nominal wavelengths inside fitting window [nm]: 305.0986 305.2399 305.3812 305.5224 305.6637 305.8050 305.9462 306.0874 306.2286 306.3698 306.5110 306.6522 306.7934 306.9345 307.0757 307.2168 307.3579 307.4990 307.6401 307.7812 307.9223 308.0633 308.2044 308.3454 308.4864 308.6275 308.7685 308.9095 309.0504 309.1914 309.3324 309.4733 309.6142 309.7552 309.8961 310.0370 310.1779 310.3187 310.4596 310.6004 310.7413 310.8821 311.0229 311.1637 311.3045 311.4453 311.5861 311.7268 311.8676 312.0083 312.1490 312.2897 312.4304 312.5711 312.7118 312.8525 312.9931 313.1338 313.2744 313.4150 313.5556 313.6962 313.8368 313.9773 314.1179 314.2584 314.3990 314.5395 314.6800 314.8205 314.9610 315.1015 315.2419 315.3824 315.5228 315.6632 315.8037 315.9441 316.0845 316.2248 316.3652 316.5056 316.6459 316.7862 316.9265 317.0669 317.2072 317.3474 317.4877 317.6280 317.7682 317.9085 318.0487 318.1889 318.3291 318.4693 318.6095 318.7496 318.8898 319.0299 319.1701 319.3102 319.4503 319.5904 319.7305 319.8705 320.0106 320.1506 320.2907 320.4307 320.5707 320.7107 320.8507 320.9907 321.1306 321.2706 321.4105 321.5504 321.6903 321.8302 321.9701 322.1100 322.2499 322.3897 322.5296 322.6694 322.8092 322.9490 323.0888 323.2286 323.3684 323.5081 323.6479 323.7876 323.9273 324.0670 324.2067 324.3464 324.4861 324.6258 324.7654 324.9051 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220905T172134.4Z 8283.723315 256 1 20.35 2 35.73 176.01 128.98 94.04 0.00 1 0.00 1 0 17 9.701e-03 7.452e-03 5.954e-03 3.255e-03 1.740864e-01 1.690549e-03 2.104869e-03 -6.000000e+00 5.702112e-03 229.97 -2.00 3.53 -2.00 315.87 0.00e+00 5.648931e-04 1.743140e-04 4.685625e-05 -6.000000e+00 2.533196e-04 286.79 -2.00 20.00 -2.00 315.14 0.00e+00 1.231 0.000 302.00 328.00 3 5.9503e+00 4.3900e-03 1.5144e-02 -6.0000e+00 1.4219e-02 4.6087e-02 4.8823e-03 9.0525e-03 -6.0000e+00 1.5369e-02 -1.6261e-03 2.8045e-03 4.4066e-03 -6.0000e+00 9.1603e-03 -3.2547e-03 1.2822e-03 1.2598e-03 -6.0000e+00 3.9115e-03 3.4297e-04 2.7130e-04 9.6241e-05 1.5660e-05 -6.0000e+00 2.7395e-04 -6.3297e-03 -8.5782e-05 12 9 1 12 1 1 99.97 19.37 0.23 -0.00633 -0.00429 11 8 1 5 0 1681.220 22.80 14.98 19.37 28.81 8.5 993.60 -1456 1293 -1304 -3530 1977 -328 -1126 171 351 -796 -2524 -2502 -304 63 459 753 -824 1218 109 378 1244 1463 595 830 610 -604 1485 -484 -719 237 1815 1257 -323 -1521 -1667 -1720 -1356 -943 574 4 -709 -131 -675 -389 -31 -296 -173 -1832 90 -1246 1051 -258 720 297 1167 935 264 554 -438 866 1338 1372 1105 1105 541 -31 -409 -237 216 453 391 693 710 637 -748 -1315 -837 -1287 -2689 -1233 -1498 -1914 -1213 -927 -225 -101 474 1275 1140 269 843 -1043 -748 -128 -931 -160 817 1454 207 -288 -963 -1071 -598 -525 -1082 -692 -711 -199 886 598 1081 386 -18 -690 -289 -394 -357 -24 105 367 164 473 764 -125 307 265 92 187 89 342 2 -122 226 -194 211 157 635 380 -180 -413 -586 -909 -358 326 -333 -836 395 -65 -241 40 89 -209 -656 -670 -88 20 163 282 -320 475 44 157 512 596 250 364 277 -283 662 -203 -283 91 719 529 -145 -679 -696 -729 -638 -518 350 3 -525 -100 -500 -287 -24 -224 -126 -1308 61 -867 752 -197 570 245 969 753 215 466 -366 723 1111 1223 1052 1077 503 -28 -341 -196 194 434 400 724 729 622 -678 -1124 -649 -980 -2230 -1125 -1444 -2001 -1321 -1017 -263 -125 612 1661 1463 327 973 -1109 -734 -131 -981 -184 981 1869 272 -365 -1139 -1240 -686 -645 -1371 -915 -981 -272 1258 892 1640 574 -24 -925 -372 -491 -456 -31 147 534 231 679 1055 -164 401 327 111 232 118 451 3 -168 319 -288 317 244 1004 611 -287 -643 -884 -1398 SS 20220905T173036.8Z 8283.729593 262 1 6.23 2 35.67 179.86 127.40 95.39 0.00 1 0.00 1 0 25 1.797e-02 1.210e-02 1.420e-02 8.508e-03 1.774104e-01 4.439221e-03 2.127081e-03 -6.000000e+00 1.055933e-02 229.97 -2.00 3.53 -2.00 315.51 0.00e+00 9.494242e-04 4.253539e-04 2.451095e-05 -6.000000e+00 4.692294e-04 286.79 -2.00 20.00 -2.00 314.81 0.00e+00 1.230 0.000 302.00 328.00 3 6.3036e+00 1.1485e-02 1.5228e-02 -6.0000e+00 2.6331e-02 6.0745e-02 1.2765e-02 9.2248e-03 -6.0000e+00 2.8462e-02 -8.5950e-03 7.3073e-03 4.4627e-03 -6.0000e+00 1.6964e-02 -2.9759e-03 3.2917e-03 1.3744e-03 -6.0000e+00 7.2433e-03 2.3848e-04 5.8644e-04 2.4978e-04 1.6147e-05 -6.0000e+00 5.0745e-04 -8.9046e-03 -2.2501e-04 12 9 9 12 1 1 999.00 19.34 0.35 -0.00890 -0.00450 1 4 1 5 0 3024.340 22.71 15.00 19.34 28.98 8.4 994.53 2290 270 -2515 1721 -5913 1977 2042 614 513 3415 306 -7568 176 -1754 1507 -2999 4513 -877 3243 -795 2810 2510 -3453 3058 -1273 1008 -415 -359 -1855 939 -1538 -2616 1203 115 -1126 -7632 196 -2549 -1627 -948 424 1564 -189 1447 -1143 672 -1690 -284 -1100 3188 225 1044 2343 841 1698 -137 362 118 191 416 2048 2271 -36 2750 -680 -1420 -1267 -423 671 -200 -141 1360 -63 2379 -155 -2871 -2320 -1118 -1820 -1474 -2041 -2060 -705 -1577 -503 1037 1486 1141 1516 1377 -587 -947 -2137 -1274 -256 251 258 -427 412 -1157 23 -238 -1158 -966 -74 -1066 -416 674 370 1689 1323 946 -427 -671 -326 -1014 342 -541 -182 -336 873 -289 1914 1048 -592 -1120 -660 -385 -379 1567 253 -327 48 867 738 1060 378 -296 -23 -796 -515 -1402 624 75 -745 442 -1465 442 487 165 149 977 88 -2437 58 -632 581 -1281 1824 -384 1398 -366 1247 1108 -1656 1431 -644 506 -205 -163 -803 412 -691 -1257 585 55 -512 -3770 100 -1499 -1072 -698 327 1177 -147 1108 -893 529 -1315 -210 -797 2239 172 831 1847 697 1416 -118 311 100 160 352 1788 2125 -35 2681 -649 -1287 -1073 -355 611 -197 -147 1433 -66 2314 -147 -2502 -1914 -893 -1578 -1365 -2017 -2196 -777 -1785 -605 1259 1873 1468 1906 1628 -669 -1018 -2155 -1329 -273 283 319 -553 534 -1453 28 -278 -1308 -1167 -92 -1394 -565 907 525 2397 1923 1387 -593 -885 -410 -1245 424 -696 -252 -468 1210 -398 2573 1395 -761 -1369 -813 -471 -492 2091 339 -447 67 1216 1095 1621 576 -461 -36 -1235 -772 -2065 SS 20220905T182244.2Z 8283.765790 290 1 5.46 2 37.48 201.46 118.37 102.88 0.00 1 0.00 1 0 17 2.144e-02 1.304e-02 1.624e-02 9.393e-03 1.782702e-01 4.893498e-03 2.122473e-03 -6.000000e+00 1.260405e-02 229.96 -2.00 3.53 -2.00 315.61 0.00e+00 1.894544e-04 4.805681e-04 1.220331e-04 -6.000000e+00 5.598444e-04 286.79 -2.00 20.00 -2.00 314.91 0.00e+00 1.259 0.000 302.00 328.00 3 6.3105e+00 1.2674e-02 1.5413e-02 -6.0000e+00 3.1431e-02 4.5405e-02 1.4076e-02 9.1045e-03 -6.0000e+00 3.3969e-02 6.1087e-03 8.0662e-03 4.4334e-03 -6.0000e+00 2.0247e-02 -3.4406e-03 3.6639e-03 1.2302e-03 -6.0000e+00 8.6481e-03 2.3020e-04 3.0599e-04 2.7565e-04 1.5668e-05 -6.0000e+00 6.0541e-04 -8.8025e-03 -1.1906e-04 12 9 9 12 1 1 999.00 19.40 1.20 -0.00880 -0.00650 1 5 1 5 0 2641.480 22.80 14.99 19.40 29.68 8.5 999.88 -673 -219 -200 -309 11209 -4972 312 7519 2796 -4913 1779 -629 -1396 6 -2934 1525 -3221 4202 -5370 1757 -126 2056 -744 -2487 1841 -3433 1915 -2430 74 3222 -52 3906 1454 -2220 -6361 -71 -6389 -84 1770 1419 -1242 1059 -1575 -1994 2830 736 1071 -848 61 -1439 877 -94 1711 699 1681 295 204 2155 -656 2190 140 3450 -211 1089 804 -939 -754 -734 1972 465 1567 696 835 733 -669 -427 -1276 -1622 -3045 -752 -1798 -2187 -3203 -1788 -464 -470 302 755 790 -569 402 -324 -310 -1233 -2223 91 1284 1530 787 1009 -1040 -319 -2097 -109 -1154 -679 -98 -269 -313 1061 1128 -246 1065 -206 -606 -1987 811 -51 1031 499 798 1675 546 -24 -1233 347 666 1664 508 -245 -429 -626 -456 -788 1992 -298 825 758 -530 -1034 -587 -1229 -178 -61 -55 -77 2221 -1130 72 1797 762 -1477 488 -182 -449 2 -1134 598 -1352 1678 -2425 758 -56 881 -337 -1197 882 -1694 907 -1111 31 1343 -22 1708 687 -1067 -2979 -32 -3386 -47 1152 1005 -924 794 -1234 -1565 2188 572 802 -624 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