File name: Pandora208s1_Windsor-West_20221215_L2Fit_fwvt1c4d20220407p1-8.txt File generation date: 20250611T151906.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 208 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora208_OF_v4d20211014.txt Instrument calibration file used: Pandora208s1_CF_v4d20220407.txt Level 1 file used: Pandora208s1_Windsor-West_20221215_L1_smca1c4d20220407p1-8.txt Full location name: Ontario Ministry of the Environment, Windsor West Short location name: Windsor-West Country of location: Canada Location latitude [deg]: 42.2929 Location longitude [deg]: -83.0731 Location altitude [m]: 180 Local noon date: 20221215 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1623 1772 Nominal wavelengths inside fitting window [nm]: 492.0606 492.1820 492.3034 492.4247 492.5461 492.6674 492.7888 492.9101 493.0314 493.1527 493.2739 493.3952 493.5164 493.6376 493.7588 493.8800 494.0011 494.1223 494.2434 494.3645 494.4856 494.6067 494.7277 494.8488 494.9698 495.0908 495.2118 495.3328 495.4537 495.5747 495.6956 495.8165 495.9374 496.0583 496.1791 496.3000 496.4208 496.5416 496.6624 496.7832 496.9039 497.0247 497.1454 497.2661 497.3868 497.5075 497.6282 497.7488 497.8694 497.9900 498.1106 498.2312 498.3518 498.4723 498.5928 498.7133 498.8338 498.9543 499.0748 499.1952 499.3156 499.4360 499.5564 499.6768 499.7972 499.9175 500.0378 500.1581 500.2784 500.3987 500.5190 500.6392 500.7594 500.8796 500.9998 501.1200 501.2402 501.3603 501.4804 501.6005 501.7206 501.8407 501.9607 502.0808 502.2008 502.3208 502.4408 502.5608 502.6807 502.8007 502.9206 503.0405 503.1604 503.2802 503.4001 503.5199 503.6398 503.7596 503.8793 503.9991 504.1189 504.2386 504.3583 504.4780 504.5977 504.7174 504.8370 504.9567 505.0763 505.1959 505.3155 505.4350 505.5546 505.6741 505.7936 505.9131 506.0326 506.1521 506.2715 506.3909 506.5104 506.6297 506.7491 506.8685 506.9878 507.1072 507.2265 507.3458 507.4650 507.5843 507.7035 507.8228 507.9420 508.0612 508.1804 508.2995 508.4187 508.5378 508.6569 508.7760 508.8950 509.0141 509.1331 509.2522 509.3712 509.4902 509.6091 509.7281 509.8470 509.9659 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20221215T163244.7Z 8384.689406 391 1 42.35 2 66.79 166.31 77.57 270.81 0.00 1 0.00 1 0 15 3.405e-03 3.409e-03 1.716e-03 1.709e-03 1.366214e+03 1.000073e+02 1.012996e+02 -6.000000e+00 1.879435e+02 275.01 -2.00 20.00 -2.00 505.24 0.00e+00 7.890433e-04 4.633988e-05 4.009190e-05 -6.000000e+00 9.470769e-05 275.01 -2.00 20.00 -2.00 500.29 0.00e+00 1.572783e-01 3.420769e-02 1.241597e-02 -6.000000e+00 6.799302e-02 222.46 -2.00 3.53 -2.00 501.91 0.00e+00 2.518 0.000 489.00 513.00 1 6.9127e+00 2.6194e-03 3.7977e-03 -6.0000e+00 5.2117e-03 1.3777e-02 6.7299e-04 3.3046e-04 -6.0000e+00 1.3371e-03 1.3410e-03 -4.8585e-04 1.8118e-04 1.9623e-05 -6.0000e+00 3.7252e-04 -4.1677e-03 5.4850e-05 12 1 1 12 1 1 96.94 19.19 1.54 -0.00417 -0.00754 11 4 1 4 0 3514.310 22.61 15.01 19.19 12.26 9.4 939.06 -918 -19 -270 -31 -80 -97 436 623 424 350 177 -126 -406 -222 -302 -271 -302 34 220 17 314 718 46 662 399 -94 91 251 -172 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-173 67 -368 -11 370 268 478 491 415 334 679 172 154 51 5 385 37 141 238 352 373 -173 -252 -134 18 -209 33 -233 -197 -40 -211 222 193 368 -30 116 1 -136 -38 -290 -430 -52 SQ 20221215T165623.6Z 8384.705829 401 1 43.88 2 65.97 172.17 81.89 274.57 0.00 1 0.00 1 0 15 3.519e-03 3.539e-03 1.875e-03 1.868e-03 1.464801e+03 1.096782e+02 1.093431e+02 -6.000000e+00 1.942640e+02 275.01 -2.00 20.00 -2.00 505.24 0.00e+00 5.785028e-04 5.088777e-05 3.298415e-05 -6.000000e+00 9.790325e-05 275.01 -2.00 20.00 -2.00 500.27 0.00e+00 1.531300e-01 3.753905e-02 1.255484e-02 -6.000000e+00 7.032304e-02 222.46 -2.00 3.53 -2.00 501.89 0.00e+00 2.439 0.000 489.00 513.00 1 7.0419e+00 2.8772e-03 3.6573e-03 -6.0000e+00 5.3897e-03 1.6630e-02 7.3857e-04 3.3818e-04 -6.0000e+00 1.3839e-03 1.1952e-03 7.5276e-04 1.9921e-04 1.8077e-05 -6.0000e+00 3.8510e-04 -1.7818e-03 -8.8832e-06 12 1 1 12 1 1 98.36 19.18 1.55 -0.00178 0.00344 10 3 1 4 0 3972.430 22.61 15.00 19.18 12.50 9.4 941.32 -512 -105 -74 -78 275 88 865 154 1106 253 -212 -295 -564 28 50 -26 -512 17 136 217 273 348 425 692 273 -180 284 -12 -212 -530 -494 -516 -33 228 -89 77 -121 24 -112 -154 -71 22 -69 676 38 -20 144 89 -188 -749 -358 -649 -726 -706 -406 -416 101 134 471 193 -55 594 278 412 370 370 462 -58 -22 251 -65 -365 -471 -390 -236 49 -397 -591 51 -468 -275 -484 -366 -200 -229 65 -595 -241 603 426 95 -222 603 205 145 -147 5 -259 -15 -65 -722 -422 -272 198 -609 -246 -304 -266 126 41 100 -206 459 362 362 447 487 430 452 -142 214 -94 475 -83 -15 123 -292 418 184 -181 440 -425 200 208 -369 -315 -184 -2 326 258 274 199 256 -24 -107 225 -123 25 -144 -447 -512 -106 -74 -81 290 95 941 170 1206 275 -229 -313 -592 29 52 -27 -539 18 143 230 291 371 453 738 293 -194 303 -12 -218 -533 -508 -533 -33 236 -95 82 -129 25 -117 -160 -74 23 -72 713 41 -21 153 93 -194 -755 -350 -622 -693 -680 -400 -421 104 139 486 199 -57 614 289 426 379 374 459 -57 -22 241 -62 -353 -460 -385 -234 48 -384 -565 48 -443 -261 -464 -353 -194 -225 64 -592 -239 594 422 92 -218 594 203 142 -142 5 -248 -14 -60 -673 -400 -256 191 -600 -241 -295 -254 120 39 97 -204 456 364 366 453 494 435 452 -141 209 -91 456 -81 -15 119 -284 403 177 -174 415 -398 184 190 -341 -295 -175 -2 308 246 262 192 247 -24 -104 213 -115 24 -135 -421 SQ 20221215T170035.3Z 8384.708742 404 1 6.64 2 65.88 173.22 82.65 275.23 0.00 1 0.00 1 0 15 3.145e-03 3.150e-03 1.880e-03 1.875e-03 1.046301e+03 1.073882e+02 7.507767e+01 -6.000000e+00 1.736183e+02 275.01 -2.00 20.00 -2.00 505.25 0.00e+00 5.904332e-04 5.098606e-05 3.163044e-05 -6.000000e+00 8.748997e-05 275.01 -2.00 20.00 -2.00 500.35 0.00e+00 2.085542e-01 3.747164e-02 1.031576e-02 -6.000000e+00 6.281586e-02 222.46 -2.00 3.53 -2.00 501.96 0.00e+00 2.430 0.000 489.00 513.00 1 5.6041e+00 2.8720e-03 3.5875e-03 -6.0000e+00 4.8148e-03 1.7692e-02 7.3727e-04 2.8559e-04 -6.0000e+00 1.2354e-03 5.0230e-03 -1.6579e-04 1.9974e-04 1.5225e-05 -6.0000e+00 3.4414e-04 8.2367e-03 -2.6560e-05 12 1 1 12 1 1 91.65 19.18 1.56 0.00824 0.00709 5 12 1 4 0 1077.100 22.61 15.00 19.18 12.65 9.4 942.10 -428 -813 -293 -93 28 397 721 -97 388 -105 -94 175 72 -87 169 306 -21 28 184 164 132 217 492 392 464 338 40 -255 -8 -582 -332 -609 -111 26 -72 32 114 -57 -366 -206 -117 -177 471 435 412 43 234 227 -345 -330 -617 -632 -324 -523 -609 -339 -148 128 440 442 213 123 476 572 323 569 100 -274 88 -494 -40 -433 -419 -58 -168 130 -377 -443 -2 -142 -43 -246 -345 -141 -84 -130 123 -231 192 51 59 74 281 342 221 74 -232 -33 -511 88 -378 -220 -359 5 -123 -794 15 -269 -204 -5 -169 179 175 580 328 576 361 439 301 380 51 68 48 101 -233 -122 111 491 305 147 -96 -337 -127 -102 -420 2 -76 174 -389 280 -1 495 482 -36 -51 -204 -6 -153 -326 -163 -421 -813 -299 -95 30 424 758 -104 411 -110 -98 184 74 -89 172 313 -22 28 194 174 142 232 525 420 498 363 43 -270 -8 -586 -338 -625 -113 27 -76 33 121 -60 -383 -214 -122 -185 494 448 426 45 241 237 -356 -331 -622 -624 -317 -518 -602 -343 -152 133 454 456 220 125 480 574 331 574 100 -271 86 -478 -39 -418 -409 -57 -166 127 -364 -422 -2 -138 -41 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