File name: Pandora208s1_Windsor-West_20230421_L2Fit_fsus1c4d20220407p1-8.txt File generation date: 20251128T155804.2Z Data description: Level 2 spectral fitting results file Data file version: fsus1c4p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 208 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora208_OF_v4d20211014.txt Instrument calibration file used: Pandora208s1_CF_v4d20220407.txt Level 1 file used: Pandora208s1_Windsor-West_20230421_L1_smca1c4d20220407p1-8.txt Full location name: Ontario Ministry of the Environment, Windsor West Short location name: Windsor-West Country of location: Canada Location latitude [deg]: 42.2929 Location longitude [deg]: -83.0731 Location altitude [m]: 180 Local noon date: 20230421 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 213 357 Nominal wavelengths inside fitting window [nm]: 306.0874 306.2286 306.3698 306.5110 306.6522 306.7934 306.9345 307.0757 307.2168 307.3579 307.4990 307.6401 307.7812 307.9223 308.0633 308.2044 308.3454 308.4864 308.6275 308.7685 308.9095 309.0504 309.1914 309.3324 309.4733 309.6142 309.7552 309.8961 310.0370 310.1779 310.3187 310.4596 310.6004 310.7413 310.8821 311.0229 311.1637 311.3045 311.4453 311.5861 311.7268 311.8676 312.0083 312.1490 312.2897 312.4304 312.5711 312.7118 312.8525 312.9931 313.1338 313.2744 313.4150 313.5556 313.6962 313.8368 313.9773 314.1179 314.2584 314.3990 314.5395 314.6800 314.8205 314.9610 315.1015 315.2419 315.3824 315.5228 315.6632 315.8037 315.9441 316.0845 316.2248 316.3652 316.5056 316.6459 316.7862 316.9265 317.0669 317.2072 317.3474 317.4877 317.6280 317.7682 317.9085 318.0487 318.1889 318.3291 318.4693 318.6095 318.7496 318.8898 319.0299 319.1701 319.3102 319.4503 319.5904 319.7305 319.8705 320.0106 320.1506 320.2907 320.4307 320.5707 320.7107 320.8507 320.9907 321.1306 321.2706 321.4105 321.5504 321.6903 321.8302 321.9701 322.1100 322.2499 322.3897 322.5296 322.6694 322.8092 322.9490 323.0888 323.2286 323.3684 323.5081 323.6479 323.7876 323.9273 324.0670 324.2067 324.3464 324.4861 324.6258 324.7654 324.9051 325.0447 325.1843 325.3239 325.4635 325.6031 325.7426 325.8822 326.0217 326.1613 326.3008 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Bromine oxide slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of bromine oxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of bromine oxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of bromine oxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of bromine oxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Bromine oxide effective temperature [K] Column 28: Independent uncertainty of bromine oxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of bromine oxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of bromine oxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective bromine oxide fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for bromine oxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Formaldehyde slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of formaldehyde slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of formaldehyde slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of formaldehyde slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of formaldehyde slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Formaldehyde effective temperature [K] Column 39: Independent uncertainty of formaldehyde effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of formaldehyde effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of formaldehyde effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective formaldehyde fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for formaldehyde [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Nitrous acid slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of nitrous acid slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of nitrous acid slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of nitrous acid slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of nitrous acid slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Nitrous acid effective temperature [K] Column 50: Independent uncertainty of nitrous acid effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of nitrous acid effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of nitrous acid effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective nitrous acid fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for nitrous acid [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 56: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 57: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 58: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 59: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 60: Nitrogen dioxide effective temperature [K] Column 61: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 62: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 63: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 64: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 65: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 66: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 67: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 68: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 69: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 70: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 71: Ozone effective temperature [K] Column 72: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 73: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 74: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 75: rms-based uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 76: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 77: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 78: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 79: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 80: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 81: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 82: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 83: Sulfur dioxide effective temperature [K] Column 84: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 85: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 86: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 87: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 88: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 89: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 90: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 91: Lower limit used for wavelength scaling [nm] Column 92: Upper limit used for wavelength scaling [nm] Column 93: Order of smoothing polynomial Column 94: Smoothing polynomial coefficient, order 0 Column 95: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 96: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 97: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 98: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 99: Smoothing polynomial coefficient, order 1 Column 100: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 101: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 102: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 103: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 104: Smoothing polynomial coefficient, order 2 Column 105: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 106: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 107: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 108: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 109: Smoothing polynomial coefficient, order 3 Column 110: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 111: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 112: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 113: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 114: Smoothing polynomial coefficient, order 4 Column 115: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 116: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 117: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 118: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 119: Mean value of measured data inside fitting window [same units as measurements] Column 120: Offset polynomial coefficient, order 0 Column 121: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 122: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 123: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 124: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 125: Wavelength change polynomial coefficient, order 0 Column 126: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 127: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 128: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 129: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 130: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 131: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 132: Resolution change polynomial coefficient, order 0 Column 133: Independent uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 134: Structured uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 135: Common uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 136: rms-based uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 137: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 138: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 139: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 140: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 141: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 142: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 143: Atmospheric variability [%], 999=no atmospheric variability was determined Column 144: Wavelength effective temperature [°C], 999=no effective temperature given Column 145: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 146: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 147: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 148: Number of bright count cycles Column 149: Number of dark count cycles Column 150: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 151: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 152: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 153: Integration time [ms] Column 154: Temperature at electronics board [°C], 999=no temperature signal Column 155: Spectrometer control temperature [°C], 999=no temperature signal Column 156: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 157: Temperature in head sensor [°C], 999=no temperature signal Column 158: Humidity in head sensor [%], -9=no humidity signal Column 159: Pressure in head sensor [hPa], -9=no pressure signal Columns 160-304: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 305-449: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230421T124716.9Z 8511.532835 99 1 13.05 2 67.99 93.88 76.66 77.77 0.00 1 0.00 1 0 49 3.703e-02 8.956e-03 3.912e-02 6.830e-03 -1.181265e-06 2.554317e-06 3.801818e-07 3.791190e-07 1.675777e-05 228.85 -2.00 3.53 -2.00 322.60 0.00e+00 1.935006e-03 9.954813e-04 2.269044e-04 4.137482e-05 4.359590e-03 279.11 -2.00 20.00 -2.00 322.76 0.00e+00 5.704077e-04 1.292098e-03 4.317504e-05 2.628410e-05 7.977814e-03 279.11 -2.00 20.00 -2.00 322.25 0.00e+00 4.179804e-03 2.412590e-03 5.327240e-04 1.456825e-05 8.180277e-03 279.11 -2.00 20.00 -2.00 322.44 0.00e+00 3.195356e-01 1.124464e-02 1.714344e-03 1.268301e-03 4.765281e-02 203.64 7.73 0.00 0.20 80.73 319.69 0.00e+00 2.213168e-03 9.058801e-04 2.880410e-04 5.790201e-05 1.251807e-03 279.11 -2.00 20.00 -2.00 318.69 0.00e+00 2.645 0.000 303.00 329.40 4 5.3669e+00 2.2098e-02 2.5439e-02 1.9159e-03 1.4642e-01 -7.8001e-02 3.8013e-02 8.1283e-03 4.0339e-04 1.5822e-01 2.1404e-02 2.1233e-02 5.2963e-03 3.5725e-04 8.5656e-02 2.0381e-02 1.2868e-02 3.7322e-03 1.7511e-04 3.2305e-02 -1.4877e-02 7.6425e-03 5.1708e-04 9.2988e-05 2.4127e-02 1.4865e-04 6.5285e-03 4.7876e-03 5.1041e-04 3.0165e-05 3.3966e-03 -3.1199e-04 2.2470e-04 2.4797e-05 2.8455e-06 1.1701e-03 -2.6620e-03 -1.2746e-04 9.2103e-01 5.3913e-01 4.4213e-03 4.6122e-04 2.4143e+00 12 9 9 12 1 1 97.84 19.16 0.23 -0.00266 -0.00504 4 5 1 5 0 2575.200 22.61 15.00 19.16 22.37 11.1 1074.82 -1209 -11551 6952 2050 9405 -18631 2715 2158 5120 -7687 7939 8360 -7539 3505 -8096 886 -13783 -4886 9457 5903 -40 6805 4989 -5822 112 -6730 2656 3023 1557 396 2612 5633 -2448 4712 -1887 3921 -3478 2302 1650 -2773 -4784 1238 2835 287 2532 -805 2880 -4072 1672 230 1017 -214 -7 2737 -1124 4144 -800 1138 -2006 1872 -1823 -93 -1 738 25 -1440 1233 -2197 -631 -4443 -529 -2434 1243 1302 -482 854 -192 -35 -1088 -428 -1296 380 -407 1156 274 -768 -366 373 -142 -15 1258 -709 1272 -191 -234 277 151 718 -789 -315 41 1418 -468 411 -200 522 316 470 -257 -959 358 -160 391 -526 957 429 207 -854 -857 1376 -345 829 -989 -201 -725 82 -1067 -274 771 190 10 -216 215 -369 361 -139 -815 -65 498 -354 544 173 -99 271 -267 -49 -580 295 93 434 -1400 192 180 459 -836 770 842 -924 384 -1000 103 -1991 -673 1156 734 -5 761 593 -853 17 -1206 437 472 255 74 560 1335 -721 1389 -622 1253 -1206 756 548 -952 -1666 407 948 106 978 -342 1240 -1934 765 108 466 -98 -3 1300 -580 2210 -474 643 -1096 993 -1023 -54 -1 510 18 -1011 797 -1345 -360 -2482 -288 -1505 812 955 -395 698 -167 -33 -1078 -436 -1295 381 -387 995 229 -620 -304 326 -140 -16 1435 -844 1417 -201 -236 274 159 775 -906 -379 52 1811 -652 591 -287 707 415 574 -308 -1188 463 -214 538 -724 1266 572 262 -1046 -1004 1619 -421 1085 -1359 -287 -1071 124 -1658 -446 1285 325 17 -370 353 -587 574 -215 -1347 -113 922 -689 1125 364 -214 588 -577 SS 20230421T132005.5Z 8511.555620 120 1 47.07 2 61.96 99.73 70.79 82.71 0.00 1 0.00 1 0 49 5.835e-03 1.692e-03 7.960e-03 2.012e-03 5.295929e-08 7.603438e-07 4.141464e-08 3.789627e-07 2.737027e-06 228.85 -2.00 3.53 -2.00 322.45 0.00e+00 5.183269e-04 2.902823e-04 2.460666e-05 4.097526e-05 6.993778e-04 279.11 -2.00 20.00 -2.00 322.64 0.00e+00 -3.422229e-04 3.822253e-04 1.210259e-05 2.641406e-05 1.252891e-03 279.11 -2.00 20.00 -2.00 322.11 0.00e+00 7.884564e-04 6.398953e-04 7.570006e-05 1.671495e-05 1.289984e-03 279.11 -2.00 20.00 -2.00 322.29 0.00e+00 2.744060e-01 3.276317e-03 2.318220e-04 1.269393e-03 7.474500e-03 222.31 2.78 0.00 0.23 12.85 319.22 0.00e+00 2.162766e-04 2.247025e-04 5.654380e-05 5.808973e-05 1.906809e-04 279.11 -2.00 20.00 -2.00 318.11 0.00e+00 2.117 0.000 303.00 329.40 4 4.4902e+00 7.4079e-03 2.0189e-02 1.9168e-03 2.3224e-02 -1.2514e-02 1.1947e-02 2.4104e-03 4.5557e-04 2.5049e-02 1.1555e-02 6.4550e-03 8.2371e-04 3.6325e-04 1.3619e-02 -9.8639e-03 3.2406e-03 4.7680e-04 1.3979e-04 5.4437e-03 4.1742e-03 1.9913e-03 5.9800e-05 9.4968e-05 3.7509e-03 6.3541e-04 -3.0515e-03 1.5672e-03 1.0908e-04 3.4063e-05 1.2623e-03 -5.0356e-04 6.4748e-05 3.6115e-06 2.9718e-06 1.8425e-04 -2.0565e-03 -1.5123e-04 2.0249e-01 1.8367e-01 2.0957e-03 3.8286e-04 4.3162e-01 12 8 8 10 0 0 99.97 19.13 0.42 -0.00206 -0.00590 124 34 1 5 0 379.490 22.61 15.00 19.13 22.54 11.1 1076.25 -560 4628 682 264 1585 -770 1356 -1488 -941 -1251 -735 -244 -83 -333 -465 21 70 -161 688 -816 -1208 -724 -499 -283 568 -234 864 -45 402 -30 556 -127 574 -270 -224 211 360 299 -149 206 -889 617 299 429 -443 878 40 -253 -264 43 -14 -282 -54 375 545 -162 113 96 -384 -17 -183 -237 -60 38 -59 -68 -3 424 -328 -11 467 401 -46 -309 -112 -386 -151 -72 71 31 12 -44 -136 258 -91 -45 -115 71 238 152 381 149 -383 -178 -243 56 -156 -145 -19 73 -49 -57 -146 40 253 3 -56 81 -18 9 46 133 159 46 11 262 -30 -108 -93 170 23 20 239 -12 -224 -42 -172 -102 78 -12 -48 95 -229 228 -8 -110 -73 -107 -88 53 -81 -15 91 37 60 -37 321 51 20 126 -71 141 -180 -122 -170 -104 -36 -12 -51 -71 3 12 -28 124 -146 -204 -115 -81 -49 106 -48 175 -9 80 -7 146 -40 204 -104 -89 86 146 121 -60 81 -349 237 118 181 -200 414 20 -130 -138 23 -7 -145 -28 203 319 -103 75 62 -229 -10 -105 -150 -42 29 -45 -51 -2 276 -194 -6 255 242 -32 -237 -93 -342 -141 -72 68 31 12 -43 -139 241 -78 -36 -95 64 237 168 418 167 -412 -196 -248 56 -169 -168 -22 84 -59 -73 -198 56 348 4 -67 100 -22 10 60 169 210 61 14 357 -38 -134 -110 195 28 25 331 -18 -301 -59 -252 -157 125 -19 -80 154 -361 346 -12 -164 -115 -182 -161 104 -171 -33 205 83 133 SS 20230421T132811.8Z 8511.561248 126 1 16.37 2 60.48 101.24 69.33 83.94 0.00 1 0.00 1 0 49 9.530e-03 3.013e-03 9.802e-03 3.203e-03 -2.636185e-06 1.208548e-06 5.634970e-08 3.788221e-07 4.478883e-06 228.85 -2.00 3.53 -2.00 322.02 0.00e+00 9.407242e-04 4.445132e-04 4.218749e-05 4.069284e-05 1.154454e-03 279.11 -2.00 20.00 -2.00 321.98 0.00e+00 7.279553e-04 5.965780e-04 1.351064e-05 2.626737e-05 2.036428e-03 279.11 -2.00 20.00 -2.00 321.80 0.00e+00 9.992373e-04 9.371926e-04 8.853045e-05 1.736845e-05 2.107399e-03 279.11 -2.00 20.00 -2.00 321.88 0.00e+00 2.686514e-01 4.916070e-03 2.032924e-04 1.269158e-03 1.219160e-02 222.96 4.29 0.00 0.23 20.92 318.56 0.00e+00 -1.611745e-05 3.019960e-04 4.492622e-06 5.812045e-05 3.109338e-04 279.11 -2.00 20.00 -2.00 317.49 0.00e+00 2.021 0.000 303.00 329.40 4 4.9587e+00 1.1711e-02 1.9278e-02 1.9133e-03 3.7895e-02 2.2120e-03 1.7747e-02 2.2426e-03 4.4799e-04 4.0895e-02 9.0172e-03 9.5969e-03 5.3083e-04 3.4316e-04 2.2405e-02 -4.6544e-03 4.5764e-03 1.7492e-04 1.0833e-04 8.9495e-03 -3.1460e-04 2.9303e-03 1.0141e-04 9.7788e-05 5.9156e-03 4.3345e-04 -3.6736e-03 2.3505e-03 9.8914e-05 2.5187e-05 2.4625e-03 -8.1300e-04 1.0063e-04 2.3995e-06 2.8051e-06 3.0074e-04 -2.0830e-03 -1.6909e-04 5.0606e-01 2.9170e-01 5.3463e-03 3.2040e-04 7.4000e-01 12 9 9 12 1 1 99.98 19.10 0.30 -0.00208 -0.00829 17 14 1 5 0 899.580 22.50 15.01 19.10 22.33 11.2 1075.19 -5301 841 -3208 2784 -436 1761 -233 -469 -2192 -2382 1749 -1941 2786 -980 922 1600 -637 885 1192 -1331 -522 630 -1303 2985 -287 1635 -1456 800 1511 -455 544 -25 1076 -127 1253 -510 525 -717 -294 220 -132 982 -749 -309 -709 343 -909 -263 34 -73 -557 -610 -141 -440 505 -354 529 -341 -142 -324 52 89 -93 528 566 356 -162 53 -75 375 230 573 461 -167 -266 9 -337 -202 43 -192 238 -94 60 156 -265 -394 -460 30 -443 468 381 17 -204 464 -295 -200 101 -268 317 -157 425 128 -133 -89 196 13 75 218 -130 -42 -88 -100 -163 114 -464 341 -14 -311 405 -205 174 -324 -4 -151 232 -101 -51 138 -152 157 -103 189 -250 197 -50 417 -357 29 14 140 -103 -25 222 -187 -6 -493 81 -333 273 -47 210 -32 -73 -376 -426 312 -372 525 -193 178 319 -138 198 274 -306 -112 126 -270 635 -68 411 -379 194 373 -129 178 -9 445 -57 575 -243 248 -341 -139 101 -60 434 -344 -150 -369 187 -524 -155 20 -44 -335 -361 -84 -275 338 -242 373 -234 -96 -209 34 64 -70 422 461 284 -124 39 -50 232 142 387 353 -135 -235 8 -331 -199 45 -208 261 -101 61 153 -240 -335 -399 28 -464 509 451 21 -237 498 -314 -210 106 -305 375 -195 551 167 -183 -128 275 17 97 262 -152 -51 -112 -129 -220 152 -609 452 -18 -375 461 -243 204 -410 -6 -211 313 -141 -74 213 -243 244 -163 308 -396 300 -75 623 -566 47 24 250 -197 -50 451 -380 -12 SS 20230421T162201.0Z 8511.681956 241 1 6.13 2 33.87 148.62 38.35 116.55 0.00 1 0.00 1 0 49 2.901e-03 1.899e-03 2.624e-03 1.837e-03 -1.868843e-06 7.261283e-07 2.650824e-08 3.785021e-07 1.375369e-06 228.86 -2.00 3.53 -2.00 320.57 0.00e+00 6.607819e-04 2.361372e-04 5.313325e-06 3.974385e-05 3.606343e-04 279.12 -2.00 20.00 -2.00 320.19 0.00e+00 1.737703e-04 3.479692e-04 9.478498e-06 2.525308e-05 6.225269e-04 279.12 -2.00 20.00 -2.00 320.75 0.00e+00 7.082788e-04 4.295903e-04 5.705402e-05 1.762275e-05 6.422385e-04 279.12 -2.00 20.00 -2.00 320.47 0.00e+00 1.552652e-01 2.300048e-03 1.124469e-04 1.268243e-03 3.636393e-03 217.86 3.59 0.00 0.41 6.34 315.85 0.00e+00 5.100919e-05 9.578992e-05 1.436201e-05 5.807814e-05 9.249837e-05 279.12 -2.00 20.00 -2.00 314.95 0.00e+00 1.204 0.000 303.00 329.40 4 4.2031e+00 6.2982e-03 1.1486e-02 1.9106e-03 1.1550e-02 5.1239e-04 7.8638e-03 1.3389e-03 4.3276e-04 1.2336e-02 1.0236e-02 4.4635e-03 2.5189e-04 2.6774e-04 6.8875e-03 -6.4934e-03 1.6481e-03 8.1050e-05 5.2061e-05 2.4993e-03 9.1092e-04 1.2846e-03 2.8258e-05 7.6681e-05 1.6809e-03 2.4043e-03 -1.2654e-03 1.4820e-03 5.6421e-05 1.4310e-05 1.5761e-03 -4.2397e-04 5.5035e-05 1.5966e-06 2.3410e-06 9.1396e-05 -2.7104e-03 -1.2968e-04 1.7886e-01 2.0113e-01 8.1987e-04 1.3855e-03 2.8087e-01 12 9 9 12 9 1 99.97 19.15 0.48 -0.00271 -0.00595 20 45 1 5 0 283.330 22.61 15.00 19.15 15.90 11.1 1019.80 -58 747 507 -109 -604 452 1023 -472 -111 -738 67 -713 83 -510 287 3 -42 489 -463 -105 -383 544 132 1062 -192 -23 -400 -204 663 -317 411 -55 309 -144 395 -567 -240 73 -445 222 -23 496 36 494 -371 212 55 194 -236 -95 351 -292 44 240 250 261 -5 -114 -121 -200 7 96 -211 71 79 244 -398 -63 -241 -270 34 -149 191 0 -110 -242 115 -170 286 -47 -146 -92 -28 -42 -130 -34 -132 -239 -314 325 -60 18 289 131 118 -20 54 -246 74 8 -32 161 104 66 183 17 50 101 -104 -131 26 58 55 -21 100 69 76 -110 19 48 -114 -257 92 115 57 5 -122 -196 -197 -70 -78 79 84 -40 40 124 -111 -205 132 -20 -99 63 136 10 19 -16 224 156 -33 -189 154 383 -197 -49 -330 30 -334 39 -244 135 1 -20 234 -229 -50 -185 241 58 480 -92 -12 -203 -97 319 -157 235 -34 217 -107 302 -445 -186 56 -339 162 -16 337 25 353 -280 166 45 160 -198 -74 292 -241 36 193 216 238 -5 -102 -98 -164 6 79 -195 69 79 239 -375 -54 -201 -207 25 -120 171 0 -109 -253 117 -187 330 -53 -168 -104 -32 -44 -130 -31 -123 -238 -319 361 -73 20 336 142 128 -21 59 -289 91 9 -40 208 140 86 245 22 61 114 -114 -146 31 70 69 -26 125 83 92 -126 20 54 -125 -299 112 145 72 6 -156 -265 -276 -94 -106 107 118 -55 53 166 -156 -292 201 -30 -161 105 219 17 31 SS 20230421T170508.2Z 8511.711901 263 1 47.49 2 30.87 167.58 31.69 129.53 0.00 1 0.00 1 0 49 6.531e-03 3.493e-03 6.600e-03 3.680e-03 -2.281344e-06 1.436041e-06 5.814590e-08 3.783807e-07 3.081731e-06 228.86 -2.00 3.53 -2.00 321.29 0.00e+00 8.287884e-04 4.947732e-04 3.586281e-05 4.005828e-05 8.053980e-04 279.13 -2.00 20.00 -2.00 321.19 0.00e+00 1.655987e-03 6.984497e-04 1.655564e-05 2.563441e-05 1.402117e-03 279.13 -2.00 20.00 -2.00 321.25 0.00e+00 1.096962e-03 9.495444e-04 3.326902e-05 1.857543e-05 1.446270e-03 279.13 -2.00 20.00 -2.00 321.19 0.00e+00 1.554958e-01 4.784983e-03 7.850953e-05 1.268633e-03 8.169146e-03 207.97 7.25 0.00 0.42 14.26 316.93 0.00e+00 -1.362987e-05 2.348690e-04 6.689423e-06 5.814574e-05 2.084231e-04 279.13 -2.00 20.00 -2.00 315.92 0.00e+00 1.164 0.000 303.00 329.40 4 6.5700e+00 1.1994e-02 1.1118e-02 1.9093e-03 2.5939e-02 5.8965e-03 1.5800e-02 1.2044e-03 4.4174e-04 2.7707e-02 1.4682e-02 9.1963e-03 3.9416e-04 3.0599e-04 1.5415e-02 -1.0809e-02 3.5615e-03 9.5611e-05 7.0127e-05 5.6218e-03 5.4803e-03 2.7738e-03 1.1909e-04 8.8725e-05 3.7810e-03 2.3325e-04 -9.3265e-03 3.4853e-03 1.0670e-04 2.2788e-05 3.6891e-03 -4.6744e-04 1.1599e-04 2.1083e-06 2.6436e-06 2.0576e-04 -3.3500e-03 -1.2308e-04 1.7391e+00 4.3002e-01 8.1863e-03 6.6570e-04 6.3921e-01 12 9 8 11 8 0 99.94 19.18 0.59 -0.00335 -0.00692 34 9 1 5 0 1396.510 22.61 14.99 19.18 17.54 11.1 1033.94 -601 -248 178 1846 2403 3056 779 1115 -877 1360 309 -983 -592 -1731 -743 344 -1319 -1761 -4 -931 221 -700 -1542 1339 316 -342 -660 -476 586 -13 1593 49 177 433 -93 -214 150 558 -254 579 -334 838 -48 7 -245 -27 105 46 -492 -312 -593 -346 160 181 84 -365 582 -1168 264 29 236 -674 -59 362 248 480 431 583 414 -647 -224 76 -523 412 -193 421 -110 568 69 -466 348 -169 -65 382 -781 -360 74 355 176 -106 192 356 -405 162 -362 15 120 -513 -647 100 393 -231 97 28 242 -225 380 22 -420 -440 69 28 -238 -88 9 125 382 -394 279 79 -661 90 -31 189 13 96 46 -208 132 53 39 -67 351 240 139 -58 -96 -250 99 172 43 44 -70 122 -343 -117 -52 38 408 544 753 216 319 -270 441 103 -341 -208 -618 -261 123 -500 -693 -2 -360 78 -234 -513 448 112 -129 -248 -169 210 -5 727 27 108 279 -62 -145 101 371 -168 366 -205 493 -29 4 -160 -18 74 33 -359 -229 -430 -248 115 136 67 -311 505 -980 200 21 166 -519 -50 327 229 434 373 463 296 -431 -145 53 -407 350 -178 404 -112 611 79 -555 418 -200 -72 386 -725 -309 63 323 176 -117 227 426 -466 174 -366 15 128 -592 -781 124 507 -313 137 40 337 -295 455 24 -452 -484 81 35 -313 -116 11 156 448 -443 316 87 -759 108 -36 230 16 121 61 -290 190 78 59 -100 505 336 190 -81 -139 -389 166 305 81 86 -129 237 -658