File name: Pandora208s1_Windsor-West_20220924_L2Fit_fout2c4d20220407p1-8.txt File generation date: 20251128T150628.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 208 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora208_OF_v4d20211014.txt Instrument calibration file used: Pandora208s1_CF_v4d20220407.txt Level 1 file used: Pandora208s1_Windsor-West_20220924_L1_smca1c4d20220407p1-8.txt Full location name: Ontario Ministry of the Environment, Windsor West Short location name: Windsor-West Country of location: Canada Location latitude [deg]: 42.2929 Location longitude [deg]: -83.0731 Location altitude [m]: 180 Local noon date: 20220924 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 206 347 Nominal wavelengths inside fitting window [nm]: 305.0986 305.2399 305.3812 305.5224 305.6637 305.8050 305.9462 306.0874 306.2286 306.3698 306.5110 306.6522 306.7934 306.9345 307.0757 307.2168 307.3579 307.4990 307.6401 307.7812 307.9223 308.0633 308.2044 308.3454 308.4864 308.6275 308.7685 308.9095 309.0504 309.1914 309.3324 309.4733 309.6142 309.7552 309.8961 310.0370 310.1779 310.3187 310.4596 310.6004 310.7413 310.8821 311.0229 311.1637 311.3045 311.4453 311.5861 311.7268 311.8676 312.0083 312.1490 312.2897 312.4304 312.5711 312.7118 312.8525 312.9931 313.1338 313.2744 313.4150 313.5556 313.6962 313.8368 313.9773 314.1179 314.2584 314.3990 314.5395 314.6800 314.8205 314.9610 315.1015 315.2419 315.3824 315.5228 315.6632 315.8037 315.9441 316.0845 316.2248 316.3652 316.5056 316.6459 316.7862 316.9265 317.0669 317.2072 317.3474 317.4877 317.6280 317.7682 317.9085 318.0487 318.1889 318.3291 318.4693 318.6095 318.7496 318.8898 319.0299 319.1701 319.3102 319.4503 319.5904 319.7305 319.8705 320.0106 320.1506 320.2907 320.4307 320.5707 320.7107 320.8507 320.9907 321.1306 321.2706 321.4105 321.5504 321.6903 321.8302 321.9701 322.1100 322.2499 322.3897 322.5296 322.6694 322.8092 322.9490 323.0888 323.2286 323.3684 323.5081 323.6479 323.7876 323.9273 324.0670 324.2067 324.3464 324.4861 324.6258 324.7654 324.9051 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220924T145734.8Z 8302.623320 195 1 47.47 2 54.13 132.52 39.74 139.98 0.00 1 0.00 1 0 17 1.876e-02 7.010e-03 1.304e-02 3.985e-03 2.329413e-01 2.044870e-03 2.830612e-03 -6.000000e+00 1.094363e-02 228.06 -2.00 3.53 -2.00 317.57 0.00e+00 2.267381e-04 3.144094e-04 1.621661e-04 -6.000000e+00 4.858304e-04 284.87 -2.00 20.00 -2.00 316.80 0.00e+00 1.702 0.000 302.00 328.00 3 5.9381e+00 5.4147e-03 2.0655e-02 -6.0000e+00 2.7184e-02 3.8245e-02 6.0936e-03 1.2135e-02 -6.0000e+00 2.9435e-02 1.3761e-02 3.6906e-03 5.9634e-03 -6.0000e+00 1.7551e-02 -1.1834e-02 1.8359e-03 1.6761e-03 -6.0000e+00 7.5085e-03 1.9747e-04 6.7531e-05 1.2048e-04 1.9583e-05 -6.0000e+00 5.2940e-04 -5.5864e-03 -1.2677e-04 11 8 0 10 0 0 99.47 19.39 0.65 -0.00559 -0.00508 34 9 1 5 0 1395.860 22.80 15.01 19.39 20.33 8.6 928.46 4451 -7717 5175 -8403 19 -6162 3490 -6015 -87 -1571 -4115 838 -939 1011 -1834 -1482 1421 104 3215 736 3909 -479 2536 -2985 468 -2567 2098 -2333 1363 1803 -2995 5337 -1879 289 -2633 -371 -2466 -492 -757 -940 -184 235 835 -1565 1208 -1743 181 -1680 -237 -395 -204 1617 1128 1424 360 1569 -168 231 266 1101 1124 1474 2339 198 899 -312 222 -461 74 -864 664 1079 -159 995 -402 218 -1658 -354 -1170 -1301 -1249 -1742 -1323 -1111 40 -627 562 262 1084 209 316 -611 -265 77 -201 697 779 565 -483 119 -1525 -726 -126 -870 -659 -1038 -190 -643 656 137 400 473 164 -111 -429 72 -19 507 269 -138 154 -39 594 455 608 -255 954 190 281 42 38 -355 34 153 49 373 204 246 -642 78 -813 -407 465 -972 571 -972 2 -618 343 -729 -11 -205 -545 111 -142 171 -358 -310 298 23 711 172 890 -114 604 -792 126 -727 553 -597 337 446 -825 1453 -586 87 -767 -108 -819 -189 -327 -462 -96 126 456 -876 655 -964 95 -879 -128 -218 -119 926 683 897 235 1028 -113 153 173 761 767 1083 1829 163 703 -240 161 -338 59 -736 595 985 -145 898 -337 162 -1158 -241 -872 -1091 -1162 -1768 -1324 -1173 45 -752 696 331 1332 244 358 -635 -256 75 -212 806 939 739 -648 151 -1830 -856 -146 -1088 -830 -1374 -262 -926 987 218 655 757 248 -154 -589 96 -25 728 390 -210 234 -58 904 657 833 -334 1208 253 399 62 59 -563 55 246 83 655 366 447 -1164 136 -1378 -668 SS 20220924T150221.5Z 8302.626638 198 1 1.78 2 53.49 133.76 39.21 141.60 0.00 1 0.00 1 0 17 1.844e-02 9.745e-03 1.517e-02 7.555e-03 2.318287e-01 3.902298e-03 2.849013e-03 -6.000000e+00 1.076251e-02 228.06 -2.00 3.53 -2.00 316.12 0.00e+00 3.252414e-04 4.272529e-04 3.780221e-05 -6.000000e+00 4.775947e-04 284.87 -2.00 20.00 -2.00 315.41 0.00e+00 1.676 0.000 302.00 328.00 3 4.4369e+00 1.0120e-02 2.0416e-02 -6.0000e+00 2.6734e-02 3.9777e-02 1.1293e-02 1.2061e-02 -6.0000e+00 2.8944e-02 -4.5843e-03 6.5314e-03 5.9220e-03 -6.0000e+00 1.7258e-02 -3.4717e-03 3.0427e-03 1.6808e-03 -6.0000e+00 7.3866e-03 9.1464e-04 3.9853e-04 2.2144e-04 2.1285e-05 -6.0000e+00 5.2039e-04 -7.1814e-03 -7.9445e-05 12 9 9 12 1 1 999.00 19.38 0.34 -0.00718 -0.00419 1 16 1 5 0 795.400 22.80 15.01 19.38 20.00 8.6 927.13 5422 -2639 1071 -8138 -1348 -6298 4927 -2157 -2326 -5571 3535 -2489 -3146 2711 123 3952 -2403 2669 -440 1382 1791 1718 4250 214 2107 -708 1717 -1596 3042 1539 545 -607 290 1356 -1750 95 -4491 -1228 -1764 -2471 -1432 -4 179 -396 1374 -3501 271 -1790 694 -2718 1400 397 1763 803 905 1199 2194 -281 707 -7 207 109 1326 713 1059 939 250 1155 842 -1062 696 423 797 83 261 -570 -1228 1396 -1994 -1702 -1366 -1533 -2454 -52 -1259 -246 407 489 1074 230 798 -488 15 1399 702 85 882 730 -721 -500 -890 -559 -1534 -670 -22 -291 688 -1208 -263 954 -608 143 -581 -384 70 529 -1241 1261 177 1243 -783 85 -54 448 304 -47 902 1132 784 522 507 -249 -389 612 228 -656 308 229 -261 -170 -745 -791 1025 -551 225 -1710 -238 -1146 862 -453 -535 -1360 778 -608 -829 766 40 1272 -851 930 -163 519 673 644 1603 88 855 -303 729 -650 1113 574 218 -263 127 581 -757 41 -2181 -653 -1079 -1664 -984 -2 128 -284 966 -2559 186 -1261 468 -1866 978 297 1325 635 731 983 1794 -233 569 -6 172 98 1220 681 963 809 211 974 757 -1019 701 438 805 80 237 -501 -998 1130 -1749 -1565 -1348 -1593 -2709 -57 -1472 -294 504 616 1322 276 896 -521 16 1424 754 99 1093 929 -944 -641 -1093 -656 -1803 -812 -27 -384 914 -1663 -370 1399 -908 212 -819 -523 91 678 -1613 1697 245 1774 -1114 120 -77 612 396 -60 1112 1452 1048 718 722 -354 -569 910 351 -1027 489 369 -416 -269 -1144 -1211 SS 20220924T150706.6Z 8302.629938 201 1 28.64 2 52.86 135.03 38.70 143.24 0.00 1 0.00 1 0 17 7.910e-03 5.466e-03 1.039e-03 4.038e-04 2.243076e-01 2.076253e-04 2.738213e-03 -6.000000e+00 4.614606e-03 228.06 -2.00 3.53 -2.00 316.92 0.00e+00 4.263813e-04 2.710196e-05 1.038787e-04 -6.000000e+00 2.048722e-04 284.87 -2.00 20.00 -2.00 316.16 0.00e+00 1.652 0.000 302.00 328.00 3 1.7883e+00 5.4462e-04 1.9975e-02 -6.0000e+00 1.1463e-02 1.3408e-02 6.0978e-04 1.1647e-02 -6.0000e+00 1.2412e-02 3.2614e-03 3.5843e-04 5.7254e-03 -6.0000e+00 7.4008e-03 -6.8070e-03 1.7265e-04 1.6245e-03 -6.0000e+00 3.1660e-03 1.3542e-02 8.0863e-05 1.2064e-05 1.9694e-05 -6.0000e+00 2.2324e-04 -5.3935e-03 -1.3394e-04 12 1 1 12 1 1 99.97 19.40 0.28 -0.00539 -0.00479 884 386 1 5 0 31.720 22.80 15.01 19.40 20.03 8.7 928.34 -1150 -1296 -1744 -2508 -1675 -1675 -867 -466 -886 -1642 -1484 -1264 -1238 -86 -401 77 -2 530 517 781 642 986 1011 481 692 160 96 -430 291 565 829 1236 9 -1240 -1876 -1875 -1898 -686 -747 -795 -766 -673 -550 -294 -21 -371 -258 -435 -151 270 651 725 762 735 663 909 461 505 477 903 1032 1250 1543 649 289 93 12 274 704 218 318 183 405 219 -201 -221 -921 -488 -884 -1161 -1332 -1827 -1600 -1110 -654 -390 259 197 470 194 337 125 348 473 107 509 536 226 -494 -404 -872 -713 -181 -786 -937 -806 -473 -218 411 482 327 68 45 -169 162 295 467 472 141 -162 2 78 187 518 357 391 923 586 393 163 75 -216 189 41 115 112 122 -75 -284 -379 -589 -430 -169 -204 -274 -362 -216 -212 -117 -70 -146 -281 -250 -222 -244 -19 -100 20 0 150 151 235 194 296 313 158 236 56 33 -138 87 169 263 418 3 -451 -644 -657 -745 -313 -369 -447 -459 -417 -348 -185 -13 -231 -156 -256 -87 158 403 476 526 529 488 679 349 377 351 668 800 1045 1381 554 258 76 10 212 597 191 297 175 379 195 -179 -176 -681 -355 -700 -1035 -1211 -1810 -1664 -1215 -766 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